公开(公告)号：US12054596B2

公开(公告)日：2024-08-06

申请号：US17532510

申请日：2021-11-22

Applicant: Honeywell International Inc.

Inventor： Bin Yu ,  Hang T. Pham

IPC: C08J9/12 ,  C08J9/14

CPC classification number: C08J9/127 ,  C08J9/125 ,  C08J9/144 ,  C08J2203/10 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2375/04

Abstract: Heterogeneous azeotrope or azeotrope-like compositions comprising Z-1-chloro-2,3,3,3-tetrafluoropropene (HCFO-1224yd(Z)) and water which may include from about 47.0 wt. % to about 99.7 wt. % Z-1-chloro-2,3,3,3-tetrafluoropropene (HCFO-1224yd(Z)) and from about 0.3 wt. % to about 53.0 wt. % water and having a boiling point between about 13.0° C. and about 14.0° C. at a pressure of between about 14.0 psia and about 15.0 psia. The azeotrope or azeotrope-like compositions may be used to as blowing agents in the formation of foams.

公开(公告)号：US20220169816A1

公开(公告)日：2022-06-02

申请号：US17532510

申请日：2021-11-22

Applicant: Honeywell International Inc.

Inventor： Bin Yu ,  Hang T. Pham

IPC: C08J9/12 ,  C08J9/14

Abstract: Heterogeneous azeotrope or azeotrope-like compositions comprising Z-1-chloro-2,3,3,3-tetrafluoropropene (HCFO-1224yd(Z)) and water which may include from about 47.0 wt. % to about 99.7 wt. % Z-1-chloro-2,3,3,3-tetrafluoropropene (HCFO-1224yd(Z)) and from about 0.3 wt. % to about 53.0 wt. % water and having a boiling point between about 13.0° C. and about 14.0° C. at a pressure of between about 14.0 psia and about 15.0 psia. The azeotrope or azeotrope-like compositions may be used to as blowing agents in the formation of foams.

公开(公告)号：US20210032430A1

公开(公告)日：2021-02-04

申请号：US17068279

申请日：2020-10-12

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Bin Yu ,  David J. Williams

IPC: C08J9/14 ,  C08J9/02 ,  C08G18/50 ,  C08G18/76 ,  C08G18/16 ,  C08G18/18 ,  C08G18/22 ,  C08G18/40 ,  C08G18/42 ,  C08G18/48

Abstract: Disclosed are polyol premix compositions, and foams formed therefrom, which comprise a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a catalyst system that includes a bismuth-based metal catalyst. Such catalysts may be used alone or in combination with an amine catalyst and/or other non-amine catalysts.

公开(公告)号：US20190185635A1

公开(公告)日：2019-06-20

申请号：US16148531

申请日：2018-10-01

Applicant: Honeywell International Inc.

Inventor： Bin Yu ,  Mary C. Bogdan ,  Clifford B. Gittere ,  Michael Ross ,  Ronald S. Grossman ,  David J. Williams

IPC: C08J9/14 ,  C08G18/40 ,  C08G18/76 ,  C08G18/16 ,  C08J9/02 ,  C08G18/48 ,  C08G18/42 ,  C08G18/50 ,  C08G18/22 ,  C08G18/18

CPC classification number: C08J9/146 ,  C08G18/163 ,  C08G18/1808 ,  C08G18/1816 ,  C08G18/222 ,  C08G18/227 ,  C08G18/4018 ,  C08G18/4208 ,  C08G18/482 ,  C08G18/5021 ,  C08G18/7664 ,  C08G2101/00 ,  C08J9/02 ,  C08J9/144 ,  C08J2201/022 ,  C08J2203/162 ,  C08J2375/04

Abstract: The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a precipitation-resistant metal-based catalyst used alone or in combination with an amine catalyst.

公开(公告)号：US20190085145A1

公开(公告)日：2019-03-21

申请号：US16135269

申请日：2018-09-19

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Bin Yu ,  Mary C. Bogdan ,  David John Williams ,  Yiu Keung Ling

IPC: C08J9/02 ,  C08J9/14

Abstract: This invention relates to thermoset, thermal insulating panel, pour-in-place and pour-in-place foams having desirable and unexpectedly low thermal conductivity, and to compositions, method and systems which use and/or are used to make such foams comprising: (a) providing thermosetting foam forming component and a blowing agent for forming predominantly closed cells in the foam, wherein the blowing agent comprises: (i) cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336mzzm(Z)) and cyclopentane, with the HFO-1336mzzm(Z) and cyclopentane in the blowing agent together comprising at least about 50% by weight of the total of all components in the blowing agent and (ii) the weight ratio of HFO-1336mzzm(Z) to cyclopentane in the blowing agent is from about 45:55 to less than 68:32 and (b) forming foam from said provided foamable composition.

公开(公告)号：US20170355893A1

公开(公告)日：2017-12-14

申请号：US15606582

申请日：2017-05-26

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Yiu K. Ling ,  Mary C. Bogdan ,  Bin Yu ,  David J. Wilkes ,  David J. Williams

IPC: C09K3/30 ,  C11D7/50 ,  A23L27/10 ,  C11D3/24 ,  C11D7/26 ,  C08J9/12 ,  C11D7/24 ,  C08G18/76 ,  A01N27/00 ,  C08G18/40 ,  C08G18/08 ,  A23L27/20 ,  C09K5/04 ,  C09K21/08 ,  C10M131/04 ,  A62D1/00 ,  C11D7/02 ,  A01N59/00 ,  C08J9/14 ,  A01N29/02 ,  C11B9/02 ,  C10M171/00 ,  A01N35/02 ,  A01N31/02

CPC classification number: C09K3/30 ,  A01N27/00 ,  A01N29/02 ,  A01N31/02 ,  A01N35/02 ,  A01N59/00 ,  A01N2300/00 ,  A23L27/11 ,  A23L27/202 ,  A23V2002/00 ,  A62D1/0057 ,  C08G18/14 ,  C08G18/163 ,  C08G18/18 ,  C08G18/225 ,  C08G18/4018 ,  C08G18/4208 ,  C08G18/4816 ,  C08G18/4883 ,  C08G18/5021 ,  C08G18/7664 ,  C08G2101/0025 ,  C08J9/127 ,  C08J9/141 ,  C08J9/144 ,  C08J9/146 ,  C08J9/149 ,  C08J2201/022 ,  C08J2203/14 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2203/184 ,  C08J2205/052 ,  C08J2205/08 ,  C08J2205/10 ,  C08J2375/04 ,  C08J2375/08 ,  C09K5/044 ,  C09K5/045 ,  C09K21/08 ,  C09K2205/112 ,  C09K2205/12 ,  C09K2205/22 ,  C10M131/04 ,  C10M171/008 ,  C10M2211/022 ,  C10N2240/30 ,  C11B9/025 ,  C11D3/245 ,  C11D7/02 ,  C11D7/24 ,  C11D7/263 ,  C11D7/264 ,  C11D7/5018

Abstract: Disclosed is a thermoset, thermal insulating foams having desirable and unexpectedly low thermal conductivity, and to compositions, method and systems which use and/or are used to make such foams comprising: (a) providing thermosetting foam forming component and a blowing agent for forming predominantly closed cells in the foam, wherein the blowing agent comprises: (i) cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336mzzm(Z)) and cyclopentane, with the HFO-1336mzzm(Z) and cyclopentane in the blowing agent together comprising at least about 50% by weight of the total of all components in the blowing agent and (ii) the weight ratio of HFO-1336mzzm(Z) to cyclopentane in the blowing agent is from about 45:55 to less than 68:32 and (b) forming foam from said provided foamable composition.

公开(公告)号：US20230110847A1

公开(公告)日：2023-04-13

申请号：US17943110

申请日：2022-09-12

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Bin Yu ,  Ryan Hulse

IPC: C08G18/42 ,  C08G18/08 ,  C08J9/14 ,  C08G18/22 ,  C08G18/18 ,  C08G18/16 ,  C08J9/00

Abstract: Disclosed are methods of forming foam comprising: (a) providing a foamable composition comprising an isocyanate, a polyol and a physical blowing agent comprising at least about 50% by weight of hydrohaloolefin, including trans1233zd, and wherein the polyol comprises a polyol or mixture of polyols such that the hydrohaloolefin, including trans1233zd, has a solubility in said polyol of less than about 30%; and (b) forming a foam from said foamable composition.

公开(公告)号：US20200247941A1

公开(公告)日：2020-08-06

申请号：US16777962

申请日：2020-01-31

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Bin Yu ,  Ryan Hulse

IPC: C08G18/42 ,  C08G18/08 ,  C08G18/18 ,  C08J9/00 ,  C08J9/14 ,  C08G18/22 ,  C08G18/16

Abstract: Disclosed are methods of forming foam comprising: (a) providing a foamable composition comprising an isocyanate, a polyol and a physical blowing agent comprising at least about 50% by weight of hydrohaloolefin, including trans1233zd, and wherein the polyol comprises a polyol or mixture of polyols such that the hydrohaloolefin, including trans1233zd, has a solubility in said polyol of less than about 30%; and (b) forming a foam from said foamable composition.

公开(公告)号：US20140171525A1

公开(公告)日：2014-06-19

申请号：US14187633

申请日：2014-02-24

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Bin Yu ,  David J. Williams

IPC: C08G18/06

CPC classification number: C08J9/146 ,  C08G18/163 ,  C08G18/1808 ,  C08G18/1816 ,  C08G18/222 ,  C08G18/227 ,  C08G18/4018 ,  C08G18/4208 ,  C08G18/482 ,  C08G18/5021 ,  C08G18/7664 ,  C08G2101/00 ,  C08J9/02 ,  C08J9/144 ,  C08J2201/022 ,  C08J2203/162 ,  C08J2375/04

Abstract: Disclosed are polyol premix compositions, and foams formed therefrom, which comprise a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a catalyst system that includes a bismuth-based metal catalyst. Such catalysts may be used alone or in combination with an amine catalyst and/or other non-amine catalysts.

Abstract translation: 公开了多元醇预混物组合物和由其形成的泡沫，其包含氢卤烯烃发泡剂，多元醇，硅氧烷表面活性剂和包含铋基金属催化剂的催化剂体系的组合。 这样的催化剂可以单独使用或与胺催化剂和/或其它非胺催化剂组合使用。

公开(公告)号：US20250084200A1

公开(公告)日：2025-03-13

申请号：US18886546

申请日：2024-09-16

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Bin Yu ,  Ryan Hulse

IPC: C08G18/42 ,  C08G18/08 ,  C08G18/16 ,  C08G18/18 ,  C08G18/22 ,  C08J9/00 ,  C08J9/14

Abstract: Disclosed are methods of forming foam comprising: (a) providing a foamable composition comprising an isocyanate, a polyol and a physical blowing agent comprising at least about 50% by weight of hydrohaloolefin, including trans1233zd, and wherein the polyol comprises a polyol or mixture of polyols such that the hydrohaloolefin, including trans1233zd, has a solubility in said polyol of less than about 30%; and (b) forming a foam from said foamable composition.