Light-stabilized synthetic linear polyesters and shaped structures made therefrom
    1.
    发明授权
    Light-stabilized synthetic linear polyesters and shaped structures made therefrom 失效
    光稳定的合成线性聚酯和由其制成的成型结构

    公开(公告)号:US3887521A

    公开(公告)日:1975-06-03

    申请号:US46903274

    申请日:1974-05-10

    Applicant: HOECHST AG

    CPC classification number: C08G63/60

    Abstract: Light-stabilized synthetic linear, fiber- and film-forming polyesters are obtained by incorporating into the macromolecules composed of dicarboxylic acid and diol moieties about 0.1 to 5 mole percent of structural units of the formula

    IN WHICH X stands for the group

    WHEREIN R1, R2 and R3 each are hydrogen or an alkyl radical having from 1 to 4 carbon atoms.

    Abstract translation: 通过掺入由二羧酸和二醇部分组成的大分子中获得轻稳定的合成线性,纤维和成膜聚酯,其中约0.1至5摩尔%的式IN结构单元,其中X代表WHEREIN R1,R2 和R 3各自为氢或具有1至4个碳原子的烷基。

    RAPIDLY CRYSTALLIZING POLYESTER MOLDING MATERIALS

    公开(公告)号:CA2027068A1

    公开(公告)日:1991-04-07

    申请号:CA2027068

    申请日:1990-10-05

    Applicant: HOECHST AG

    Inventor: BLOCKER ERICH

    Abstract: Thermoplastic molding materials substantially consisting of, in each case, at least one (A) polyalkylene terephthalate having a reduced specific viscosity (measured in 1% strength solution in dichloroacetic acid at 25.degree.C) of at least 0.3 dl/g, (B) nucleating agent, (C) crystallization accelerator, and (D) if required, reinforcing agents and other conventional additives, in which (C) is at least one N,N'-disubstituted asymmetric oxalic acid bismide. The use of such components (C) leads to only little migration and sublimation where moldings produced from the molding material are heated, so that a satisfactory surface quality results. The nucleating agents and accelerators used in the molding material make it possible to reduce the mold temperature to at least 100 to 100.degree.C.

    PROCESS FOR THE PREPARATION OF AROMATIC COPOLYAMIDE-PHOSPHONAMIDES

    公开(公告)号:CA956744A

    公开(公告)日:1974-10-22

    申请号:CA130260

    申请日:1971-12-16

    Applicant: HOECHST AG

    Abstract: 1331840 Copolycarbonamide-phosphonamide filaments FARBWERKE HOECHST AG 17 Dec 1971 [19 Dec 1970] 58866/71 Heading B5B [Also in Division C3] A process for preparing co-poly-carbonamidephosphonamides comprises (a) reacting a phosphonic acid dihalide with at least one molten aromatic diamine and subsequently, after complete reaction, (b) polycondensing the reaction product with at least one aromatic dicarboxylic acid halide. Step (b) is preferably effected in an amide solvent but emulsion or interfaval techniques may also be used. The ratio of phosphonic, carboxylic acids will normally be between 1 : 99 and 30 : 70. The phosphonic dihalide may be a chloride or bromide of an aliphatic, cycloaliphatic or aromatic phosphonic acid, e.g. methyl, ethyl, n- or iso-propyl, cyclohexyl, phenyl, tolyl or naphthyl phosphonic acid. Specified diamines are m- and p-phenylene diamines, benzidine, 4,4 1 -diamino-stilbene and 4,4 1 -diamino-diphenyl-methane, ether-or-sulphone. Specified carboxylic acids are iso- and tere-phthalic and 4,4 1 -dicarboxy-diphenyl, -diphenyl ether or -diphenyl sulphone. Up to 10 mol. per cent of the aromatic diamine and/or diacid may be replaced by a corresponding aliphatic compound. Solutions of the polymers of inherent viscosity above 1 in dimethyl acetamide and 2% CaCl 2 may be spun into dyeable fire-resistant filaments. In examples a 22% solution of the polymer is spun through a nozzle having 100 holes of 150 Á diameter into a coagulation bath of 50 parts water, 10 parts dimethylacetamide and 40 parts CaCl 2 . After several washings the filament is after-drawn and fixed at 300‹ C. the total draw-ratio being 1 : 2À75.

Patent Agency Ranking