公开(公告)号：BR8801120A

公开(公告)日：1988-10-18

申请号：BR8801120

申请日：1988-03-11

Applicant: IBM

Inventor： BEYERS ROBERT BRUCE ,  ENGLER EDWARD MARTIN ,  GRANT PAUL MICHAEL ,  LIM GRACE SU ,  PARKIN STUART STEPHEN PAPWORTH

IPC: C01G1/00 ,  C01G3/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/00 ,  H01B13/00 ,  H01L39/12 ,  H01L39/24

Abstract: Compositions having the formula A1+/-xM2+/-xCu3Oy, wherein A is Y, or a combination of Y La, Lu, Sc or Yb; M is Ba, or a combination of Ba, Sr or Ca and y is sufficient to satisfy the valence demands, have been found to be bulk electrical superconductors at a temperature above 77K. The compositions are single phase perovskite-like crystalline structures. They are made by a process involving intimately mixing the metal oxides or their precursors in the proper molar ratios, heating the mixture in the presence of oxygen to a temperature between about 800 DEG C and about 1100 DEG C and slowly cooling the mixture to room temperature in the presence of oxygen over a period of at least four hours.

公开(公告)号：HK1004302A1

公开(公告)日：1998-11-20

申请号：HK98103445

申请日：1998-04-24

Applicant: IBM

Inventor： BEYERS ROBERT BRUCE ,  ENGLER EDWARD MARTIN ,  GRANT PAUL MICHAEL ,  LIM GRACE SU ,  PARKIN STUART STEPHEN PAPWORTH

IPC: C01G1/00 ,  C01G3/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/00 ,  H01B13/00 ,  H01L39/12 ,  H01L39/24 ,  H01L ,  C04B ,  C01G

Abstract: Compositions having the formula A1+/-xM2+/-xCu3Oy, wherein A is Y, or a combination of Y La, Lu, Sc or Yb; M is Ba, or a combination of Ba, Sr or Ca and y is sufficient to satisfy the valence demands, have been found to be bulk electrical superconductors at a temperature above 77K. The compositions are single phase perovskite-like crystalline structures. They are made by a process involving intimately mixing the metal oxides or their precursors in the proper molar ratios, heating the mixture in the presence of oxygen to a temperature between about 800 DEG C and about 1100 DEG C and slowly cooling the mixture to room temperature in the presence of oxygen over a period of at least four hours.

公开(公告)号：HK34092A

公开(公告)日：1992-05-15

申请号：HK34092

申请日：1992-05-07

Applicant: IBM

Inventor： BEYERS ROBERT BRUCE ,  ENGLER EDWARD MARTIN ,  GRANT PAUL MICHAEL ,  LIM GRACE SU ,  PARKIN STUART STEPHEN PAPWORTH

IPC: C01G1/00 ,  C01G3/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/00 ,  H01B13/00 ,  H01L39/12 ,  H01L39/24

Abstract: Compositions having the formula A1+/-xM2+/-xCu3Oy, wherein A is Y, or a combination of Y La, Lu, Sc or Yb; M is Ba, or a combination of Ba, Sr or Ca and y is sufficient to satisfy the valence demands, have been found to be bulk electrical superconductors at a temperature above 77K. The compositions are single phase perovskite-like crystalline structures. They are made by a process involving intimately mixing the metal oxides or their precursors in the proper molar ratios, heating the mixture in the presence of oxygen to a temperature between about 800 DEG C and about 1100 DEG C and slowly cooling the mixture to room temperature in the presence of oxygen over a period of at least four hours.

公开(公告)号：DE3888217T2

公开(公告)日：1994-09-22

申请号：DE3888217

申请日：1988-01-29

Applicant: IBM

Inventor： BEYERS ROBERT BRUCE ,  ENGLER EDWARD MARTIN ,  GRANT PAUL MICHAEL ,  LIM GRACE SU ,  PARKIN STUART STEPHEN PAPWORTH

IPC: C01G1/00 ,  C01G3/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/00 ,  H01B13/00 ,  H01L39/12 ,  H01L39/24

Abstract: Compositions having the formula A1+/-xM2+/-xCu3Oy, wherein A is Y, or a combination of Y La, Lu, Sc or Yb; M is Ba, or a combination of Ba, Sr or Ca and y is sufficient to satisfy the valence demands, have been found to be bulk electrical superconductors at a temperature above 77K. The compositions are single phase perovskite-like crystalline structures. They are made by a process involving intimately mixing the metal oxides or their precursors in the proper molar ratios, heating the mixture in the presence of oxygen to a temperature between about 800 DEG C and about 1100 DEG C and slowly cooling the mixture to room temperature in the presence of oxygen over a period of at least four hours.

公开(公告)号：DE3888217D1

公开(公告)日：1994-04-14

申请号：DE3888217

申请日：1988-01-29

Applicant: IBM

Inventor： BEYERS ROBERT BRUCE ,  ENGLER EDWARD MARTIN ,  GRANT PAUL MICHAEL ,  LIM GRACE SU ,  PARKIN STUART STEPHEN PAPWORTH

IPC: C01G1/00 ,  C01G3/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/00 ,  H01B13/00 ,  H01L39/12 ,  H01L39/24

Abstract: Compositions having the formula A1+/-xM2+/-xCu3Oy, wherein A is Y, or a combination of Y La, Lu, Sc or Yb; M is Ba, or a combination of Ba, Sr or Ca and y is sufficient to satisfy the valence demands, have been found to be bulk electrical superconductors at a temperature above 77K. The compositions are single phase perovskite-like crystalline structures. They are made by a process involving intimately mixing the metal oxides or their precursors in the proper molar ratios, heating the mixture in the presence of oxygen to a temperature between about 800 DEG C and about 1100 DEG C and slowly cooling the mixture to room temperature in the presence of oxygen over a period of at least four hours.

公开(公告)号：IN175115B

公开(公告)日：1995-04-29

申请号：IN168DE1988

申请日：1988-03-07

Applicant: IBM

Inventor： BEYERS ROBERT BRULE ,  ENGLER EDWARD MARTIN ,  GRANT PAUL MICHAEL ,  LIM GRALE SU

IPC: C01G1/00 ,  C01G3/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/00 ,  H01B13/00 ,  H01L39/12 ,  H01L39/24 ,  B22F1/00

Abstract: Compositions having the formula A1+/-xM2+/-xCu3Oy, wherein A is Y, or a combination of Y La, Lu, Sc or Yb; M is Ba, or a combination of Ba, Sr or Ca and y is sufficient to satisfy the valence demands, have been found to be bulk electrical superconductors at a temperature above 77K. The compositions are single phase perovskite-like crystalline structures. They are made by a process involving intimately mixing the metal oxides or their precursors in the proper molar ratios, heating the mixture in the presence of oxygen to a temperature between about 800 DEG C and about 1100 DEG C and slowly cooling the mixture to room temperature in the presence of oxygen over a period of at least four hours.

公开(公告)号：GB2201955B

公开(公告)日：1991-09-18

申请号：GB8801770

申请日：1988-01-15

Applicant: IBM

Inventor： BEYERS ROBERT BRUCE ,  ENGLER EDWARD MARTIN ,  GRANT PAUL MICHAEL ,  LIM GRACE SU ,  PARKIN STUART STEPHEN PAPWORTH

IPC: C01G1/00 ,  C01G3/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/00 ,  H01B13/00 ,  H01L39/12 ,  H01L39/24

Abstract: Compositions having the formula A1+/-xM2+/-xCu3Oy, wherein A is Y, or a combination of Y La, Lu, Sc or Yb; M is Ba, or a combination of Ba, Sr or Ca and y is sufficient to satisfy the valence demands, have been found to be bulk electrical superconductors at a temperature above 77K. The compositions are single phase perovskite-like crystalline structures. They are made by a process involving intimately mixing the metal oxides or their precursors in the proper molar ratios, heating the mixture in the presence of oxygen to a temperature between about 800 DEG C and about 1100 DEG C and slowly cooling the mixture to room temperature in the presence of oxygen over a period of at least four hours.

公开(公告)号：GB2201955A

公开(公告)日：1988-09-14

申请号：GB8801770

申请日：1988-01-15

Applicant: IBM

Inventor： BEYERS ROBERT BRUCE ,  ENGLER EDWARD MARTIN ,  GRANT PAUL MICHAEL ,  LIM GRACE SU ,  PARKIN STUART STEPHEN PAPWORTH

IPC: C01G1/00 ,  C01G3/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/00 ,  H01B13/00 ,  H01L39/12 ,  H01L39/24

Abstract: Compositions having the formula A1+/-xM2+/-xCu3Oy, wherein A is Y, or a combination of Y La, Lu, Sc or Yb; M is Ba, or a combination of Ba, Sr or Ca and y is sufficient to satisfy the valence demands, have been found to be bulk electrical superconductors at a temperature above 77K. The compositions are single phase perovskite-like crystalline structures. They are made by a process involving intimately mixing the metal oxides or their precursors in the proper molar ratios, heating the mixture in the presence of oxygen to a temperature between about 800 DEG C and about 1100 DEG C and slowly cooling the mixture to room temperature in the presence of oxygen over a period of at least four hours.