Abstract:
A curable resin composition comprising a urethane (meth)acrylate having a molecular terminal represented by formula (3), wherein R is a hydrogen atom or a methyl group and R is a hydrogen atom or an organic group having one or more carbon atoms, the urethane (meth)acrylate being prepared by reacting (A) a polyol having a melting point of 0 DEG C or higher, (B) a polyisocyanate, and (C) a (meth)acrylate containing a hydroxyl group. The composition having excellent liquid stability and can produce cured products with superior mechanical characteristics by polymerization.
Abstract:
The invention relates to a curable resin composition, cured products thereof, and laminated materials. The curable composition comprises : (A-1) acicular oxide particles, the oxide being an oxide of at least one element selected from the group consisting of silicon, aluminium, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium, (B) a compound having two or more polymerizable unsaturated groups, (c) a photopolymerization initiator is provided. After cure, the composition has excellent scratch resistance. In addition, it may have excellent antistatic characteristics and transparency. In a preferred embodiment the composition also comprises (A-2) particles other than the acicular particles (A-1), being oxide of at least one element selected from the group consisting of silicon, aluminium, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium.
Abstract:
A photosensitive resin composition for optical waveguide formation, comprising: (A) a di(meth)acrylate having the structure represented by the following general formula (1): (wherein R is -(OCH2CH2)m-, -(OCH(CH3)CH2)m-, or -OCH2CH(OH)CH2-; X is -C(CH3)2-, -CH2-, -O-, or -SO2-; Y is a hydrogen atom or a halogen atom; m is an integer of 0 to 4); (B) a mono(meth)acrylate having the structure represented by the following general formula (2): (wherein R is -(OCH2CH2)p-, -(OCH(CH3)CH2)p-, or -OCH2CH(OH)CH2-; Y is a hydrogen atom, a halogen atom, Ph-C(CH3)2-, Ph-, or an alkyl group having 1 to 20 carbon atoms; p is an integer of 0 to 4; Ph is a phenyl group); and (C) a photoradical polymerization initiator. The composition has excellent patterning ability, refractive index, heat resistance, and transmission characteristic.
Abstract:
The invention relates to a photocurable resin composition comprising: (A) (A1) a (meth)acrylate having a structure shown by the formula (1) or (2), or (A2) an epoxy compound having a structure shown by the formula (1) or (2); (B) a (meth)acrylate having three or more functional groups other than (A1); (C) a radical photoinitiator; (D) a compound having three or more cyclic ether linkages in the molecule other than (A2) and (E) a cationic photoinitiator; the invention also relates to optical parts made from the resins of the invention and use of the resin in other applications.
Abstract:
A curable resin composition comprising a urethane (meth)acrylate having a molecular terminal represented by the following formula (3), wherein R1 is a hydrogen atom or a methyl group and R2 is a hydrogen atom or an organic group having one or more carbon atoms, the urethane (meth)acrylate being prepared by reacting (A) a polyol having a melting point of 0° C. or higher, (B) a polyisocyanate, and (C) a (meth)acrylate containing a hydroxyl group. The composition having excellent liquid stability and can produce cured products with superior mechanical characteristics by polymerization.
Abstract:
The invention relates to a curable resin composition, cured products thereof, and laminated materials. The curable composition comprises: (A-1) acicular oxide particles, the oxide being an oxide of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium, (B) a compound having two or more polymerizable unsaturated groups, (C) a photopolymerization initiator is provided. After cure, the composition has excellent scratch resistance. In addition, it may have excellent antistatic characteristics and transparency. In a preferred embodiment the composition also comprises (A-2) particles other than the acicular particles (A-1), being oxide of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium.
Abstract:
A photosensitive resin composition for optical waveguide formation, comprising: (A) a di(meth)acrylate having the structure represented by the following general formula (1): (wherein R is -(OCH2CH2)m-, -(OCH(CH3)CH2)m-, or -OCH2CH(OH)CH2-; X is -C(CH3)2-, -CH2-, -O-, or -SO2-; Y is a hydrogen atom or a halogen atom; m is an integer of 0 to 4); (B) a mono(meth)acrylate having the structure represented by the following general formula (2): (wherein R is -(OCH2CH2)p-, -(OCH(CH3)CH2)p-, or -OCH2CH(OH)CH2-; Y is a hydrogen atom, a halogen atom, Ph-C(CH3)2-, Ph-, or an alkyl group having 1 to 20 carbon atoms; p is an integer of 0 to 4; Ph is a phenyl group); and (C) a photoradical polymerization initiator. The composition has excellent patterning ability, refractive index, heat resistance, and transmission characteristic.
Abstract:
The invention relates to a curable resin composition, cured products thereof, and laminated materials. The curable composition comprises: (A-1) acicular oxide particles, the oxide being an oxide of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium, (B) a compound having two or more polymerizable unsaturated groups, (C) a photopolymerization initiator is provided. After cure, the composition has excellent scratch resistance. In addition, it may have excellent antistatic characteristics and transparency. In a preferred embodiment the composition also comprises (A-2) particles other than the acicular particles (A-1), being oxide of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium.