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公开(公告)号:AU5331886A
公开(公告)日:1986-08-14
申请号:AU5331886
申请日:1986-02-07
Applicant: HOECHST AG
Inventor: JUST CHRISTOPH , PLATH KIETER , WALZ GERD
IPC: C08F222/22 , C08F246/00 , C09D135/00 , C09D175/14 , C08F220/06 , C08F220/18 , C08F220/32 , C08F220/44 , C08F220/56 , C08F212/08 , C08F218/08 , C09D3/52 , C09D3/66
Abstract: Copolymers based on (A) 5-95% by weight of at least one polymerizable carbamoyloxyalkyldicarboxylic acid ester, carrying hydroxyl groups, of the general formula I in which R1 represents hydrogen or alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, R2 represents alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, or the radical subject to the proviso that R1 is hydrogen and x is an integer from 2 to 10, R3 represents linear or branched alkylene having 2 to 5 carbon atoms, R4 represents hydrogen or methyl and R5 represents hydroxyalkyl or hydroxyaminoalkyl having in each case 2 to 20 carbon atoms in the alkyl radical, or an alkyl radical of this type which also contains ester groups and/or ether groups, and (B) 5-95% by weight of at least one copolymerizable monomer belonging to the group comprising (a) alpha , beta -olefinically unsaturated monocarboxylic acid and alkyl and hydroxyalkyl esters thereof having in each case 1 to 18 carbon atoms in the alkyl radical, and amides and nitriles thereof, and also monoalkyl and dialkyl esters of alpha , beta -olefinically unsaturated dicarboxylic acids having 1 to 18 carbon atoms in the alkyl radical, (b) vinyl-aromatic monomers, (c) vinyl esters of organic monocarboxylic acids having 1 to 18 carbon atoms in the carboxylic acid radical, and (d) glycidyl esters of unsaturated monocarboxylic and/or dicarboxylic acids, the sum of the components (A) and (B) being in all cases 100% by weight, and a process for their preparation. The copolymers are used for the preparation of shaped articles and/or coatings which have excellent properties.