公开(公告)号：NL103690C

公开(公告)日：1963-01-15

申请号：NL241980

申请日：1959-08-04

Applicant: INVENTA AG

Inventor： BAUMANN HANS-PETER P DR ,  BUCK ALFRED DIPL ING ,  GIESEN JOHANN DR

IPC: C07C20060101 ,  C07C45/53

公开(公告)号：AT212299B

公开(公告)日：1960-12-12

申请号：AT537459

申请日：1959-07-22

Applicant: INVENTA AG

Inventor： BAUMANN HANS-PETER P DR ,  BUCK ALFRED DIPL ING ,  GIESEN JOHANN DR

IPC: C07C20060101 ,  C07C45/53

公开(公告)号：ATA273774A

公开(公告)日：1977-12-15

申请号：AT273774

申请日：1974-04-02

Applicant: INVENTA AG

Inventor： BUCK ALFRED DIPL ING ,  RATHGEB KARL DR ING

IPC: C07C273/04 ,  C07C126/00

公开(公告)号：AT254168B

公开(公告)日：1967-05-10

申请号：AT135565

申请日：1965-02-16

Applicant: INVENTA AG

Inventor： BUCK ALFRED DIPL ING

IPC: C07C45/33

公开(公告)号：DK90173C

公开(公告)日：1960-12-27

申请号：DK260159

申请日：1959-07-21

Applicant: INVENTA AG

Inventor： BAUMANN HANS-PETER P DR ,  BUCK ALFRED DIPL ING ,  GIESEN JOHANN DR

IPC: C07C20060101 ,  C07C45/53 ,  C07C

公开(公告)号：CH387207A

公开(公告)日：1965-01-31

申请号：CH1378760

申请日：1960-12-10

Applicant: INVENTA AG

Inventor： BUCK ALFRED DIPL ING

IPC: C10G7/00

公开(公告)号：CH377807A

公开(公告)日：1964-05-31

申请号：CH6464258

申请日：1958-10-03

Applicant: INVENTA AG

Inventor： BUCK ALFRED DIPL ING

公开(公告)号：GB878066A

公开(公告)日：1961-09-27

申请号：GB2967059

申请日：1959-08-31

Applicant: INVENTA AG

Inventor： BAUMANN HANS-PETER P DR ,  BUCK ALFRED DIPL ING ,  GIESEN JOHANN DR

IPC: C07C20060101 ,  C07C45/53

Abstract: A process for the manufacture of cyclohexanone and cyclohexanol by partial oxidation of cyclohexane with molecular oxygen-containing gases at elevated temperatures and pressures in a liquid system, comprises limiting the oxidation of said cyclohexane to not more than 10% by weight calculated on the input of cyclohexane, using a retention-time in the reactor of one half to two hours and by using a gas for the oxidation containing at the most 10% by volume oxygen; decomposing the peroxides formed during oxidation; saponifying the esters formed and neutralising the acids formed during the oxidation and removing the saponified esters and neutralised acids; expanding the reaction mixture for distillation; drawing off cyclohexane vapours thus liberated and compressing them; using the heat evolved to heat the reaction mixture to be distilled; conducting part of the now liquid cyclohexane to the still head and recycling the remainder; separating the crude cyclohexanone and cyclohexanol from unreacted cyclohexane in the still bottoms and refining the cyclohexanol and cyclohexanone by fractional distillation. The continuous oxidation of cyclohexane by the above process and an apparatus therefor is described.

公开(公告)号：CH433222A

公开(公告)日：1967-04-15

申请号：CH384164

申请日：1964-03-25

Applicant: INVENTA AG

Inventor： BUCK ALFRED DIPL ING

IPC: C07C45/33 ,  C07C35/08 ,  C07C49/30

公开(公告)号：CH378873A

公开(公告)日：1964-06-30

申请号：CH6390758

申请日：1958-09-13

Applicant: INVENTA AG

Inventor： BAUMANN HANS-PETER P DR ,  BUCK ALFRED DIPL ING ,  GIESEN JOHANN DR

IPC: C07C20060101 ,  C07C45/53