公开(公告)号：US3760059A

公开(公告)日：1973-09-18

申请号：US3760059D

申请日：1971-11-16

Applicant: HOECHST AG

Inventor： ERTEL H ,  FRISCH P

IPC: B01J27/06 ,  C01G30/00 ,  C01B29/00

CPC classification number: C01G30/007 ,  B01J27/06

Abstract: The invention relates to the recovery of antimony pentachloride from catalyst solutions, which are used for the fluorination of chlorosubstituted methanes or ethanes. The process is based on the reduction of antimony pentachloride, which is dissolved in a used catalyst solution by means of trichloroethylene, at a temperature of from 100* C to 170* C. The crystalline antimony trichloride obtained precipitates from the solution and is separated from all the impurities. The antimony trichloride obtained can be re-oxidized to form antimony pentachloride by any known process.

Abstract translation: 本发明涉及从催化剂溶液中回收五氯化锑，其用于氯取代的甲烷或乙烷的氟化。 该方法基于在100℃至170℃的温度下，通过三氯乙烯溶解在所用催化剂溶液中的五氯化锑的还原。结晶三氯化锑从溶液中获得沉淀，并从 所有的杂质。 获得的三氯化锑可以通过任何已知的方法再氧化形成五氯化锑。

公开(公告)号：US3752850A

公开(公告)日：1973-08-14

申请号：US3752850D

申请日：1970-12-24

Applicant: HOECHST AG

Inventor： SCHERER O ,  KORINTH J ,  FRISCH P

IPC: C07B39/00 ,  C07C17/20 ,  C07C17/21 ,  C07C45/63 ,  C07C49/16 ,  C07C53/14 ,  C07C53/34

CPC classification number: C07C45/63 ,  C07B39/00 ,  C07C17/206 ,  C07C17/21 ,  C07C47/14 ,  C07C49/167

Abstract: FLUORINATION OF HALOGENATED ALIPHATIC HYDROCARBON IS EFFECTED BY REACTING SAID HYDROCARBONS WITH HYDROGEN FLUORIDE IN GASEOUS PHASE AT ELEVATED TEMPERATURES IN THE PRESENCE OF A CATALYST, THE EMPIRICAL COMPOSITION OF WHICH VARIES SUCH AS BETWEEN CRF1.5O1.5 AND CRF2O OR A CATALYST, THE EMPIRICAL COMPOSITION OF WHICH VARIES SUCH AS BETWEEN CRFO2 AND CRF2O.

公开(公告)号：SE313804B

公开(公告)日：1969-08-25

申请号：SE1372466

申请日：1966-10-11

Applicant: HOECHST AG

Inventor： FRISCH P ,  KORINTH J

IPC: C01B7/19