Abstract:
PROBLEM TO BE SOLVED: To provide a retardation film for extending a film making a principal component of a ring-like olefin-based additional copolymer exhibiting characteristics such as melting molding working, excellent transparency, heat resistance, low water absorption and a low dielectric constant. SOLUTION: The retardation film has: a structural unit (1) induced from a ring-like olefin-based compound having 4C alkyl group; and a structural unit (2) induced from a ring-like olefin-based compound having 5-12C alkyl group. The retardation film extends the film consisting of a ring-like olefin-based compound additional copolymer having a structural unit (3) induced from the other ring-like olefin-based compound at need. The retardation film consisting of the ring-like olefin-based additional copolymer has excellent transparency, heat resistance, low water absorption, dielectric constant, a small metal constant, excellent flexibility and toughness. The retardation film has high uniformity of retardation in the face of the film, hardly influences temperature and humidity of an environment by obtained retardation properties, has excellent elapse stability and excellent expression of the retardation. COPYRIGHT: (C)2008,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a norbornene-based addition copolymer having excellent heat resistance, being excellent in transparency and toughness, melt-moldable and suitably used as an optical material; a process for producing the addition copolymer; and a film or sheet prepared by molding the addition copolymer. SOLUTION: The norbornene-based addition copolymer of the invention has a structural unit derived from bicyclo[2.2.1]hepta-2-ene and a structural unit derived from bicyclo[2.2.1]hepta-2-ene having a ≥6C alkyl substituent at a specific proportion. In a wide angle X-ray scattering (WAXS) pattern for the addition copolymer, 2θ of a lower angle peak of the measured two peaks is 10° or greater. COPYRIGHT: (C)2007,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide an oil extended rubber based on ethylene-α-olefin-nonconjugated diene, giving vulcanizates improved in mechanical strength, compression set, impact resilience and the like when vulcanized. SOLUTION: The oil extended rubber comprises (A) 100 pts.wt. ultrahigh molecular weight ethylene-α-olefin-nonconjugated diene copolymer rubber having ≥5.5 dL/g intrinsic viscosity (measured in a decalin solvent at 135°C) and X pts.wt. mineral oil-based extender, wherein Mooney viscosity Y (ML 1+4 , 190°C) of the oil extended rubber and oil extender amount X pts.wt. satisfy formula (1); Y≥-0.5X+80. COPYRIGHT: (C)2006,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To obtain a cycloolefin base addition polymer which has no substantial distribution in a composition of a structural unit, wherein the structural unit is derived from a cycloolefin base compound which has at least one polar substituent group selected from a hydrolyzable silyl group, ester group and oxetane group. SOLUTION: The cycloolefin base addition polymer can be produced by polymerizing a cycloolefin base monomer using compounds (A), (B) and (C) as follows, (A) a palladium compound represented by the formula (1): Pd(R 1 ) a (X) b , (B) a phosphonium compound represented by the formula (2): [PR 2 R 3 R 4 R 5 ] + [CA 1 ] - , and (C) an organic aluminium compound. COPYRIGHT: (C)2005,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To provide a cycloolefin copolymer formed by ring-opening polymerization excellent in optical properties including transparency, etc., having reduced water (moisture) absorption, a high affinity for other materials, satisfactory suitability for bonding, printing, and other processings after molding, and excellent in heat resistance and mechanical strength, and to provide a method for producing the same and an optical material. SOLUTION: The cycloolefin copolymer formed by ring-opening polymerization comprises structural units (A) represented by general formula (1-1) to (1-3) and structural units (B) derived from a specific cycloolefin having an ester group, in a proportion of from 10/90 to 50/50 by mole. The monomers for obtaining the structural units (A) are tricyclomonoolefin compounds at least 80 mol% of which are accounted for by one or more endo forms. The copolymer has a glass transition temperature of 120 to 250 °C. [In the general formula (1-1) to (1-3), R 1 to R 13 each represents hydrogen, a halogen, or a group selected from among 1-4C alkyl and halogenated alkyl; and X 1 to X 3 each represents an ethylene- or vinylene-group.]. COPYRIGHT: (C)2004,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To provide a method for producing a cyclic olefin-based addition (co)polymer reduced in the molecular weight in a molecular weight range suitable for mold processing to films, sheets and the like, requiring no process for removing catalyst residues and unreacted monomers, excellent in high transparency and toughness by solely using a small amount of a palladium catalyst and a molecular weight regulator. SOLUTION: The method for producing the cyclic olefin-based addition polymer is to carry out an addition (co)polymerization of monomers containing a cyclic olefin as a main ingredient in the presence of ethene by using a catalyst comprising (a) an organic acid salt of palladium or a β-diketonate compound, (b) a cyclopentyl phosphine compound and (c) an ionic boron compound or an ionic aluminum compound. COPYRIGHT: (C)2007,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a heat storage material which is prevented from bleeding while maintaining a sufficient latent heat amount as a heat storage material.SOLUTION: The heat storage material is formed of a compact of a composition comprising a heat storage substance (A), at least one (B) selected from conjugated diene-based (co)polymers and metal salts of fatty acids, and at least one (C) selected from polar resins and crystalline polyolefins. The component (A) is at least one kind selected from paraffin compounds, fatty acid esters, fatty ketones, fatty alcohols, and fatty ethers.
Abstract:
PROBLEM TO BE SOLVED: To provide a crosslinked material of a hydrogenated cyclic olefin ring-opening copolymer which is excellent in high transparency, adhesiveness, tight adhesiveness and anti-water absorption, is excellent also in dimensional stability, solvent resistance and chemical resistance, moreover, is easily processed into a molded product and has high cross-linking density, and to provide a composition for crosslinking the hydrogenated cyclic olefin ring-opening copolymer. SOLUTION: The crosslinked material is provided by crosslinking the hydrogenated cyclic olefin ring-opening copolymer which is obtained by ring-opening polymerizing a norbornene type monomer having a specified silyl group such as 5-triethoxysilyl-2-norbornene and other norbornene type monomer such as an 8-methyl-8-methoxycarbonyl teteracyclo[4. 4. 0. 1 2,5 . 1 7,10 ]-3-dodecene and has a number-average molecular weight of 5,000 to 1,000,000, with siloxane bonds by means of heating, wherein the degree of swelling measured with toluene or cyclohexane at 25°C is 500% or less. Further, the crosslinking composition is produced by compounding a crosslinking agent (for example, a compound operating as an acid at a temperature of 50°C or higher) to the cyclic olefin ring-opening copolymer. COPYRIGHT: (C)2011,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide an optical substrate which excels in transparency, heat resistance, moisture resistance, water resistance, solvent resistance, and chemical resistance to an acid, an alkali and the like, has a small coefficient of thermal expansion (coefficient of linear expansion), improved mechanical properties, and toughness, and its manufacturing method. SOLUTION: The optical substrate is composed of a cyclic olefin addition copolymer having a cyclic olefin structural unit (1) having no substituent or only any one of substituents of a halogen atom, a methyl group, and an ethyl group and a cyclic olefin structural unit (2) having a substituent such as a trimethylsilyl group at a specific ratio, and a number average molecular weight (Mn) of 20,000-300,000. COPYRIGHT: (C)2007,JPO&INPIT