PROCESS AND APPARATUS FOR THE PRODUCTION OF SUBSTANTIALLY WATER-INSOLUBLE LINEAR AMMONIUM POLYPHOSPHATES

    公开(公告)号:CA1035543A

    公开(公告)日:1978-08-01

    申请号:CA202384

    申请日:1974-06-13

    Applicant: HOECHST AG

    Abstract: 1446260 Ammonium polyphosphates HOECHST AG 10 April 1974 [14 June 1973] 15885/74 Heading C1A Linear ammonium polyphosphates, where n=10-1000, being water-insoluble or having a controlled water-insolubility, are prepared by reacting equimolecular proportions of ammonium orthophosphate and phosphorus pentoxide with gaseous ammonia at 170-350‹ C. while continuously and simultaneously mixing, kneading and comminuting the reactants. The water-insolubility of the final product may be predetermined by the use of a certain reaction temperature, the water-insolubility increasing with increased temperature (e.g. watersolubility is 22% at 200‹ C., 13% at 210 ‹C, 9% at 230‹ C., 6% at 250‹ C. and 2-3% at 270‹ C.). The preparation may be carried out in an apparatus, Fig. 1, in which the solid reactants are delivered from reservoirs 1 and 1 1 , via weighing means 2 and 2 1 , through a conduit 3 to a reactor 4. The latter is a closed trough provided with a heating jacket through which a heating medium is circulated through an inlet 6 and outlet 6 1 . Ammonia is introduced at 4 by a supply tube 7 and distributed across the surface of the reaction mass, preferably by means of a tube provided with a plurality of small perforations. Excess ammonia escapes via 9. Implements 10 (normally two double Z-shaped blades) mix, knead and comminute the reaction material. The reaction product is delivered via 14 and cooling means 11 to a sieving or screening mechanism 12. Oversize material may be returned to the reactor.

    2.
    发明专利
    未知

    公开(公告)号:PT93412A

    公开(公告)日:1990-11-07

    申请号:PT9341290

    申请日:1990-03-12

    Applicant: HOECHST AG

    Abstract: An agent for desulfurizing molten metals, in particular molten iron, comprises a CaC2/CaO crystal blend with a maximum of 62% by weight of CaC2, gas-evolving substances and 0 to 44% by weight of metallic magnesium as the components. For desulfurizing molten metals, in particular molten iron, using this agent, either the mixture comprising both the CaC2/CaO crystal blend and gas-evolving substances, and the magnesium, are fluidized separately and the two fluidized products are combined immediately before they enter the melt, or the CaC2/CaO crystal blend, gas-evolving substances and magnesium components are fluidized together and the fluidized product is introduced into the melt.

    AGENT AND PROCESS FOR DESULFURIZING MOLTEN METALS

    公开(公告)号:CA2011380A1

    公开(公告)日:1990-09-13

    申请号:CA2011380

    申请日:1990-03-02

    Applicant: HOECHST AG

    Abstract: HOE 89/H 010 Agent and process for desulfurizing molten metals An agent for desulfurizing molten metals, in particular molten iron, comprises a CaC2/CaO crystal blend with a maximum of 62% by weight of CaC2, gas-evolving substances and 0 to 44% by weight of metallic magnesium as the components. For desulfurizing molten metals, in particular molten iron, using this agent, either the mixture comprising both the CaC2/CaO crystal blend and gas-evolving substances, and the magnesium, are fluidized separately and the two fluidized products are combined immediately before they enter the melt, or the CaC2/CaO crystal blend, gasevolving substances and magnesium components are fluidized together and the fluidized product is introduced into the melt.

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