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    STABLE LIGAND MIXTURES AND PROCESSES FOR MAKING SAME
    1.
    发明公开
    STABLE LIGAND MIXTURES AND PROCESSES FOR MAKING SAME 审中-公开
    稳定配体化合物和方法及其生产

    公开(公告)号：EP2870167A1

    公开(公告)日：2015-05-13

    申请号：EP13797871.4

    申请日：2013-05-24

    Applicant: INVISTA Technologies S.à.r.l.

    Inventor： AKI, Sudhir ,  TENN, William, J. ,  VOS, Thomas, E.

    IPC: C07F9/08 ,  C07F9/6574 ,  C07F9/50

    CPC classification number: C07C253/30 ,  C07F9/145 ,  C07F9/4006 ,  C07F9/65744 ,  C07F15/04

    Abstract: A process of stabilizing a bidentate or tridentate phosphorus-based phosphite ester ligand or mixture thereof in a hydrocyanation reaction milieu comprising water, wherein the ligand or ligand mixture comprises one or more of (i) a bidentate biphosphite ligand of formula (III), (R
    12 -X
    12 ) (R
    13 -X
    13 ) P-X
    14 -Y-Χ
    24 -P (X
    22 -R
    22 ) (X
    23 -R
    23 ) or (ii) a tridentate triphosphite ligand of formula (ΙIIΑ) (R
    12 -X
    12 ) (R
    13 -X
    13 ) Ρ-Χ
    14 -Y-X
    32 -P(X
    34 -R
    34 )-(X
    33 -Y
    2 -R
    24 -P(X
    23 -R
    23 )-(X
    22 -R
    22 ) where each X is oxygen or a bond and each Y is an optionally substituted C6-C20 arylene group, comprising admixing the bidentate and/or tridentate with a stabilizing amount of one or more monodentate phosphite ligand of formula P(X
    1 -R
    1 )(X
    2 -R
    2 )(X
    3 -R
    3 ) where each X is oxygen or a bond, wherein the monodentate ligand has a rate of hydrolysis greater than the rate of hydrolysis of the bidentate or tridentate ligand in the presence of water in a hydrocyanation reaction milieu, and thereby preserve concentrations and proportions of the bidentate and/or tridentate ligand(s) in the ligand blend.

    STABILIZED HYDROCYANATION LIGAND COMPOSITION
    5.
    发明公开
    STABILIZED HYDROCYANATION LIGAND COMPOSITION 审中-公开
    稳定的氢化配体组成

    公开(公告)号：EP2855493A1

    公开(公告)日：2015-04-08

    申请号：EP13798060.3

    申请日：2013-05-24

    Applicant: Invista Technologies S.à.r.l.

    Inventor： AKI, Sudhir ,  VOS, Thomas, E.

    IPC: C07F9/08 ,  C07F9/6574 ,  C07F9/50

    CPC classification number: C07F9/025 ,  B01J31/22 ,  B01J2231/322 ,  B01J2531/847 ,  B65D25/14 ,  C07F9/145 ,  C07F9/65744

    Abstract: A method of stabilizing a phosphorus-based ligand or a ligand blend comprising a plurality of phosphorus-based ligands, wherein the ligand or ligand blend comprises one or more of (i) a bidentate biphosphite ligand of formula (III), (R
    12 -X
    12 ) (R
    13 -X
    13 )P-X
    14 -Y-Χ
    24 -P (X
    22 -R
    22 ) (X
    23 -R
    23 ) (ii) a tridentate triphosphite ligand of formula (IIIΑ) (R
    12 -X
    12 ) (R
    13 -X
    13 )P-X
    14 -Y-Χ
    32 -P(X
    34 -R
    34 )-(X
    33 -Y
    2 -R
    24 -P(X
    23 -R
    23 )-(X
    22 -R
    22 ) or (iii) a monodentate phosphite ligand of formula (IV) P(X
    1 -R
    1 )(X
    2 -R
    2 )(X
    3 -R
    3 ) where each X is oxygen or a bond and each Y is optionally substituted C6-C20 arylene; the process comprising forming a mixture of the ligand or the ligand blend with a liquid which partially or fully solubilizes the ligand or ligand blend, the liquid consisting essentially of one or more of: (a) a solvent system that does not contain peroxidizable species; or, (b) a solvent system that is substantially free of a dissolved metal.

    Abstract translation: 一种稳定包含多种磷基配体的磷基配体或配体混合物的方法，其中所述配体或配体混合物包含以下中的一种或多种：（i）式（III）的二齿亚磷酸二酯配体，（R 12- （ⅱ）式（ⅢA）的三齿三亚磷酸酯配体（R 12 -X 12）（R 13 -X 13）PX 14 -Y-X 24 -P（X 22 -R 22）（X 23 -R 23） 12）（R 13 -X 13）PX 14 -Y-X 32 -P（X 34 -R 34） - （X 33 -Y 2 -R 24 -P（X 23 -R 23） - （X 22 -R （IV）P（X 1 -R 1）（X 2 -R 2）（X 3 -R 3）的单齿亚磷酸酯配体，其中每个X是氧或键，并且每个Y任选地 取代的C 6 -C 20亚芳基;所述方法包括形成所述配体或所述配体共混物与部分或完全溶解所述配体或配体共混物的液体的混合物，所述液体基本上由以下一种或多种组成：（a） 不含过氧化物质;或（b）基本上不含溶解金属的溶剂体系。

    SEPARATING A SOLVENT FROM A NICKEL CATALYST BY DISTILLATION
    6.
    发明公开
    SEPARATING A SOLVENT FROM A NICKEL CATALYST BY DISTILLATION 审中-公开
    美国爱丁堡爱尔兰尼克斯

    公开(公告)号：EP3022172A1

    公开(公告)日：2016-05-25

    申请号：EP14750398.1

    申请日：2014-07-16

    Applicant: Invista Technologies S.à.r.l.

    Inventor： AKI, Sudhir, N.V.K. ,  GARNER, James, Michael ,  TENN, William, J. ,  VOS, Thomas, E.

    IPC: C07C255/07 ,  C07C253/34

    CPC classification number: C07C253/10 ,  B01D3/143 ,  B01J31/185 ,  C07C253/34 ,  C07C255/07 ,  C07C255/04

    Abstract: A solvent is at least partially separated from a catalyst. The catalyst comprises nickel and a bidentate phosphorus-containing ligand. The method for separation involves distilling a catalyst solution. The ratio of 2-pentenenitrile to 3-pentenenitrile in distillation column bottoms is controlled to reduce the amount of 3-pentenenitrile which is isomerized to form 2-methyl-3-butenenitrile. Isomerization of 3-pentenenitrile to 2-methyl-3-butenenitrile and subsequent isomerization of 2-methyl-3-butenenitrile to 2-methyl-2-butenenitrile, and/or hydrocyanation of 2-methyl-3-butenenitrile to methylglutaronitrile represents a loss in adiponitrile yield in a process for making adiponitrile.

    Abstract translation: 溶剂与催化剂至少部分分离。 催化剂包括镍和二齿磷含量配体。 分离方法包括蒸馏催化剂溶液。 控制蒸馏塔底馏分中2-戊烯腈与3-戊烯腈的比例，以减少异构化形成2-甲基-3-丁烯腈的3-戊烯腈的量。 3-戊烯腈异构化为2-甲基-3-丁烯腈，随后将2-甲基-3-丁烯腈异构化为2-甲基-2-丁烯腈，和/或2-甲基-3-丁烯腈氢化为甲基戊二烯代表损失 在己二腈的制备方法中的己二腈产率。

    HYDROLYSIS CATALYST AND PROCESS
    8.
    发明公开
    HYDROLYSIS CATALYST AND PROCESS 有权
    水解催化剂及工艺

    公开(公告)号：EP2870166A1

    公开(公告)日：2015-05-13

    申请号：EP13797289.9

    申请日：2013-05-24

    Applicant: Invista Technologies S.à.r.l.

    Inventor： AKI, Sudhir ,  VOS, Thomas, E.

    IPC: C07F9/08 ,  C07F9/6574 ,  C07F9/50

    CPC classification number: C07F9/145 ,  B01J31/185 ,  B01J2231/322 ,  C07F9/65744

    Abstract: A process of hydrolyzing a monodentate, bidentate or tridentate phosphorus-based phosphite ester ligand or ligand blend for a transition metal catalyst comprising contacting the ligand or ligand blend with a hydrolysis catalyst of the formula (R
    11 X
    11 )
    n P (OH)
    3-n where n is 0, 1 or 2 wherein the ligand or ligand blend comprises one or more of (i) a bidentate biphosphite ligand of formula (III), (R
    12 -X
    12 ) (R
    13 -X
    13 ) P-X
    14 -Y-X
    24 -P (X
    22 -R
    22 ) (X
    23 -R
    23 ), (ii) a tridentate triphosphite ligand of formula (IIIΑ) (R
    12 -X
    12 ) (R
    13 -X
    13 ) Ρ-Χ
    14 -Y-X
    32 -P(X
    34 -R
    34 )-(X
    33 -Y
    2 -Κ
    24 -P(X
    23 -R
    23 )-(X
    22 -R
    22 ) or (iii) a monodentate phosphite ligand of formula (IV) P(X
    1 -R
    1 )(X
    2 -R
    2 )(X
    3 -R
    3 ) where each X is oxygen or a bond and each Y is an optionally substituted C6-C20 arylene, followed by separation of the ligand hydrolysis products.

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