Abstract:
A PROCESS FOR PREPARING BENZOXAZOLONES-(2) AND BENZOTHIAZONES-(2) HAVING THE GENERAL FORMULA
O=C WHEREIN R IS A HYDROGEN OR HALOEN ATOM, PREFERABLY A CHLORINE OR BROMINE ATOM, AN ALKYL GROUP HAVING 1 TO 3 CARBON ATOMS, PREFERABLY AMETHYL GROUP, AN ALKOXY GROUP HAVING 1 TO 3 CARBON ATOMS, PREFERABLY A METHYL GROUP AND X IS OXYGEN OR SULFUR. THE BENZOXAZOLONES-(2) OR THE BENOTHIAZOLONES-(2) THUS OBTAINED ARE VALUABLE INTERMEDIATES FOR PHARMACEUTICAL PRODUCTS, FOR EXAMPLE ANALGETICS, HYPNOTIC, ANTIPYRETICS AND ESPECIALLY FOR DYESTUFFS SUCH AS AZO DYESTUFFS.
Abstract:
Novel valuable, water-insoluble disazo pigments of the general formula 1 WHEREIN R is hydrogen, methyl, methoxy or halogen, preferably chlorine or bromine, and X also represents hydrogen or halogen, preferably chlorine. The disazo compounds are obtained by bisdiazotizing a 2,7-diaminodiphenylenesulfone and coupling it on an acetoacetylbenzimidazolone. These pigments are suitable for preparing printing inks, color lakes and dispersion paints, for dyeing rubber, plastics and natural or synthetic resins. Furthermore, they are suitable for the printing of pigments on substrates, especially textile fibre materials or other flat articles such as paper.
Abstract:
1,2,4-TRIAMINO BENZENES ARE OBTAINED IN HIGH YIELD AND PURITY BY CATALYTIC HYDROGENATION OF 2,4-DINITRO ANILINES IN WATER CONTAINING AT LEAST ONE MOLAR EQUIVALENT OF A MONO- OR DI-CARBOXYLIC ACID. The products are known and useful as intermediates for dyes and biocides.
Abstract:
Novel valuable, water-insoluble disazo pigments of the general formula 1 WHEREIN R is hydrogen, methyl, methoxy or halogen, preferably chlorine or bromine, and X also represents hydrogen or halogen, preferably chlorine. The disazo compounds are obtained by bisdiazotizing a 2,7-diaminodiphenylenesulfone and coupling it on an acetoacetylbenzimidazolone. These pigments are suitable for preparing printing inks, color lakes and dispersion paints, for dyeing rubber, plastics and natural or synthetic resins. Furthermore, they are suitable for the printing of pigments on substrates, especially textile fibre materials or other flat articles such as paper.
Abstract:
1371688 Preparation of benzoxalones-(2) and benzothiazolones-(2) FARBWERKE HOECHST AG 22 June 1972 [24 June 1971] 29273/72 Heading C2C Benzoxazolanes - (2) and benzothiazolones- (2) of general formula where R represents hydrogen, halogen, C 1 -C 3 alkyl or C 1 -C 3 alkyloxy and X is O or S are prepared by condensing urea in solution, preferably aqueous, in the presence of an acid, with an aminophenol or an aminothiophenol of formula the pH of the reaction mixture not exceeding 7. The acid catalyst may be sulphuric, hydrochloric, phosphoric or hydrobromic acid and preferably 1À5 to 3 moles of urea are used per mol of aminophenol or aminothiophenol.
Abstract:
1527892 Preparation of 4-chloro-2,5-dimethoxyaniline HOECHST AG 25 Nov 1975 [25 Nov 1974] 48445/75 Heading C2C 4 - Chloro - 2,5 - dimethoxyaniline or a salt thereof is obtained by treating a mixture comprising water and particles of 4-chloro-2,5- dimethoxynitrobenzene having an average size of less than 100 microns with hydrogen in the presence of a nickel catalyst, and if desired, converting the 4-chloro-2,5-dimethoxyaniline to a salt thereof.