公开(公告)号：US10143999B2

公开(公告)日：2018-12-04

申请号：US15525627

申请日：2015-11-11

Applicant: INVISTA NORTH AMERICA S.A R.L.

Inventor： Joan Fraga-Dubreuil ,  Vinay Medhekar ,  John A. Turner ,  Keith Whiston

IPC: B01J27/043 ,  B01J23/755 ,  B01J31/18 ,  B01J35/00 ,  B01J35/10 ,  C07F9/145 ,  C07F15/04

Abstract: Disclosed are nickel-containing complexation precursors having high complexation activity for bidentate phosphite ligands. Also disclosed are methods of making the complexation precursors. The disclosed method of generating the nickel-containing complexation precursor includes including contacting a nickel starting material with a reductant under conditions sufficient to generate a nickel-containing complexation precursor having at least about 1,500 ppmw sulfur in the form of sulfide.

公开(公告)号：US09687836B2

公开(公告)日：2017-06-27

申请号：US14669121

申请日：2015-03-26

Applicant: INVISTA North America S.a r.l.

Inventor： Joan Fraga-Dubreuil ,  Vinay Medhekar ,  Thomas A. Micka ,  Keith Whiston

IPC: C07C253/10 ,  B01J31/22 ,  B01J31/18 ,  C22B23/02 ,  B01J31/24 ,  B01J35/00 ,  B01J23/755 ,  B01J35/10

CPC classification number: B01J31/22 ,  B01J23/755 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/2409 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1009 ,  B01J2231/322 ,  B01J2531/007 ,  B01J2531/847 ,  C07C253/10 ,  C22B23/021 ,  Y10T428/2982 ,  C07C255/04

Abstract: A novel nickel particulate form is provided that efficiently forms a zero-valent nickel complex with a phosphorus-containing ligands in an organic liquid to form a hydrocyanation catalyst. Particles in the nickel particulate form comprise nickel crystallites. For example, the nickel particulate form can have a BET Specific Surface Area of at least about 1 m2/gm; an average crystallite size less than about 20-25 nm, the nickel particulate form can have at least 10% of the crystallites in the nickel form can have can have a diameter (C10) of less than about 10 nm, and/or there are on average at least about 1015 surface crystallites per gram nickel. A ratio of BET SSA to C50 for the nickel particulate form can be at least about 0.1×109 m/gm and preferably at least about 0.4×109 m/gm. Methods of preparation and use are also provided.

公开(公告)号：US20140343313A1

公开(公告)日：2014-11-20

申请号：US14354110

申请日：2012-10-15

Applicant: INVISTA NORTH AMERICA S.A R.L.

Inventor： Stewart Forsyth ,  John Arthur Turner ,  Keith Whiston ,  Thomas E. Voss

IPC: C07F9/144

CPC classification number: C07F9/144 ,  C07F9/145 ,  C07F9/146 ,  C07F9/65744

Abstract: Claimed is a process for producing a phosphorus-containing ligand, preferably a diphosphite ligand structure (DLS) such as structure I. The method includes contacting a phosphorochloridite (structure II) with a compound having the structure X—OH (which can be a bisaryl compound), and a tertiary organic amine to provide structure I′ and as preferred embodiment structure I.

Abstract translation: 要求的是制备含磷配体，优选二亚磷酸酯配体结构（DLS）如结构I的方法。该方法包括使磷酰氯（结构II）与具有结构X-OH的化合物（其可以是二芳基 化合物）和叔有机胺以提供结构I'和优选实施方案结构I.

公开(公告)号：US09221852B2

公开(公告)日：2015-12-29

申请号：US14354110

申请日：2012-10-15

Applicant: INVISTA North America S.a r.l.

Inventor： Stewart Forsyth ,  John Arthur Turner ,  Keith Whiston ,  Thomas E Vos

IPC: C07F9/144 ,  C07F9/145 ,  C07F9/146 ,  C07F9/6574

CPC classification number: C07F9/144 ,  C07F9/145 ,  C07F9/146 ,  C07F9/65744

Abstract: Claimed is a process for producing a phosphorus-containing ligand, preferably a diphosphite ligand structure (DLS) such as structure I. The method includes contacting a phosphorochloridite (structure II) with a compound having the structure X—OH (which can be a bisaryl compound), and a tertiary organic amine to provide structure I′ and as preferred embodiment structure I.

Abstract translation: 要求的是制备含磷配体，优选二亚磷酸酯配体结构（DLS）如结构I的方法。该方法包括使磷酰氯（结构II）与具有结构X-OH的化合物（其可以是二芳基 化合物）和叔有机胺以提供结构I'和优选实施方案结构I.

公开(公告)号：US20150011797A1

公开(公告)日：2015-01-08

申请号：US14375512

申请日：2013-02-01

Applicant: INVISTA NORTH AMERICA S.A R.L.

Inventor： Keith Whiston ,  Xi Liu ,  Graham Hutchings

IPC: C07C45/32 ,  C07C29/52 ,  C07C29/50

CPC classification number: C07C45/32 ,  B01J23/52 ,  B01J23/60 ,  B01J23/66 ,  B01J27/22 ,  B01J27/224 ,  B01J27/24 ,  B01J29/068 ,  B01J35/0013 ,  B01J35/006 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/16 ,  C07C29/50 ,  C07C29/52 ,  C07C45/33 ,  C07C2601/14 ,  Y02P20/588 ,  C07C49/403 ,  C07C35/08

Abstract: The present invention relates to a process for the oxidation of cycloalkanes utilising a supported gold and palladium catalyst and the use of the supported gold and palladium catalyst for the oxidation of cycloalkanes. Also described is a process for the preparation of the supported catalyst.

Abstract translation: 本发明涉及一种利用负载的金和钯催化剂氧化环烷烃的方法，以及使用负载的金和钯催化剂用于环烷烃的氧化。 还描述了制备负载型催化剂的方法。