公开(公告)号：WO2014099622A1

公开(公告)日：2014-06-26

申请号：PCT/US2013/074729

申请日：2013-12-12

Applicant: INVISTA NORTH AMERICA S.A.R.L. ,  INVISTA TECHNOLOGIES S.A.R.L.

Inventor： FORSYTH, Stewart ,  LIU, Aiguo ,  RENNER, Martin, J. ,  STAHLMAN, Brent, J.

IPC: C01C3/02 ,  B01D53/26 ,  F26B21/08

CPC classification number: C01C3/0212 ,  B01D53/26 ,  C01C3/022

Abstract: The system and methods described herein solve problems of inaccurate flow control, loss of optimum reactant gas feed ratios, and the associated inefficiencies brought on by variable humidity in reactant feedstream gases during production of hydrogen cyanide by an Andrussow process.

Abstract translation: 本文所述的系统和方法解决了通过安德鲁斯（Andrussow）工艺生产氰化氢期间反应物进料流气体中由不可变湿度引起的流量控制不正确，最佳反应气体进料比的损失以及相关的无效率问题。

公开(公告)号：WO2014099593A1

公开(公告)日：2014-06-26

申请号：PCT/US2013/074616

申请日：2013-12-12

Applicant: INVISTA TECHNOLOGIES S.A.R.L.

Inventor： FORSYTH, Stewart ,  RENNER, Martin, J. ,  LIU, Aiguo ,  STAHLMAN, Brent, J.

IPC: C01B3/56 ,  C01C3/02

CPC classification number: B01D53/047 ,  B01D2253/102 ,  B01D2253/106 ,  B01D2253/108 ,  B01D2253/116 ,  B01D2256/16 ,  B01D2257/406 ,  B01D2257/408 ,  C01B3/56 ,  C01B2203/0233 ,  C01B2203/0405 ,  C01B2203/0415 ,  C01B2203/043 ,  C01B2203/0465 ,  C01B2203/0495 ,  C01B2203/1676 ,  C01C3/0212

Abstract: A method and a system for recovering hydrogen from a process for making hydrogen cyanide are described herein. In the method, hydrogen is recovered from a gaseous waste stream of an Andrussow process. The method comprises the following steps: (a) adjusting a reaction mixture comprising methane, ammonia and oxygen to provide the reaction mixture with sufficient oxygen to generate a gaseous waste stream that has at least 40% hydrogen after removal of ammonia and recovery of hydrogen cyanide; and(b) removing components from the gaseous waste stream to generate recovered hydrogen.

Abstract translation: 本文描述了用于从制造氰化氢的方法回收氢的方法和系统。 在该方法中，从Andrussow工艺的气态废物流中回收氢。 该方法包括以下步骤：（a）调整包含甲烷，氨和氧的反应混合物，以使反应混合物具有足够的氧气以产生在除去氨后具有至少40％的氢气并回收氰化氢的气态废物流 ; 和（b）从气态废物流中除去组分以产生回收的氢气。

公开(公告)号：WO2008150842A1

公开(公告)日：2008-12-11

申请号：PCT/US2008/065048

申请日：2008-05-29

Applicant: INVISTA TECHNOLOGIES S.A.R.L. ,  FORSYTH, Stewart ,  SEDDON, Kenneth, R. ,  WHISTON, Keith

Inventor： FORSYTH, Stewart ,  SEDDON, Kenneth, R. ,  WHISTON, Keith

IPC: C07D211/14 ,  C07D223/04 ,  C25B3/00

CPC classification number: C07D211/14 ,  C07D223/04 ,  C25B3/02

Abstract: The invention relates to an ionic liquid composition and a method for preparing the ionic liquid. The ionic liquid comprises a cation containing the Formula I , disclosed, and wherein: n is 1 or 2, R 1 is selected from the group consisting of: H, C 1 - C 12 alkyl, aryl or together with R 2 may form a heterocyclic ring, and R 2 is selected from the group consisting of: H, C 1 - C 12 alkyl, aryl or together with R 1 may form a heterocyclic ring, and R 3 is selected from the group consisting of hydrogen and C 1 -C 12 alkyl, wherein if n is 1, then R 3 is C 1 -C 12 alkyl; and wherein R 1 and R 2 are not simultaneously selected from hydrogen. The method for the preparation of the ionic liquid composition provided herein starts with at least one N-substitution of the compound of Formula II , as herein disclosed, and wherein: n is 1 or 2, R 3 is selected from the group consisting of hydrogen and C 1 -C 12 alkyl, wherein if n is 1, then R 3 is C 1 -C 12 alkyl. Further provided is a use of the ionic liquid in a chemical method including at least a method for electro-chemical oxidation.

Abstract translation: 本发明涉及一种离子液体组合物和一种制备离子液体的方法。 离子液体包含含有式的阳离子

公开(公告)号：WO2009016378A2

公开(公告)日：2009-02-05

申请号：PCT/GB2008/002605

申请日：2008-07-31

Applicant: INVISTA TECHNOLOGIES S.A.R.L. ,  WHISTON, Keith ,  FORSYTH, Stewart ,  SEDDON, Kenneth, R.

Inventor： WHISTON, Keith ,  FORSYTH, Stewart ,  SEDDON, Kenneth, R.

IPC: C08J11/18 ,  C07D201/12

CPC classification number: C08J11/18 ,  C07D201/12 ,  Y02P20/542 ,  Y02W30/706

Abstract: An improved process for the hydrolysis of nylon polymer is herein disclosed using ionic liquids and optionally one equivalent of sulfuric acid per amide residue of the polymer. The process provides for a simplified means for separation of the hydrolyzed polyamide constituent monomers.

Abstract translation: 本文公开了尼龙聚合物的水解的改进方法，其中每个聚合物的酰胺残基使用离子液体和任选的一当量硫酸。 该方法提供了用于分离水解的聚酰胺组分单体的简化方法。

公开(公告)号：WO2014179051A1

公开(公告)日：2014-11-06

申请号：PCT/US2014/034169

申请日：2014-04-15

Applicant: INVISTA TECHNOLOGIES S.A.R.L.

Inventor： KELMAN, Charles R. ,  FORSYTH, Stewart ,  SHRIDHARANI, Ketan G.

IPC: B01J3/04 ,  C08G69/00

CPC classification number: B01J19/18 ,  B01J3/04 ,  B01J2208/00017 ,  B01J2219/00029 ,  B01J2219/00038 ,  B01J2219/00078 ,  B01J2219/0009 ,  B01J2219/00092 ,  B01J2219/00094 ,  B01J2219/00162 ,  C08G69/28

Abstract: The disclosure relates to apparatuses and methods for production of polyamide polymers utilizing additive injectors. In one embodiment, an apparatus for batch production of a polyamide polymer is provided. The apparatus can include a salt strike vessel configured to produce a polyamide salt composition and an evaporator configured to reduce water content of the polyamide salt composition to produce a polymerizable polyamide composition. The apparatus can further include a first autoclave operably connected to the evaporator such that a first portion of the polymerizable polyamide composition is deliverable from the evaporator to the first autoclave, and a second autoclave operably connected to the evaporator such that a second portion of the polymerizable polyamide composition is deliverable from the evaporator to the second autoclave. The first additive injector can be associated with the first autoclave and can be configured to inject additives into the first autoclave.

Abstract translation: 本公开涉及使用添加剂注射器生产聚酰胺聚合物的装置和方法。 在一个实施例中，提供了一种批量生产聚酰胺聚合物的设备。 该装置可以包括构造成产生聚酰胺盐组合物的盐击容器和构造成减少聚酰胺盐组合物的水含量以产生聚合性聚酰胺组合物的蒸发器。 该装置还可以包括可操作地连接到蒸发器的第一高压釜，使得可聚合聚酰胺组合物的第一部分可从蒸发器输送到第一高压釜，以及可操作地连接到蒸发器的第二高压釜，使得第二部分可聚合的 聚酰胺组合物可从蒸发器输送到第二高压釜。 第一添加剂注射器可以与第一高压釜相关联并且可以被配置为将添加剂注入到第一高压釜中。

公开(公告)号：WO2014099620A1

公开(公告)日：2014-06-26

申请号：PCT/US2013/074726

申请日：2013-12-12

Applicant: INVISTA NORTH AMERICA S.A.R.L. ,  INVISTA TECHNOLOGIES S.A.R.L.

Inventor： FORSYTH, Stewart ,  LIU, Aiguo ,  RENNER, Martin, J. ,  STAHLMAN, Brent, J.

IPC: C01C3/02 ,  B01D53/86

CPC classification number: C01C3/0216 ,  C01C3/0212 ,  C01C3/022

Abstract: Processes and systems for the production of hydrogen cyanide via the Andrussow process are described. A reaction zone, wherein oxygen, ammonia, and methane can be allowed to react in the presence of a catalyst comprising platinum to provide hydrogen cyanide. A desulfurization zone, wherein a feed stream comprising sulfur and at least one of the oxygen, the ammonia, and the methane can be contacted with a desulfurization material to produce a sulfur- reduced feed stream that is provided to the reaction zone. In an example, the desulfurization material includes zinc oxide.

Abstract translation: 描述了通过Andrussow方法生产氰化氢的方法和系统。 反应区，其中氧气，氨和甲烷可以在包含铂的催化剂的存在下反应以提供氰化氢。 脱硫区，其中包含硫和至少一种氧，氨和甲烷的进料流可与脱硫材料接触，以产生提供给反应区的硫还原进料流。 在一个实例中，脱硫材料包括氧化锌。

公开(公告)号：WO2014099565A1

公开(公告)日：2014-06-26

申请号：PCT/US2013/074526

申请日：2013-12-12

Applicant: INVISTA NORTH AMERICA S.A.R.L. ,  INVISTA TECHNOLOGIES S.A.R.L.

Inventor： FORSYTH, Stewart ,  RENNER, Martin J. ,  LIU, Aiguo ,  STAHLMAN, Brent J.

IPC: C01C3/02 ,  B01D53/00 ,  F25J3/02

CPC classification number: C01C3/0212

Abstract: Methane and ammonia raw materials are typically the major costs for HCN production. The methods described herein can be used to vary the molar ratio of methane to ammonia during HCN production to reduce costs.

Abstract translation: 甲烷和氨原料通常是HCN生产的主要成本。 本文所述的方法可用于在HCN生产期间改变甲烷与氨的摩尔比以降低成本。

公开(公告)号：EP2162435A1

公开(公告)日：2010-03-17

申请号：EP08756424.1

申请日：2008-05-29

Applicant: Invista Technologies S.A.R.L.

Inventor： FORSYTH, Stewart ,  SEDDON, Kenneth, R. ,  WHISTON, Keith

IPC: C07D211/14 ,  C07D223/04 ,  C25B3/00

CPC classification number: C07D211/14 ,  C07D223/04 ,  C25B3/02

Abstract: The invention relates to an ionic liquid composition and a method for preparing the ionic liquid. The ionic liquid comprises a cation containing the Formula I, disclosed, and wherein: n is 1 or 2, R1 is selected from the group consisting of: H, C1 - C12 alkyl, aryl or together with R2 may form a heterocyclic ring, and R2 is selected from the group consisting of: H, C1 - C12 alkyl, aryl or together with R1 may form a heterocyclic ring, and R3 is selected from the group consisting of hydrogen and C1-C12 alkyl, wherein if n is 1, then R3 is C1-C12 alkyl; and wherein R1 and R2 are not simultaneously selected from hydrogen. The method for the preparation of the ionic liquid composition provided herein starts with at least one N-substitution of the compound of Formula II, as herein disclosed, and wherein: n is 1 or 2, R3 is selected from the group consisting of hydrogen and C1-C12 alkyl, wherein if n is 1, then R3 is C1-C12 alkyl. Further provided is a use of the ionic liquid in a chemical method including at least a method for electro-chemical oxidation.