Abstract:
Provided are inorganic-organic block copolymers that self assemble without the addition of a precursor. The inorganic block of the polymers includes silicon and the organic block may be any organic polymer. The inorganic-organic block copolymers self assemble to form a material in which the inorganic polymer block may be crosslinked to produce an organosilicate and/or silica matrix, and further thermal curing of the matrix results in the formation of a porous nanostructured film.
Abstract:
Es werden anorganisch-organische Block-Copolymere bereitgestellt, die sich ohne die Hinzufügung einer Vorläuferverbindung selbst organisieren. Der anorganische Block der Polymere beinhaltet Silicium, und der organische Block kann irgendein organisches Polymer sein. Die anorganisch-organischen Block-Copolymere organisieren sich selbst, um ein Material zu bilden, in dem der anorganische Polymerblock quervernetzt werden kann, um eine Organosilicat- und/oder Siliciumdioxid-Matrix zu erzeugen, und ein weiteres thermisches Härten der Matrix resultiert in der Bildung einer porösen nanostrukturierten Dünnschicht.
Abstract:
Provided are inorganic-organic block copolymers that self assemble without the addition of a precursor. The inorganic block of the polymers includes silicon and the organic block may be any organic polymer. The inorganic-organic block copolymers self assemble to form a material in which the inorganic polymer block may be crosslinked to produce an organosilicate and/or silica matrix, and further thermal curing of the matrix results in the formation of a porous nanostructured film.
Abstract:
Provided are inorganic-organic block copolymers that self assemble without the addition of a precursor. The inorganic block of the polymers includes silicon and the organic block may be any organic polymer. The inorganic-organic block copolymers self assemble to form a material in which the inorganic polymer block may be crosslinked to produce an organosilicate and/or silica matrix, and further thermal curing of the matrix results in the formation of a porous nanostructured film.