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公开(公告)号:CH594587A5
公开(公告)日:1978-01-13
申请号:CH190775
申请日:1975-02-17
Applicant: HOECHST AG
Inventor: SARTORIUS RUDOLF DR , STAPF HANS
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公开(公告)号:CH630600A5
公开(公告)日:1982-06-30
申请号:CH1557677
申请日:1977-12-19
Applicant: HOECHST AG
Inventor: SARTORIUS RUDOLF DR , STAPF HANS , SCHAUM HELMUT DR , SCHENK FRIEDRICH
IPC: B01J27/00 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/235 , C07C53/08 , C07C67/00 , C07C51/285
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公开(公告)号:CA1052315A
公开(公告)日:1979-04-10
申请号:CA219962
申请日:1975-02-13
Applicant: HOECHST AG
Inventor: SARTORIUS RUDOLF , STAPF HANS
Abstract: PROCESS FOR PREPARING TECHNICALLY PURE ACETIC ACID BY EXTRACTIVE DISTILLATION of the disclosure: Process for preparing technically pure acetic acid from water - acetic acid mixtures by extractive distillation with N-methyl acetamide.
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公开(公告)号:DE2658043A1
公开(公告)日:1978-06-29
申请号:DE2658043
申请日:1976-12-22
Applicant: HOECHST AG
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公开(公告)号:CA1107758A
公开(公告)日:1981-08-25
申请号:CA293780
申请日:1977-12-22
Applicant: HOECHST AG
Inventor: SARTORIUS RUDOLF , STAPF HANS , SCHAUM HELMUT , SCHENK FRIEDRICH
Abstract: PROCESS FOR THE MANUFACTURE OF ACETIC ACID of the disclosure: Acetic acid is produced by oxidizing acetaldehyde at elevated temperature in the liquid phase using oxygen or gases containing oxygen in the presence of one or more heavy metal compounds as the catalyst, and adding to the reaction mixture at the start of the addition of oxygen one or more organic peroxides which under the reaction conditions decompose, with a half-life up to 350 minutes, into free radicals in order to initiate the reaction.
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公开(公告)号:DE2459761A1
公开(公告)日:1976-07-01
申请号:DE2459761
申请日:1974-12-18
Applicant: HOECHST AG
Inventor: SARTORIUS RUDOLF DR , STARCK DIETER DR , STAPF HANS
IPC: B01J23/94 , C07C29/141 , C07C29/145
Abstract: The reactivation of hydrogenation catalysts contg. Cu and opt. Cr is achieved by treating with aq. NH3 soln and then washing NH3-free with H2O. Treatment pref. is carried out with 1-5 wt.% NH2 soln. at temps. below 50 degrees C and pref. takes place in the hydrogenation zone itself. For the reactivation of catalysts used in the gas phase hydrogenation of aldehydes and ketones to the corresp. alcohols. The process is simple and has technical and economical advantages, esp. when used for in situ reactivation. The catalyst is fully reactivated.
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公开(公告)号:DE2408011A1
公开(公告)日:1975-09-04
申请号:DE2408011
申请日:1974-02-20
Applicant: HOECHST AG
Inventor: SARTORIUS RUDOLF DR , STAPF HANS
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