公开(公告)号：KR20180055912A

公开(公告)日：2018-05-25

申请号：KR20187013311

申请日：2016-10-14

Applicant: HONEYWELL INT INC

Inventor： KOPKALLI HALUK ,  ROOF RON JOSEPH ,  CHIU YUON ,  TUNG HSUEH SUNG ,  SMITH ROBERT A

IPC: B01J8/06 ,  B01J8/02 ,  B01J23/72 ,  B01J23/745 ,  B01J23/755 ,  C07C17/23 ,  C07C17/42

CPC classification number: B01J8/02 ,  B01J8/06 ,  B01J23/745 ,  B01J23/755 ,  C07C17/25 ,  Y02P20/582 ,  C07C21/18

Abstract: 본발명은, 반응챔버에서반응물과접촉하는촉매면을갖는반응챔버; 및상기촉매면을통해전류를통과시키기위한전원을포함하는반응기를제공한다. 본반응기는 HCFC-244bb의 HFO-1234yf로의탈염화수소와같은탈할로겐화수소반응에그리고촉매작용에 0가금속이사용되는반응에사용될수 있다. 본발명은또한전기로가열되는반응챔버를사용하여 HCFC-244bb로부터 HFO-1234yf를제조하는방법을제공한다.

公开(公告)号：WO2015120427A3

公开(公告)日：2015-12-30

申请号：PCT/US2015015126

申请日：2015-02-10

Applicant: HONEYWELL INT INC

Inventor： KOPKALLI HALUK ,  CHIU YUON ,  MERKEL DANIEL C ,  ROOF RON JOSEPH ,  SMITH ROBERT A ,  PRANKE AUSTIN V

IPC: B01J8/22 ,  C07C17/20

CPC classification number: C07C17/087 ,  B01F7/00041 ,  B01F15/00837 ,  B01F2015/00097 ,  B01J4/001 ,  B01J8/22 ,  B01J10/00 ,  B01J12/00 ,  B01J19/006 ,  B01J19/0066 ,  B01J19/02 ,  B01J19/18 ,  B01J19/248 ,  B01J2208/00212 ,  B01J2219/00094 ,  B01J2219/00768 ,  B01J2219/0218 ,  B01J2219/0245 ,  B01J2219/2404 ,  B01J2219/2406 ,  B01J2219/2408 ,  B01J2219/2419 ,  B01J2219/2481 ,  B01J2219/2487 ,  C07C17/206 ,  C07C17/25 ,  C07C19/10 ,  C07C21/18

Abstract: A reactor apparatus is provided having a reaction chamber; a compartmentalizing apparatus including a plurality of compartments, each compartment being open at a top end and bottom end, the compartmentalizing apparatus being disposed within the reaction chamber; and an inlet disposed at an area of the reactor and in fluid communication between the reaction chamber and a feed source. Also provided is a reactor apparatus having an assembly having a reaction chamber; at least one agitator assembly configured to generate mixing within the reaction chamber, the agitator assembly including: a shaft partially lined or coated with a fluoropolymer or other non-metallic corrosion-resistant material, and an impeller lined or coated with the fluoropolymer or other non-metallic corrosion-resistant material; and an inlet disposed at an area of the reactor and in fluid communication between the reaction chamber and a feed source. The provided reactor apparatus can be utilized in hydrofluorination processes.

Abstract translation: 提供具有反应室的反应器装置; 一个分隔设备，包括多个隔间，每个隔室在顶端和底端开口，隔间设备设置在反应室内; 以及设置在反应器的区域并且在反应室和进料源之间流体连通的入口。 还提供了具有具有反应室的组件的反应器装置; 至少一个搅拌器组件被配置为在反应室内产生混合，所述搅拌器组件包括：部分衬里或涂覆有含氟聚合物或其它非金属耐腐蚀材料的轴，以及内衬或涂覆有氟聚合物或其它非 - 金属耐腐蚀材料; 以及设置在反应器的区域并且在反应室和进料源之间流体连通的入口。 提供的反应器装置可用于氢氟化方法。

公开(公告)号：EP3104964A4

公开(公告)日：2018-02-14

申请号：EP15746654

申请日：2015-02-10

Applicant: HONEYWELL INT INC

Inventor： KOPKALLI HALUK ,  CHIU YUON ,  MERKEL DANIEL C ,  ROOF RON JOSEPH ,  SMITH ROBERT A ,  PRANKE AUSTIN V

IPC: B01J8/22 ,  C07C17/20

CPC classification number: C07C17/087 ,  B01F7/00041 ,  B01F15/00837 ,  B01F2015/00097 ,  B01J4/001 ,  B01J8/22 ,  B01J10/00 ,  B01J12/00 ,  B01J19/006 ,  B01J19/0066 ,  B01J19/02 ,  B01J19/18 ,  B01J19/248 ,  B01J2208/00212 ,  B01J2219/00094 ,  B01J2219/00768 ,  B01J2219/0218 ,  B01J2219/0245 ,  B01J2219/2404 ,  B01J2219/2406 ,  B01J2219/2408 ,  B01J2219/2419 ,  B01J2219/2481 ,  B01J2219/2487 ,  C07C17/206 ,  C07C17/25 ,  C07C19/10 ,  C07C21/18

Abstract: A reactor apparatus is provided having a reaction chamber; a compartmentalizing apparatus including a plurality of compartments, each compartment being open at a top end and bottom end, the compartmentalizing apparatus being disposed within the reaction chamber; and an inlet disposed at an area of the reactor and in fluid communication between the reaction chamber and a feed source. Also provided is a reactor apparatus having an assembly having a reaction chamber; at least one agitator assembly configured to generate mixing within the reaction chamber, the agitator assembly including: a shaft partially lined or coated with a fluoropolymer or other non-metallic corrosion-resistant material, and an impeller lined or coated with the fluoropolymer or other non-metallic corrosion-resistant material; and an inlet disposed at an area of the reactor and in fluid communication between the reaction chamber and a feed source. The provided reactor apparatus can be utilized in hydrofluorination processes.

公开(公告)号：EP2970052A4

公开(公告)日：2016-11-02

申请号：EP14768936

申请日：2014-03-13

Applicant: HONEYWELL INT INC

Inventor： KOPKALLI HALUK ,  MERKEL DANIEL C ,  ROOF RON JOSEPH

IPC: C07C17/04 ,  C07C17/38 ,  C07C19/12

CPC classification number: C07C17/08 ,  C07C17/087 ,  C07C17/206 ,  C07C17/23 ,  C07C17/25 ,  C07C19/10 ,  C07C21/18 ,  C07C19/08

公开(公告)号：FI2970052T3

公开(公告)日：2024-09-11

申请号：FI14768936

申请日：2014-03-13

Applicant: HONEYWELL INT INC

Inventor： KOPKALLI HALUK ,  MERKEL DANIEL C ,  ROOF RON JOSEPH

IPC: C07C17/04 ,  C07C17/38 ,  C07C19/12

Abstract: The invention relates to a process to produce HCFC-244bb from HCFO-1233xf wherein, in one embodiment, one or more co-feed species having a normal boiling point of between about -80°C to about 0°C, such as HFC-245cb, is added to the reaction at a pressure of at least about 100 psig; and in another embodiment it is added to maintain a mole ratio of HFC-245cb to HCFO- 1233xf of between about 0.005:1 to about 1:1. The HFC-245cb may be added as recycled by-product of the reaction and/or added as fresh feed. The HFC-245cb provides elevated pressures to the reaction thereby facilitating reactor operation, mixing and HCFC-244bb product removal. Other co-feed species are also disclosed.

公开(公告)号：PL2970052T3

公开(公告)日：2024-12-09

申请号：PL14768936

申请日：2014-03-13

Applicant: HONEYWELL INT INC

Inventor： KOPKALLI HALUK ,  MERKEL DANIEL C ,  ROOF RON JOSEPH

IPC: C07C17/04 ,  C07C17/38 ,  C07C19/12

公开(公告)号：DK2970052T3

公开(公告)日：2024-09-23

申请号：DK14768936

申请日：2014-03-13

Applicant: HONEYWELL INT INC

Inventor： KOPKALLI HALUK ,  MERKEL DANIEL C ,  ROOF RON JOSEPH

IPC: C07C17/04 ,  C07C17/38 ,  C07C19/12

公开(公告)号：HUE068290T2

公开(公告)日：2024-12-28

申请号：HUE14768936

申请日：2014-03-13

Applicant: HONEYWELL INT INC

Inventor： KOPKALLI HALUK ,  MERKEL DANIEL C ,  ROOF RON JOSEPH

IPC: C07C17/04 ,  C07C17/38 ,  C07C19/12

公开(公告)号：HRP20241219T1

公开(公告)日：2024-12-06

申请号：HRP20241219

申请日：2014-03-13

Applicant: HONEYWELL INT INC

Inventor： KOPKALLI HALUK ,  MERKEL DANIEL C ,  ROOF RON JOSEPH

IPC: C07C17/04 ,  C07C17/38 ,  C07C19/12

公开(公告)号：MX2015011268A

公开(公告)日：2015-12-03

申请号：MX2015011268

申请日：2014-03-13

Applicant: HONEYWELL INT INC

Inventor： MERKEL DANIEL C ,  KOPKALLI HALUK ,  ROOF RON JOSEPH

IPC: C07C17/04 ,  C07C17/38 ,  C07C19/12

Abstract: La invención se refiere a un proceso para producir HCFC-244bb de HCFO-1233xf en donde, en una modalidad, una o más especies de co-alimentación que tienen un punto de ebullición normal de entre aproximadamente -80 °C a aproximadamente O °C, tales como HFC -245cb, se añade a la reacción a una presión de al menos aproximadamente 0.68 MPa; y en otra modalidad se añade a mantener una relación en moles de HFC-245cb a HCFO-1233xf de entre aproximadamente 0.005: 1 a aproximadamente 1: 1. El HFC-245cb se puede añadir como reciclado de subproductos de la reacción y/o añadido a la alimentación fresca. El HFC-245cb ofrece presiones elevadas a la reacción facilitando de este modo el funcionamiento del reactor, el mezclado y el retiro del producto HCFC-244bb. También se describen otras especies co-alimentadas.