Abstract:
Disclosed herein are an olefin copolymer having a functional group, which comprises a structural unit (a) derived from ethylene, a structural unit (b) derived from an alpha -olefin having 3 to 12 carbon atoms, and a structural unit (c) represented by the following general formula (1), and has an intrinsic viscosity Ä eta Ü of 0.1 to 10 dl/g as measured in decalin at 135 DEG C, a production process thereof and a rubber composition containing the copolymer ; wherein X and X mean, independently of each other, a hydrogen atom, a hydrocarbon group or the following specific functional group, at least one of X and X is the specific functional group, R and R denote, independently of each other, a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, one of R and R , which is bonded to a carbon atom to which the specific functional group is bonded, is the hydrocarbon group having 1 to 10 carbon atoms, and n stands for an integer of 0 to 2; Specific functional group: a functional group selected from the group consisting of a hydroxyl group, a hydrocarbon group to which a hydroxyl group is bonded, a carboxyl group, a hydrocarbon group to which a carboxyl group is bonded, a primary or secondary amino group, a hydrocarbon group to which a primary or secondary amino group is bonded, a quaternary ammonium salt of a primary or secondary amino group and a hydrocarbon group to which a primary or secondary amino group is bonded, an amide group having at least one active hydrogen atom bonded to a nitrogen atom, a hydrocarbon group to which such an amide group is bonded, and an imide group composed of X and X and represented by -CO-NH-CO-.
Abstract:
The present invention provides a cyclic olefin addition copolymer which has a reactive silyl group having a specific structure, excels in optical transparency, heat resistance, and adhesion, and is capable of producing a crosslinked product having improved dimensional stability, solvent resistance, and chemical resistance. The present invention also provides a process for producing the cyclic olefin addition copolymer, a crosslinking composition, a crosslinked product and a process for producing the same, and an optically transparent material (transparent resin film) comprising the cyclic olefin addition copolymer. The optically transparent material excels in optical transparency and heat resistance, exhibits improved dimensional stability, adhesion, solvent resistance, and chemical resistance, and is capable of improving fragility and preventing occurrence of cracks in the film.
Abstract:
Disclosed herein are an olefin copolymer having a functional group, which comprises a structural unit (a) derived from ethylene, a structural unit (b) derived from an alpha -olefin having 3 to 12 carbon atoms, and a structural unit (c) represented by the following general formula (1), and has an intrinsic viscosity Ä eta Ü of 0.1 to 10 dl/g as measured in decalin at 135 DEG C, a production process thereof and a rubber composition containing the copolymer ; wherein X and X mean, independently of each other, a hydrogen atom, a hydrocarbon group or the following specific functional group, at least one of X and X is the specific functional group, R and R denote, independently of each other, a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, one of R and R , which is bonded to a carbon atom to which the specific functional group is bonded, is the hydrocarbon group having 1 to 10 carbon atoms, and n stands for an integer of 0 to 2; Specific functional group: a functional group selected from the group consisting of a hydroxyl group, a hydrocarbon group to which a hydroxyl group is bonded, a carboxyl group, a hydrocarbon group to which a carboxyl group is bonded, a primary or secondary amino group, a hydrocarbon group to which a primary or secondary amino group is bonded, a quaternary ammonium salt of a primary or secondary amino group and a hydrocarbon group to which a primary or secondary amino group is bonded, an amide group having at least one active hydrogen atom bonded to a nitrogen atom, a hydrocarbon group to which such an amide group is bonded, and an imide group composed of X and X and represented by -CO-NH-CO-.
Abstract:
The present invention provides a cyclic olefin addition copolymer which has a reactive silyl group having a specific structure, excels in optical transparency, heat resistance, and adhesion, and is capable of producing a crosslinked product having improved dimensional stability, solvent resistance, and chemical resistance. The present invention also provides a process for producing the cyclic olefin addition copolymer, a crosslinking composition, a crosslinked product and a process for producing the same, and an optically transparent material (transparent resin film) comprising the cyclic olefin addition copolymer. The optically transparent material excels in optical transparency and heat resistance, exhibits improved dimensional stability, adhesion, solvent resistance, and chemical resistance, and is capable of improving fragility and preventing occurrence of cracks in the film.
Abstract:
A composition comprising a cyclic olefin addition copolymer containing recurring units of the following formulas (1) and (2), and at least one compound selected from (A) a compound acting as an acid when heated to 50 DEG C or higher, (B) a metal compound of an alkoxy compound, aryloxy compound, carboxyl compound, beta -diketone compound, halogen compound, or oxide, (C) an organic carboxylic acid, organic phosphoric acid, organic sulfonic acid, ammonia, primary to tertiary amine compound, or quaternary ammonium hydroxide compound. The composition exhibits excellent optical transparency, solvent resistance, dimensional stability, heat resistance, and adhesion to metals and inorganic materials, and suitable for use in optical transparent materials and electronic material parts, to a cross-linked product obtained by crosslinking the composition via siloxane bonds, and to a film, sheet, or coating made from the composition.
Abstract:
A composition comprising a cyclic olefin addition copolymer containing recurring units of the following formulas (1) and (2), and at least one compound selected from (A) a compound acting as an acid when heated to 50 DEG C or higher, (B) a metal compound of an alkoxy compound, aryloxy compound, carboxyl compound, beta -diketone compound, halogen compound, or oxide, (C) an organic carboxylic acid, organic phosphoric acid, organic sulfonic acid, ammonia, primary to tertiary amine compound, or quaternary ammonium hydroxide compound. The composition exhibits excellent optical transparency, solvent resistance, dimensional stability, heat resistance, and adhesion to metals and inorganic materials, and suitable for use in optical transparent materials and electronic material parts, to a cross-linked product obtained by crosslinking the composition via siloxane bonds, and to a film, sheet, or coating made from the composition.
Abstract:
A film or sheet containing an optionally crosslinked organic polymer which has a high degree of crosslinking and little contains residual solvent can be produced in a short time under a low pressure by bringing a film or sheet containing an organic polymer into contact with superheated steam.
Abstract:
PROBLEM TO BE SOLVED: To provide a laminate for forming a hard coat which is excellent in fingerprint visibility, a fingerprint wiping property and the abrasion resistance and of low tackiness.SOLUTION: This invention which is a laminate for forming the hard coat where a curable composition is formed on at least one surface of a plastic film directly or by the medium of the other layer has (A) a compound which has an ethylenic unsaturated group in a molecule and of which the mass average molecular weight measured by GPC is 3,000-200,000 and the glass transition temperature 30°C or above, (B) an inorganic oxide particle which has the ethylenic unsaturated group, (C) a photopolymerization initiator, (D) a fatty ester series surfactant which has a hydroxyl group and a (meth)acryloyl group and of which the HLB value is within a range of 2-15, and (E) a compound other than the components (A), (B) and (D), which has the ethylenic unsaturated group. The total amount of the components (D) and (E) is 30 mass% or below when the whole curable composition is 100 mass%.
Abstract:
PROBLEM TO BE SOLVED: To provide a thermoconductive composition having excellent preservation stability, and to provide a thermoconductive member having a high thermal conductivity. SOLUTION: The thermoconductive composition contains (A) glass powder, (B) boron nitride powder and (C) a resin component, wherein the proportion V 1 (wt.%) of the glass powder (A) and the proportion V 2 (wt.%) of the boron nitride powder (B) in the solid component of the thermoconductive composition satisfy the following expressions (1): 5≤V 1 ≤65; (2): 15≤V 2 ≤75; and (3): 50≤V 1 +V 2 ≤80, and the specific gravity of the glass powder (A) measured by an air comparison pycnometer is within the range of 2.0-3.0 g/cm 3 . COPYRIGHT: (C)2010,JPO&INPIT