PROCEDE DE FABRICATION DE COMPOSES NITRILES A PARTIR DE COMPOSES A INSATURATION ETHYLENIQUE
    1.
    发明公开
    PROCEDE DE FABRICATION DE COMPOSES NITRILES A PARTIR DE COMPOSES A INSATURATION ETHYLENIQUE 有权
    用于制备组合物的方法包括硝酸酯组合物,其包含保护乙烯基

    公开(公告)号:EP2760824A1

    公开(公告)日:2014-08-06

    申请号:EP12769372.9

    申请日:2012-09-27

    CPC classification number: C07C253/10 C07C255/03

    Abstract: The present invention relates to a method for the hydrocyanation of organic ethylenically unsaturated compounds including at least one nitrile function. The invention specifically relates to a method for the hydrocyanation of a hydrocarbon compound including at least one ethylenic unsaturation by a reaction with hydrogen cyanide in a liquid medium and in the presence of a catalyst including a metal element selected from the transition metals and an organophosphorous ligand, the organophosphorous ligand including a compound of general formula (I), where R
    1 and R
    2 , which are identical or different, are a linear or branched alkyl radical having 1-12 carbon atoms, which can include heteroatoms, or an optionally substituted aromatic or cycloaliphatic radical that can include heteroatoms, wherein the covalent bond between P and R
    1 , and that between P and R
    2 , are P-C bonds.

    Abstract translation: 本发明涉及包含至少一个腈官能团的有机烯属不饱和化合物的氢氰化方法。 本发明特别涉及一种通过与氰化氢在液体介质中反应并在包含选自过渡金属和有机磷配体的金属元素的催化剂存在下氢化氰化包括至少一个烯属不饱和度的烃化合物的方法 该有机磷配体包括通式(I)的化合物,其中R 1和R 2相同或不同,是具有1-12个碳原子的直链或支链烷基,其可以包括杂原子或任选被取代的 芳族或脂环族基团,其可以包括杂原子,其中P和R 1之间以及P和R 2之间的共价键是PC键。

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