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    HYDROLYSIS CATALYST AND PROCESS
    1.
    发明申请
    HYDROLYSIS CATALYST AND PROCESS 审中-公开
    水解催化剂和工艺

    公开(公告)号：US20150158892A1

    公开(公告)日：2015-06-11

    申请号：US14404030

    申请日：2013-05-24

    Applicant: INVISTA NORTH AMERICA S.A.R.L.

    Inventor： Sudhir Aki ,  Thomas E. Vos

    IPC: C07F9/145 ,  B01J31/18

    CPC classification number: C07F9/145 ,  B01J31/185 ,  B01J2231/322 ,  C07F9/65744

    Abstract: A process of hydrolyzing a monodentate, bidentate or tridentate phosphorus-based phosphite ester ligand or ligand blend for a transition metal catalyst comprising contacting the ligand or ligand blend with a hydrolysis catalyst of the formula (R11X11)nP(OH)3-n where n is 0, 1 or 2 wherein the ligand or ligand blend comprises one or more of (i) a bidentate biphosphite ligand of formula (III), (R12—X12)(R13—X13)P—X14—Y—X24—P(X22—R22)(X23—R23), (ii) a tridentate triphosphite ligand of formula (IIIA) (R12—X12)(R13—X13)P—X14—Y—X32—P(X34—R34)—(X33—Y2—K24—P(X23—R23)—(X22—R22) or (iii) a monodentate phosphite ligand of formula (IV) P(X1—R1)(X2—R2)(X3—R3) where each X is oxygen or a bond and each Y is an optionally substituted C6-C20 arylene, followed by separation of the ligand hydrolysis products.

    Abstract translation: 水解用于过渡金属催化剂的单齿，二齿或三齿磷基亚磷酸酯配体或配体共混物的方法，包括使配体或配体共混物与式（R 11 X 11）nP（OH）3-n的水解催化剂接触，其中n 是其中配体或配体共混物包含（i）式（III）的二齿二亚磷酸酯配体，（R12-X12）（R13-X13）P-X14-Y-X24-P（ X22-R22）（X23-R23），（ⅱ）式（ⅢA）（R12-X12）（R13-X13）P-X14-Y-X32-P（X34-R34） - （X33- Y2-K24-P（X23-R23） - （X22-R22）或（iii）式（IV）P（X1-R1）（X2-R2）（X3-R3）的单齿亚磷酸酯配体，其中X为氧 或键，并且每个Y是任选取代的C 6 -C 20亚芳基，然后分离配体水解产物。

    STABILIZED HYDROCYANATION LIGAND COMPOSITION
    3.
    发明申请
    STABILIZED HYDROCYANATION LIGAND COMPOSITION 审中-公开
    稳定化合物配体组合物

    公开(公告)号：US20150166583A1

    公开(公告)日：2015-06-18

    申请号：US14404083

    申请日：2013-05-24

    Applicant: INVISTA NORTH AMERICA S.A.R.L.

    Inventor： Sudhir Aki ,  Thomas E. Vos

    IPC: C07F9/02 ,  B65D25/14 ,  B01J31/22 ,  C07F9/145 ,  C07F9/6574

    CPC classification number: C07F9/025 ,  B01J31/22 ,  B01J2231/322 ,  B01J2531/847 ,  B65D25/14 ,  C07F9/145 ,  C07F9/65744

    Abstract: A method of stabilizing a phosphorus-based ligand or a ligand blend comprising a plurality of phosphorus-based ligands, wherein the ligand or ligand blend comprises one or more of (i) a bidentate biphosphite ligand of formula (III), (R12—X12) (R13—X13)P—X14—Y—X24—P (X22—R22) (X23—R23) (ii) a tridentate triphosphite ligand of formula (IIIA) (R12—X12) (R13—X13)P—X14—Y—X32—P(X34—R34)—(X33—Y2—R24—P(X23—R23)—(X22—R22) or (iii) a monodentate phosphite ligand of formula (IV) P(X1—R1)(X2—R2)(X3—R3) where each X is oxygen or a bond and each Y is optionally substituted C6-C20 arylene; the process comprising forming a mixture of the ligand or the ligand blend with a liquid which partially or fully solubilizes the ligand or ligand blend, the liquid consisting essentially of one or more of: (a) a solvent system that does not contain peroxidizable species; or, (b) a solvent system that is substantially free of a dissolved metal.

    Abstract translation: 一种稳定含磷基配位体的磷基配体或配体共混物的方法，其中所述配体或配体共混物包含一种或多种（i）式（III）的二齿二亚磷酸酯配体，（R12-X12 （R13-X13）（R13-X13）（R13-X13）（R13-X13）P-X14-Y-X24-P（X22-R22）（X23-R23） -Y-X32-P（X34-R34） - （X33-Y2-R24-P（X23-R23） - （X22-R22）或（iii）式（IV）的单齿亚磷酸酯配体P（X1-R1） （X 2 -R 2）（X 3 -R 3），其中每个X是氧或一个键，并且每个Y是任选取代的C 6 -C 20亚芳基;该方法包括用部分或完全溶解的液体形成配体或配体共混物的混合物 所述配体或配体共混物，所述液体基本上由以下中的一种或多种组成：（a）不含有可过氧化物质的溶剂体系;或（b）基本上不含溶解金属的溶剂体系。

    Stable ligand mixtures and processes for making same
    4.
    发明授权
    Stable ligand mixtures and processes for making same 有权

    公开(公告)号：US09834505B2

    公开(公告)日：2017-12-05

    申请号：US14404068

    申请日：2013-05-24

    Applicant: INVISTA NORTH AMERICA S.A.R.L.

    Inventor： Sudhir Aki ,  William J. Tenn, III ,  Thomas E. Vos

    IPC: C07C253/30 ,  C07F9/40 ,  C07F9/6574 ,  C07F9/145 ,  C07F15/04

    CPC classification number: C07C253/30 ,  C07F9/145 ,  C07F9/4006 ,  C07F9/65744 ,  C07F15/04

    Abstract: A process of stabilizing a bidentate or tridentate phosphorus-based phosphite ester ligand or mixture thereof in a hydrocyanation reaction milieu comprising water, wherein the ligand or ligand mixture comprises one or more of (i) a bidentate biphosphite ligand of formula (III), (R12—X12) (R13—X13) P—X14—Y—X24—P(X22—R22) (X23—R23) or (ii) a tridentate triphosphite ligand of formula (IIIA) (R12—X12) (R13—X13) P—X14—Y—X32—P(X34—R34)—(X33—Y2—R24—P(X23—R23)—(X22—R22) where each X is oxygen or a bond and each Y is an optionally substituted C6-C20 arylene group, comprising admixing the bidentate and/or tridentate with a stabilizing amount of one or more monodentate phosphite ligand of formula P(X1—R1)(X2—R2)(X3—R3) where each X is oxygen or a bond, wherein the monodentate ligand has a rate of hydrolysis greater than the rate of hydrolysis of the bidentate or tridentate ligand in the presence of water in a hydrocyanation reaction milieu, and thereby preserve concentrations and proportions of the bidentate and/or tridentate ligand(s) in the ligand blend.

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