公开(公告)号：KR20180006399A

公开(公告)日：2018-01-17

申请号：KR20177034809

申请日：2016-04-25

Applicant: HONEYWELL INT INC

Inventor： COTTRELL STEPHEN A ,  CERRI GUSTAVO ,  CHIU YUON ,  MCCLAINE JENNIFER W

IPC: C07C17/21 ,  C07C17/20 ,  C07C19/08

CPC classification number: C07C17/21 ,  C07C17/208 ,  Y02P20/125 ,  C07C19/08

Abstract: 트랜스 HCFO-1233zd(E)의제조방법으로부터달리사용할수 없는부산물을 HFC-245fa의제조방법에도입함으로써가치있는생성물로전환되는방법이개시된다. 상기방법은 HCFO-1233zd 생산부산물을포함하는반응혼합물의촉매적하이드로플루오르화를포함한다.

Abstract translation: 其中开关不是副产物的方法，可作为在由反式HCFO-1233zd的（E）的一个不同的生产方法引进到的HFC-245fa的制造方法的有价值的产品被公开。 该方法包括对包含HCFO-1233zd生产副产物的反应混合物进行催化氢氟化。

公开(公告)号：KR20180006404A

公开(公告)日：2018-01-17

申请号：KR20177035339

申请日：2016-04-25

Applicant: HONEYWELL INT INC

Inventor： WANG HAIYOU ,  TUNG HSUEH SUNG ,  COTTRELL STEPHEN A

IPC: C07C17/25 ,  C07C21/18

CPC classification number: C07C17/25 ,  C07C21/18

Abstract: 테트라클로로플루오로프로페인들, 트라이클로로다이플루오로프로페인들, 다이클로로트라이플루오로프로페인들또는이들의혼합물을포함하는프로페인공급원료를고체촉매의존재하에서반응시키는것을포함하는 1-클로로-3,3,3-트라이플루오로프로펜(HCFO-1233zd)의제조방법이개시된다. 상기방법은일반적으로하기 4 단계들을포함한다: (i) 트라이클로로다이플루오로프로페인들및 다이클로로트라이플루오로프로페인들을포함하는프로페인공급원료를제공하는단계, (ii) 공급원료를, HCFO-1233zd 및미전환된출발물질들을포함하는생성물스트림을형성하기에효과적인조건하에서 HF의존재하에서및 고체촉매의존재하에서증기상반응기에서반응시키는단계, (iii) HCl 및 HF를회수또는제거하는단계, 및 (iv) HCFO-1233zd(E), HCFO-1233zd(Z) 또는둘다를격리시키는단계.

Abstract translation: 包括使包含四氯氟丙烷，三氯二氟丙烷，二氯三氟丙烷或其混合物的丙烯原料在固体催化剂存在下反应， -3,3,3-三氟丙烯（HCFO-1233zd）。 该方法通常包括以下四个步骤：（i）提供包含三氯二氟代丙烷和二氯三氟代丙烷的丙烷原料，（ii）使原料与原料接触， 在依赖于HF的条件下和在固体催化剂存在下，在有效形成包含HCFO-1233zd和转化的原料的产物料流的条件下，在气相反应器中反应，（iii）回收或除去HCl和HF， 和（iv）分离HCFO-1233zd（E），HCFO-1233zd（Z）或两者。

公开(公告)号：WO2012158872A3

公开(公告)日：2013-05-02

申请号：PCT/US2012038269

申请日：2012-05-17

Applicant: HONEYWELL INT INC ,  COTTRELL STEPHEN A ,  TUNG HSUEH SUNG ,  POKROVSKI KONSTANTIN A

Inventor： COTTRELL STEPHEN A ,  TUNG HSUEH SUNG ,  POKROVSKI KONSTANTIN A

IPC: C07C17/23 ,  C07C17/383 ,  C07C21/18

CPC classification number: C07C17/383 ,  C07C17/206 ,  C07C17/25 ,  C07C17/38 ,  C07C21/18 ,  Y02P20/125

Abstract: The present invention is directed to processes for the production of 1233zd from 240fa and HF, with or without a catalyst, at a commercial scale. The 240fa and HF are fed to a reactor operating at high pressure. The resulting product stream comprising 1233zd, HCl, HF, and other byproducts is treated to one or more purification techniques including phase separation and one or more distillations to provide purified 1233zd, which meets commercial product specifications, i.e., having a GC purity of 99.5% or greater.

Abstract translation: 本发明涉及以商业规模从240fa和HF生产1233zd（有或没有催化剂）的方法。 将240fa和HF进料到在高压下操作的反应器。 将包含1233zd，HCl，HF和其他副产物的所得产物流处理成一种或多种纯化技术，包括相分离和一种或多种蒸馏，以提供满足商业产品规格的纯化的1233zd，即GC纯度为99.5％ 或更大。

公开(公告)号：WO2011139591A3

公开(公告)日：2012-02-23

申请号：PCT/US2011033522

申请日：2011-04-22

Applicant: HONEYWELL INT INC ,  COOK GEORGE R ,  KOPKALLI HALUK ,  COTTRELL STEPHEN A ,  CHIU YUON ,  SCHEIDLE PETER ,  MERKEL DANIEL C

Inventor： COOK GEORGE R ,  KOPKALLI HALUK ,  COTTRELL STEPHEN A ,  CHIU YUON ,  SCHEIDLE PETER ,  MERKEL DANIEL C

IPC: C07C17/23 ,  C07C21/18

CPC classification number: C07C17/23 ,  C07C17/25 ,  C07C21/18

Abstract: A process for the manufacture of halogenated olefins in semi-batch mode by dehydrohalogenation of halogenated alkanes in the presence of an aqueous base such as KOH which simultaneously neutralizes the resulting hydrogen halide. During the process, aqueous base is continuously added to the haloalkane which results in better yields, lower by-product formation and safer/more controllable operation.

Abstract translation: 一种通过卤化烷烃在碱性水溶液（如KOH）的存在下脱卤化氢同时中和所得卤化氢，以半间歇模式制造卤代烯烃的方法。 在此过程中，将水性碱连续加入到卤代烷烃中，产生更好的产率，更低的副产物形成和更安全/更可控的操作。

公开(公告)号：WO2011025674A4

公开(公告)日：2011-05-12

申请号：PCT/US2010045416

申请日：2010-08-13

Applicant: HONEYWELL INT INC ,  KOPKALLI HALUK ,  CHIU YUON ,  RODRIGUES ORLANDO GEORGE ,  CERRI GUS ,  TUNG HSUEH SUNG ,  COTTRELL STEPHEN A

Inventor： KOPKALLI HALUK ,  CHIU YUON ,  RODRIGUES ORLANDO GEORGE ,  CERRI GUS ,  TUNG HSUEH SUNG ,  COTTRELL STEPHEN A

IPC: B01J8/06 ,  C07C17/354 ,  C07C19/08

CPC classification number: B01J8/067 ,  B01J2208/00849 ,  B01J2208/00884 ,  C07C17/354 ,  C07C19/08

Abstract: Disclosed is a process and apparatus for the catalytic hydrogenation of fluoroolefins to fluorocarbons where the reaction is carried out in a multi-tube shell and tube reactor. Reactions involving hydrogenation of fluoro-olefins are typically exothermic. In commercial processes where a fluoro-olefin C(n)H(2n-x)F(x) to C(n)H(2n-x+2)F(x) is hydrogenated (e.g. hexafluoropropylene to 236ea, 1225ye to 245eb, and the like), inadequate management or control of heat removal may induce excess hydrogenation, decomposition and hot spots resulting in reduced yields and potential safety issues. In the hydrogenation of fluoro-olefins, it is therefore necessary to control the reaction temperature as precisely as practical to overcome challenges associated with heat management and safety.

Abstract translation: 公开了将氟烯烃催化氢化成碳氟化合物的方法和装置，其中反应在多管壳管式反应器中进行。 涉及氟代烯烃氢化的反应通常是放热的。 在氟化烯烃C（n）H（2n-x）F（x）至C（n）H（2n-x + 2）F（x）被氢化（例如六氟丙烯至236ea，1225ye至245eb） ，等等），不充分的除热控制或控制可能引起过度的氢化，分解和热点，导致产量降低和潜在的安全问题。 在氟代烯烃的氢化中，因此需要精确地控制反应温度以克服与热管理和安全相关的挑战。

公开(公告)号：WO2012166836A2

公开(公告)日：2012-12-06

申请号：PCT/US2012040070

申请日：2012-05-31

Applicant: HONEYWELL INT INC ,  CLOSE JOSHUA ,  WANG HAIYOU ,  TUNG HSUEH SUNG ,  COTTRELL STEPHEN A

Inventor： CLOSE JOSHUA ,  WANG HAIYOU ,  TUNG HSUEH SUNG ,  COTTRELL STEPHEN A

IPC: B01J23/745 ,  B01J19/08 ,  B01J19/20 ,  C07C21/06

CPC classification number: B01J8/10 ,  B01J8/005 ,  B01J8/0075 ,  B01J23/745 ,  B03C1/0335 ,  B03C5/00 ,  C07C17/275 ,  C07C17/278 ,  Y02P20/584 ,  C07C19/01

Abstract: Disclosed is a method for capturing and recycling iron catalyst used in the production of haloalkane compounds and more particularly, to an improved process for the manufacture of the compound 1,1,1,3,3-pentachloropropane (HCC-240fa), in which an electromagnetic separation unit (EMSU) is used to facilitate the reaction. When energized, the EMSU functions to remove the iron particles from the reactor effluent; when de-energized, the iron particles captured by the EMSU can be flushed back into the reactor for re-use in the continued production of HCC-240fa. The present invention is also useful in the manufacturing processes for other haloalkane compounds such as HCC-250 and HCC-360.

Abstract translation: 公开了一种用于捕获和再循环用于制备卤代烷烃化合物的铁催化剂的方法，更具体地说，涉及制备化合物1,1,1,3,3-五氯丙烷（HCC-240fa）的改进方法，其中 使用电磁分离单元（EMSU）来促进反应。 当通电时，EMSU用于从反应器流出物中除去铁颗粒; 当断电时，由EMSU捕获的铁颗粒可以冲洗回反应器，以便在继续生产HCC-240fa时重新使用。 本发明也可用于其它卤代烷烃化合物如HCC-250和HCC-360的制备方法。

公开(公告)号：WO2011056441A3

公开(公告)日：2011-09-15

申请号：PCT/US2010053486

申请日：2010-10-21

Applicant: HONEYWELL INT INC ,  KOPKALLI HALUK ,  CHIU YUON ,  COTTRELL STEPHEN A ,  TUNG HSUEH SUNG ,  ULRICH KEVIN D

Inventor： KOPKALLI HALUK ,  CHIU YUON ,  COTTRELL STEPHEN A ,  TUNG HSUEH SUNG ,  ULRICH KEVIN D

IPC: C07C17/20 ,  C07C17/25 ,  C07C21/18 ,  C09K5/02

CPC classification number: C07C21/18 ,  C01B7/0718 ,  C01B7/0737 ,  C01B7/195 ,  C07C17/087 ,  C07C17/10 ,  C07C17/206 ,  C07C17/25 ,  Y02P20/125 ,  C07C19/10

Abstract: Disclosed is a process for the manufacture of HFO-1234yf from TCP in three integrated steps that include hydrofluorination of TCP (tetrachloropropene) to HCFC-1233xf in the vapor phase followed by hydrofluorination of HCFC-1233xf to HCFC-244bb in the liquid phase which is then followed by dehydrochlorination in liquid or vapor phase to produce HFO-1234yf. The vapor phase hydrofluorination is carried out at a higher pressure than the liquid phase hydrofluorination, thereby eliminating the need for compression and/or intermediate recovery. Also, any HCl generated from this reaction is fed to the liquid phase hydrofluorination section to promote agitation and mixing. This results in a more economical process from an initial capital and operating cost versus conducting the 3-steps sequentially.

Abstract translation: 公开了一种由TCP以三个整合步骤制造HFO-1234yf的方法，其包括在气相中将TCP（四氯丙烯）氢氟化为HCFC-1233xf，接着在液相中将HCFC-1233xf氢氟化为HCFC-244bb 然后在液相或汽相中进行脱氯化氢反应，生成HFO-1234yf。 气相氢氟化在比液相氢氟化更高的压力下进行，由此消除了压缩和/或中间回收的需要。 而且，由该反应产生的任何HCl被供给到液相氢氟化部分以促进搅拌和混合。 这从最初的资本和运营成本中获得了更经济的过程，而不是依次进行3个步骤。

公开(公告)号：WO2010105120A3

公开(公告)日：2011-01-13

申请号：PCT/US2010027073

申请日：2010-03-12

Applicant: HONEYWELL INT INC ,  LULY MATTHEW H ,  SMITH ROBERT A ,  NAIR HARIDASAN K ,  DEPRATO PHILIP ,  POKROVSKI KONSTANTIN A ,  MERKEL DANIEL C ,  UHRICH KEVIN ,  COTTRELL STEPHEN A ,  BRENNER DANIEL J

Inventor： LULY MATTHEW H ,  SMITH ROBERT A ,  NAIR HARIDASAN K ,  DEPRATO PHILIP ,  POKROVSKI KONSTANTIN A ,  MERKEL DANIEL C ,  UHRICH KEVIN ,  COTTRELL STEPHEN A ,  BRENNER DANIEL J

IPC: C01B25/10 ,  B01J12/00 ,  B01J19/26 ,  C01B9/08 ,  C01B25/455

CPC classification number: C01B25/10 ,  B01J4/002 ,  B01J12/00 ,  B01J19/24 ,  C01B25/455

Abstract: Processes and systems for the production of phosphorus pentafluoride (PF5) through continuous fluorination of phosphorus are provided herein. A phosphorus feed stream and a fluorine feed stream are provided to a reactor, wherein they are reacted in a gas-gas or liquid-gas reaction to produce phosphorus pentafluoride (PF5). The phosphorus feed can be derived from white phosphorus or yellow phosphorus, and can be provided to the reactor as a liquid or a vapor. The fluorine can be provided to the reactor as a vapor, and preferably comprises elemental fluorine gas.

Abstract translation: 本文提供了通过连续氟化磷生产五氟化磷（PF5）的方法和系统。 将磷进料流和氟进料流提供给反应器，其中它们在气 - 气或液 - 气反应中反应以产生五氟化磷（PF 5）。 磷进料可以来自白磷或黄磷，并且可以作为液体或蒸气提供给反应器。 可以将氟作为蒸气提供给反应器，并且优选地包含元素氟气。

公开(公告)号：WO2013106046A2

公开(公告)日：2013-07-18

申请号：PCT/US2012032698

申请日：2012-04-09

Applicant: HONEYWELL INT INC ,  THOMAS RAYMOND HILTON ,  COTTRELL STEPHEN A

Inventor： THOMAS RAYMOND HILTON ,  COTTRELL STEPHEN A

IPC: C07C17/389 ,  B01J20/18 ,  C07C21/18

CPC classification number: B01D53/70 ,  B01D2253/102 ,  B01D2253/108 ,  B01D2253/116 ,  B01D2253/308 ,  B01D2257/2066

Abstract: Disclosed is a process for removing impurities from a product stream comprising trans HFO-1234ze and an HFO-1234 impurity that uses one or more adsorbents that are selective for the HFO-1234 impurity, such that the HFO-1234 impurity is removed from the product stream. One such impurity is HFO-1234zc, which is removed from its mixture with trans HFO-1234ze by action of an adsorbent having pores in the range of from about 5 angstroms to about 10 angstroms.

Abstract translation: 公开了一种从包含反式HFO-1234ze和HFO-1234杂质的产物流中除去杂质的方法，所述HFO-1234ze和HFO-1234杂质使用对HFO-1234杂质具有选择性的一种或多种吸附剂，使得HFO-1234杂质从产物中去除 流。 一种这样的杂质是HFO-1234zc，其通过具有约5埃至约10埃范围内孔的吸附剂的作用从其与反式HFO-1234ze的混合物中除去。

公开(公告)号：WO2013048859A3

公开(公告)日：2013-06-27

申请号：PCT/US2012056269

申请日：2012-09-20

Applicant: HONEYWELL INT INC

Inventor： CHIU YUON ,  HORWATH RICHARD DURICK ,  COTTRELL STEPHEN A

IPC: C01B7/19 ,  B01J19/24

CPC classification number: C01B7/195

Abstract: Disclosed are methods used to remove HF from a fluorocarbon containing stream, thereby forming a final aqueous HF solution having both a high HF concentration and low dissolved organic content.

Abstract translation: 公开了用于从含碳氟化合物流中除去HF的方法，从而形成具有高HF浓度和低溶解有机物含量的最终HF水溶液。