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    COLORED OXYGEN SCAVENGING POLYMERS
    1.
    发明授权
    COLORED OXYGEN SCAVENGING POLYMERS 无效
    有色除氧聚合物

    公开(公告)号：EP1778791B1

    公开(公告)日：2008-08-20

    申请号：EP05786508.1

    申请日：2005-08-17

    Applicant: INVISTA Technologies S.à.r.l.

    Inventor： LIU, Zhenguo

    IPC: C08L67/02 ,  C08L77/00 ,  B32B27/34 ,  B32B27/36

    CPC classification number: C08L67/02 ,  C08K5/098 ,  C08L9/00 ,  C08L23/0823 ,  C08L77/00 ,  C08L77/06 ,  C08L2666/20 ,  C08L2666/02 ,  C08L2666/08 ,  C08L2666/06 ,  C08L2666/18

    Abstract: The present invention relates to a melt blend of a base polymer, an oxidizable organic polymer, a transition metal salt catalyst and a colorant that does not completely deactivate the catalyzed oxidation. A preferred colorant, yields in an article made from the polymer melt blend a Catalyst Deactivation Factor (CDF) of less than about 0.25, preferably less than 0.15, more preferably less than 0.1, and most preferred less than 0.05. The present invention also comprises a colored monolayer article having the described CDF, such as a film, thermoformed tray, or blow molded container, that has active oxygen scavenging properties. The colorant, after melt blending a base polymer, an oxidizable organic polymer, a transition metal catalyst, does not increase the binding energy of the transition metal catalyst ion by more than 1 eV.

    METHOD TO MAKE SINGLE-LAYER PET BOTTLES WITH HIGH BARRIER AND IMPROVED CLARITY
    4.
    发明授权
    METHOD TO MAKE SINGLE-LAYER PET BOTTLES WITH HIGH BARRIER AND IMPROVED CLARITY 无效
    工艺生产具有高阻隔性的单层PET瓶和改进Clarity功能

    公开(公告)号：EP1663630B1

    公开(公告)日：2009-12-02

    申请号：EP04780147.7

    申请日：2004-08-05

    Applicant: INVISTA Technologies S.à.r.l.

    Inventor： MEHTA, Sanjay ,  LIU, Zhenguo ,  HUANG, Xiaoyan ,  SCHIRALDI, David, A

    IPC: B29D22/00 ,  B29D23/00 ,  C08K3/08 ,  C08K3/10 ,  C08K3/18 ,  C08K3/22 ,  C08K3/30 ,  C08K5/00

    CPC classification number: C08K3/24 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/14106 ,  B29B2911/14133 ,  B29B2911/1416 ,  B29C49/0005 ,  B29C49/06 ,  B29K2067/00 ,  B65D1/0207 ,  C08G63/6886 ,  C08K5/098 ,  C08K5/42 ,  C08L67/02 ,  C08L77/06 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L2666/20

    Abstract: The present invention comprises a blend of polyester and a partially aromatic polyamide with an ionic compatibilizer and a cobalt salt. This blend can be processed into a container that has both active and passive oxygen barrier and carbon dioxide barrier properties at an improved color and clarity than containers known in the art. The partially aromatic polyarnide is preferably meta­xylylene adipamide. The ionic compatibilizer is preferably 5-sodiumsulfoisophthalic acid or 5zincsulfoisophthalic acid, or their dialkyl esters such as the dimethyl ester (SIM) and glycol ester (SIPEG). The cobalt salt is selected form the class of cobalt acetate, cobalt carbonate, cobalt chloride, cobalt hydroxide, cobalt naphthenate, cobalt oleate, cobalt linoleate, cobalt octoate, cobalt stearate, cobalt nitrate, cobalt phosphate, cobalt sulfate, cobalt (ethylene glycolate), or mixtures of two or more of these. The partially aromatic polyamide is present in a range from about I to about 10 wt. % of said composition. The ionic compatibilizer is present in a range from about 0.1 to about 2.0 mol-% of said composition. The cobalt salt is present in a range from about 20 to about 500 ppm of said composition.

    Abstract translation: 本发明包括聚酯的共混物，并用在离子相容剂部分芳族聚酰胺和钴盐。 这种共混物可以被加工成一个容器确实具有改进的颜色和清晰度比现有技术中已知的容器主动和被动的阻氧和二氧化碳的阻隔性能。 的部分芳族聚酰胺优选是间苯二亚甲基己二酰二胺。 该离子相容剂是优选间苯二甲酸-5-磺酸钠或5- zincsulfoisophthalic酸，或它们的二烷基酯：例如二甲基酯（SIM）和乙二醇酯（SIPEG）。 钴盐被选择形成所述类乙酸钴，碳酸钴，氯化钴，氢氧化钴，环烷酸钴，油酸钴，钴亚油酸，辛酸钴，硬脂酸钴，硝酸钴，磷酸钴，硫酸钴，钴（乙烯甘醇酸） 或两种或多种的混合物的合成。 的部分芳族聚酰胺是存在的范围从约1至约10wt。％的所述组合物中。 该离子相容剂的存在量为约0.1至约2.0摩尔％的所述组合物的范围内。 钴盐是存在的范围从约20至约500ppm所述组合物的。

    COLORED OXYGEN SCAVENGING POLYMERS
    5.
    发明公开
    COLORED OXYGEN SCAVENGING POLYMERS 无效
    有色除氧聚合物

    公开(公告)号：EP1778791A2

    公开(公告)日：2007-05-02

    申请号：EP05786508.1

    申请日：2005-08-17

    Applicant: INVISTA Technologies S.à.r.l.

    Inventor： LIU, Zhenguo

    IPC: C08L67/02 ,  C08L77/00 ,  B32B27/34 ,  B32B27/36

    CPC classification number: C08L67/02 ,  C08K5/098 ,  C08L9/00 ,  C08L23/0823 ,  C08L77/00 ,  C08L77/06 ,  C08L2666/20 ,  C08L2666/02 ,  C08L2666/08 ,  C08L2666/06 ,  C08L2666/18

    Abstract: The present invention relates to a melt blend of a base polymer, an oxidizable organic polymer, a transition metal salt catalyst and a colorant that does not completely deactivate the catalyzed oxidation. A preferred colorant, yields in an article made from the polymer melt blend a Catalyst Deactivation Factor (CDF) of less than about 0.25, preferably less than 0.15, more preferably less than 0.1, and most preferred less than 0.05. The present invention also comprises a colored monolayer article having the described CDF, such as a film, thermoformed tray, or blow molded container, that has active oxygen scavenging properties. The colorant, after melt blending a base polymer, an oxidizable organic polymer, a transition metal catalyst, does not increase the binding energy of the transition metal catalyst ion by more than 1 eV.

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