公开(公告)号：CA1101889A

公开(公告)日：1981-05-26

申请号：CA258464

申请日：1976-08-05

Applicant: HOECHST AG

Inventor： STRAUSS JULIUS ,  HUEBNER HERBERT ,  MUELLER HEINZ ,  KREMPL ENGELBERT

IPC: C07B61/00 ,  B01J19/18 ,  B01J23/00 ,  B01J23/72 ,  B01J23/86 ,  C07C67/00 ,  C07C209/00 ,  C07C209/14 ,  C07C209/16 ,  C07C209/26 ,  C07C211/03 ,  C07C211/08 ,  C07C211/21 ,  C07C87/127 ,  C07C87/24

Abstract: PROCESS FOR THE PREPARATION OF TERTIARY ALIPHATIC AMINES of the disclosure: A process for the preparation of tertiary aliphatic amines containing an aliphatic radical having 8 to 24 carbon atoms by reacting a liquid alcohol or aldehyde having 8 to 24 carbon atoms in the presence of a cobalt- and/or copper-chromium oxide catalyst with a gaseous mixture of hydrogen and a lower primary or secondary alkyl amine having at least one methyl group, the amine proportion of the gas mixture being in the range of from 1 to 20 % by volume, eliminating the water having been formed in the reaction from the exhaust gas, and recirculating the exhaust gas continuously back into the liquid alcohol or aldehyde.

公开(公告)号：CH622237A5

公开(公告)日：1981-03-31

申请号：CH990876

申请日：1976-08-03

Applicant: HOECHST AG

Inventor： STRAUSS JULIUS ,  HUEBNER HERBERT DR ,  MUELLER HEINZ DR ,  KREMPL ENGELBERT

IPC: C07B61/00 ,  B01J19/18 ,  B01J23/00 ,  B01J23/72 ,  B01J23/86 ,  C07C67/00 ,  C07C209/00 ,  C07C209/14 ,  C07C209/16 ,  C07C209/26 ,  C07C211/03 ,  C07C211/08 ,  C07C211/21 ,  C07C85/08 ,  C07C87/127

公开(公告)号：NO142709C

公开(公告)日：1980-10-01

申请号：NO762730

申请日：1976-08-05

Applicant: HOECHST AG

Inventor： STRAUSS JULIUS ,  HUEBNER HERBERT ,  MUELLER HEINZ ,  KREMPL ENGELBERT

IPC: C07B61/00 ,  B01J19/18 ,  B01J23/00 ,  B01J23/72 ,  B01J23/86 ,  C07C67/00 ,  C07C209/00 ,  C07C209/14 ,  C07C209/16 ,  C07C209/26 ,  C07C211/03 ,  C07C211/08 ,  C07C211/21 ,  C07C87/127 ,  C07C85/06

公开(公告)号：NO142709B

公开(公告)日：1980-06-23

申请号：NO762730

申请日：1976-08-05

Applicant: HOECHST AG

Inventor： STRAUSS JULIUS ,  HUEBNER HERBERT ,  MUELLER HEINZ ,  KREMPL ENGELBERT

IPC: C07B61/00 ,  B01J19/18 ,  B01J23/00 ,  B01J23/72 ,  B01J23/86 ,  C07C67/00 ,  C07C209/00 ,  C07C209/14 ,  C07C209/16 ,  C07C209/26 ,  C07C211/03 ,  C07C211/08 ,  C07C211/21 ,  C07C87/127 ,  C07C85/06

公开(公告)号：FI62822B

公开(公告)日：1982-11-30

申请号：FI762223

申请日：1976-08-04

Applicant: HOECHST AG

Inventor： STRAUSS JULIUS ,  HUEBNER HERBERT ,  MUELLER HEINZ ,  KREMPL ENGELBERT

IPC: C07B61/00 ,  B01J19/18 ,  B01J23/00 ,  B01J23/72 ,  B01J23/86 ,  C07C67/00 ,  C07C209/00 ,  C07C209/14 ,  C07C209/16 ,  C07C209/26 ,  C07C211/03 ,  C07C211/08 ,  C07C211/21 ,  C07C85/08 ,  C07C87/127

公开(公告)号：DE2535073A1

公开(公告)日：1977-02-17

申请号：DE2535073

申请日：1975-08-06

Applicant: HOECHST AG

Inventor： STRAUSS JULIUS ,  HUEBNER HERBERT DR ,  MUELLER HEINZ DR ,  KREMPL ENGELBERT

IPC: C07B61/00 ,  B01J19/18 ,  B01J23/00 ,  B01J23/72 ,  B01J23/86 ,  C07C67/00 ,  C07C209/00 ,  C07C209/14 ,  C07C209/16 ,  C07C209/26 ,  C07C211/03 ,  C07C211/08 ,  C07C211/21 ,  C07C87/127 ,  C07C85/08

公开(公告)号：FI762223A

公开(公告)日：1977-02-07

申请号：FI762223

申请日：1976-08-04

Applicant: HOECHST AG

Inventor： STRAUSS JULIUS ,  HUEBNER HERBERT ,  MUELLER HEINZ ,  KREMPL ENGELBERT

IPC: C07B61/00 ,  B01J19/18 ,  B01J23/00 ,  B01J23/72 ,  B01J23/86 ,  C07C67/00 ,  C07C209/00 ,  C07C209/14 ,  C07C209/16 ,  C07C209/26 ,  C07C211/03 ,  C07C211/08 ,  C07C211/21 ,  C07C

公开(公告)号：ES2087223T3

公开(公告)日：1996-07-16

申请号：ES91121361

申请日：1991-12-12

Applicant: HOECHST AG

Inventor： FRUTH ANTON ,  STRAUSS JULIUS ,  STUHLER HERBERT DR

IPC: B01J25/02 ,  C07B61/00 ,  C07C209/48 ,  C07C209/70 ,  C07C211/03

Abstract: According to the new process, the hydrogenation of unsaturated fatty acid nitriles or mixtures of unsaturated and saturated fatty acid nitriles is carried out in the liquid phase in the presence of nickel catalysts or cobalt catalysts. In a first reaction step the fatty acid nitrile, in the presence of ammonia, is treated with hydrogenation hydrogen until all the nitrile groups are hydrogenated to predominantly primary amino groups. After the ammonia content in the reaction mixture obtained from the first step has been adjusted to a value of at most 0.1 mol of ammonia per mole of fatty acid nitrile used, a second reaction step is used to hydrogenate the double bonds present to saturated bonds. The desired primary and saturated fatty amine is obtained in a very high yield and has an iodine number of at most 5.

公开(公告)号：DE59107578D1

公开(公告)日：1996-04-25

申请号：DE59107578

申请日：1991-12-12

Applicant: HOECHST AG

Inventor： FRUTH ANTON ,  STRAUSS JULIUS ,  STUEHLER HERBERT DR

IPC: B01J25/02 ,  C07B61/00 ,  C07C209/48 ,  C07C209/70 ,  C07C211/03

Abstract: According to the new process, the hydrogenation of unsaturated fatty acid nitriles or mixtures of unsaturated and saturated fatty acid nitriles is carried out in the liquid phase in the presence of nickel catalysts or cobalt catalysts. In a first reaction step the fatty acid nitrile, in the presence of ammonia, is treated with hydrogenation hydrogen until all the nitrile groups are hydrogenated to predominantly primary amino groups. After the ammonia content in the reaction mixture obtained from the first step has been adjusted to a value of at most 0.1 mol of ammonia per mole of fatty acid nitrile used, a second reaction step is used to hydrogenate the double bonds present to saturated bonds. The desired primary and saturated fatty amine is obtained in a very high yield and has an iodine number of at most 5.

公开(公告)号：BR9105358A

公开(公告)日：1992-08-25

申请号：BR9105358

申请日：1991-12-12

Applicant: HOECHST AG

Inventor： FRUTH ANTON ,  STRAUSS JULIUS ,  STUEHLER HERBERT DR

IPC: B01J25/02 ,  C07B61/00 ,  C07C209/70 ,  C07C211/03 ,  C07C211/07