CONTINUOUS PROCESS FOR REMOVING UNSTABLE COMPONENTS FROM CRUDE OXYMETHYLENE COPOLYMER

    公开(公告)号:CA1307871C

    公开(公告)日:1992-09-22

    申请号:CA558207

    申请日:1988-02-05

    Applicant: HOECHST AG

    Abstract: HOE 87/F 037 Continuous process for removing unstable components from crude oxymethylene copolymer, which still contains catalysts, monomeric starting materials and unstable components, by treating the copolymer with deactivators, optionally in the presence of auxiliaries, in a pressure zone, and subsequently removing volatile components in a pressure-release zone in the presence or absence of stabilizers, in which process the crude polymer is fully melted in the absence of the deactivators and auxiliaries immediately after completion of the polymerization step, and the deactivators are subsequently incorporated, alone or together with auxiliaries, under pressure into the resultant polymer melt in at least one pressure zone. By this process, degradation is avoided and significantly better properties are contained.

    RECOVERING UNREACTED PROPYLENE
    2.
    发明专利

    公开(公告)号:AU530075B2

    公开(公告)日:1983-06-30

    申请号:AU4805279

    申请日:1979-06-14

    Applicant: HOECHST AG

    Abstract: During the recovery of the unreacted propylene from the mother liquor obtained in the polymerization of liquid propylene, the major part of the propylene is evaporated in a first evaporation step at a low temperature and the remaining part is evaporated in a second evaporator at a high temperature. In this way an early agglomerization of the atactic and/or low-molecular weight polymer dissolved in the mother liquor and fouling of the heat exchanger tubes and/or of the column trays is avoided.

    RECOVERING UNREACTED PROPYLENE
    3.
    发明专利

    公开(公告)号:AU4805279A

    公开(公告)日:1979-12-20

    申请号:AU4805279

    申请日:1979-06-14

    Applicant: HOECHST AG

    Abstract: During the recovery of the unreacted propylene from the mother liquor obtained in the polymerization of liquid propylene, the major part of the propylene is evaporated in a first evaporation step at a low temperature and the remaining part is evaporated in a second evaporator at a high temperature. In this way an early agglomerization of the atactic and/or low-molecular weight polymer dissolved in the mother liquor and fouling of the heat exchanger tubes and/or of the column trays is avoided.

    PROCESS FOR RECOVERING UNREACTED PROPYLENE IN THE MASS POLYMERIZATION

    公开(公告)号:CA1109494A

    公开(公告)日:1981-09-22

    申请号:CA329816

    申请日:1979-06-14

    Applicant: HOECHST AG

    Abstract: PROCESS FOR RECOVERING UNREACTED PROPYLENE IN THE MASS POLYMERIZATION of the disclosure During the recovery of the unreacted propylene from the mother liquor obtained in the polymerization of liquid propylene, the major part of the propylene is evaporated in a first evaporation step at a low temperature and the remaining part is evaporated in a second evaporator at a high temperature. In this way an early agglomerization of the atactic and/or lowmolecular weight polymer dissolved in the mother liquor and fouling of the heat exchanger tubes and/or of the column trays is avoided.

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