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公开(公告)号:JPH01266166A
公开(公告)日:1989-10-24
申请号:JP9528788
申请日:1988-04-18
Applicant: KAO CORP
Inventor: FUJIOKA HIDEAKI
IPC: C08K5/06 , C08K5/07 , C08L101/02
Abstract: PURPOSE:To improve the hot water resistance of a specified synthetic resin, by incorporating an alkylketene dimer therein. CONSTITUTION:100pts.wt. synthetic resin (e.g., polybutylene terephthalate) having carboxyl, hydroxyl, or amino groups at the end of its main chain or on its side chain is mixed with 0.01-5pts.wt. alkylketene dimer of the formula (wherein R is a 6-20C, preferably 10-16C, alkyl) (e.g., laurylketene dimer) and, if necessary, a coloring agent, a lubricant, an antistatic agent, a filler, etc.
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公开(公告)号:JPH01135865A
公开(公告)日:1989-05-29
申请号:JP29375787
申请日:1987-11-20
Applicant: KAO CORP
Inventor: GOTO SHINYA , FUJIOKA HIDEAKI
Abstract: PURPOSE:To obtain a polyamide resin composition having low evaporation of plasticizer and giving a molded article free from surface tackiness and having excellent flexibility, by compounding a polyamide with a specific compound as a plasticizer. CONSTITUTION:The objective polyamide resin composition is produced by dry- blending or melt-kneading (A) 100pts.wt. of a polyamide resin having a number- average molecular weight of preferably >=10,000 and (B) 0.5-20pts.wt., preferably 1-15pts.wt. of a compound of formula I (A is oxyethylene or oxypropylene; m+n is 0-8; X is group of formula II, S, SO or SO2) as a plasticizer. The composition has low evaporation of plasticizer and gives a molded article having excellent flexibility and free from surface tackiness.
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公开(公告)号:JP2003055430A
公开(公告)日:2003-02-26
申请号:JP2001244295
申请日:2001-08-10
Inventor: ISHIKAWA ATSUSHI , SAKAI MITSURU , MORII MASAYOSHI , FUJIOKA HIDEAKI
IPC: B29C39/02 , B29K75/00 , B29K105/04 , B29K105/24 , C08G18/65 , C08G101/00
Abstract: PROBLEM TO BE SOLVED: To provide a crosslinking agent which is used for producing a polyurethane foam, is a low-viscosity liquid at room temperature, excellent in handleability, and has high reactivity, and a process which makes it possible to quickly produce a flame-retardant polyurethane foam excellent in mechanical properties such as compressive strength.
SOLUTION: The crosslinking agent for producing a polyurethane foam contains a bisphenol A derivative represented by formula (I) (wherein R
1 is H or methyl; and (m) is the average number of oxyalkylene molecules added and is 1 to 3) and a dialkanolamine compound represented by formula (II) (wherein R
2 is H or methyl; R
3 is a 1-18C linear or branched alkyl or a 2-18C linear or branched alkenyl; and (n) is the average number of oxyalkylene molecules added and is 1 to 3). The process for producing a polyurethane foam comprises reacting a polyol composition containing the crosslinking agent and a polyol component with an isocyanate component in the presence of a foaming agent and a catalyst.
COPYRIGHT: (C)2003,JPOAbstract translation: 要解决的问题:为了提供用于制备聚氨酯泡沫的交联剂,在室温下为低粘度液体,操作性优异,反应性高,并且能够快速产生火焰的方法 优异的机械性能如抗压强度的聚氨酯泡沫塑料。 解决方案:用于制备聚氨酯泡沫的交联剂含有由式(I)表示的双酚A衍生物(其中R 1是H或甲基;和(m)是加入的氧化烯分子的平均数,为1至3) 和由式(II)表示的二烷醇胺化合物(其中R 2是H或甲基; R 3是1-18C直链或支链烷基或2-18C直链或支链烯基;和(n)是 平均氧化烯分子数为1〜3)。 制备聚氨酯泡沫的方法包括在发泡剂和催化剂的存在下使包含交联剂的多元醇组合物和多元醇组分与异氰酸酯组分反应。
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公开(公告)号:JPH01304135A
公开(公告)日:1989-12-07
申请号:JP13489088
申请日:1988-06-01
Applicant: KAO CORP
Inventor: FUJIOKA HIDEAKI , GOTO SHINYA
Abstract: PURPOSE:To improve gloss by adding an alkali metal salt of an 8-22C fatty acid to a polyolefin resin. CONSTITUTION:0.01-3.0PHR alkali metal salt of an 8-22C fatty acid and, if necessary, an anti-oxidant, a weathering agent, an antistat, an antifogging agent, an antiblocking agent, a dye, a pigment, etc., are compounded with a polyolefin resin.
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公开(公告)号:JPH01266159A
公开(公告)日:1989-10-24
申请号:JP9528688
申请日:1988-04-18
Applicant: KAO CORP
Inventor: GOTO SHINYA , FUJIOKA HIDEAKI
Abstract: PURPOSE:To obtain the title composition which has excellent antistatic properties, good mechanical strength, and good moldability, and is suitable for, e.g., electrical and electronic equipment housings on which duct is apt to be deposited, by incorporating a specified antistatic agent into an aromatic polycarbonate resin/ABS resin composition. CONSTITUTION:100pts.wt. synthetic resin composition (A) consisting of 30-99wt.% aromatic polycarbonate resin and 70-1wt.% ABS resin is mixed with 0.5-5pts.wt. antistatic agent (B) containing both an alkylbenzenesulfonate of formula I (wherein R is an 8-22C straight-chain or branched alkyl; M is an alkali metal) or formula II (wherein R is the as R ; M is as defined above) and a polyethylene wax having acidic groups, thereby giving the title composition. The incorporation of component B can give a composition having improved antistatic properties without substantial reduction in the physical properties of composition A. The title composition thus obtained is suitably used for, e.g., electrical and electronic equipment housings and cases on which dust, etc. are apt to be deposited.
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公开(公告)号:JPH01185362A
公开(公告)日:1989-07-24
申请号:JP783788
申请日:1988-01-18
Applicant: KAO CORP
Inventor: GOTO SHINYA , FUJIOKA HIDEAKI
Abstract: PURPOSE:To obtain a polyamide resin composition which can give a molding free of surface stickiness and rendered very flexible, by mixing a specified p- or o-hydroxybenzoic ester with a polyamide resin. CONSTITUTION:An ester of p- or o-hydroxybenzoic acid with a 12-22C branched alcohol (e.g., 2-ethyldecyl p-hydroxybenzoate) is added in an amount of 0.1-30 pts.wt. per 100pts.wt. polyamide resin. The plasticizer obtained by using said branched alcohol can give a molding free of surface stickiness, is lowly volatile and has a marked flexibilizing effect, so that a polyamide resin of excellent flexibility can be obtained.
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公开(公告)号:JPH01108245A
公开(公告)日:1989-04-25
申请号:JP26585687
申请日:1987-10-21
Applicant: KAO CORP
Inventor: HORIBATAKE NOBORU , FUJIOKA HIDEAKI
Abstract: PURPOSE:To obtain the title composition excellent in abrasion resistance and mechanical properties, by kneading a high-impact polystyrene with a specified saturated aliphatic hydrocarbon compound. CONSTITUTION:100pts.wt. high-impact polystyrene is kneaded with 0.5-5.0pts.wt. at least one saturated aliphatic hydrocarbon compound of a number-average MW of 700-6000000, selected from polyethylene wax, polypropylene wax, an alpha-olefin/ethylene copolymer, PE and PP, and optionally a lubricant (e.g., ethylenebisstearamide), a mold release, an antistatic agent, etc.
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公开(公告)号:JPS63230764A
公开(公告)日:1988-09-27
申请号:JP6324887
申请日:1987-03-18
Applicant: KAO CORP
Inventor: GOTO SHINYA , HORIBATAKE NOBORU , FUJIOKA HIDEAKI
Abstract: PURPOSE:To provide the title compsn. having an excellent antistatic effect, by blending a polycarbonate resin with a mixture of two specific components and kneading the blend. CONSTITUTION:A component (a) of formula I (wherein R is an 8-22C alkyl; X is an alkali metal, pref. Na or K) or formula II (e.g., C12H25SO3Na) is mixed with a glycerol fatty acid ester (b) having a monoglyceride content not lower than 70% and a 12-22C fatty acid group (e.g., stearic acid monoglyceride) in a weight ratio of 30-70/70-30 to obtain a mixture (B). A polycarbonate resin (A) is blended with 0.2-3.0PHR component B and as required, silica, metallic soap of a fatty acid, a fatty acid amide and lubricant (C). The mixture is kneaded.
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公开(公告)号:JP2582392B2
公开(公告)日:1997-02-19
申请号:JP783788
申请日:1988-01-18
Applicant: KAO CORP
Inventor: GOTO SHINYA , FUJIOKA HIDEAKI
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公开(公告)号:JPH02218471A
公开(公告)日:1990-08-31
申请号:JP26762088
申请日:1988-10-24
Applicant: KAO CORP
Inventor: FUJIOKA HIDEAKI , MIYAMOTO NORIFUSA , TAKAHASHI HIROMICHI
IPC: C08J7/06 , B05D1/04 , B05D3/10 , C08J7/02 , C08J7/12 , C08L23/10 , C08L71/12 , C08L75/04 , C08L77/00
Abstract: PURPOSE:To easily make the surface of a synthetic resin conductive even when the shape thereof is complicated by bringing a synthetic resin molded body into contact with a solution of ferric chloride in a specific solvent and subsequently exposing the surface to pyrrole or the like. CONSTITUTION:Ferric chloride anhydride or ferric chloride hydrate is dissolved in a solvent, wherein surface tension is 35dyn/cm or less at 25 deg.C and solubility of ferric chloride anhydride or ferric chloride hydrate is 1.0wt.% or more at 25 deg.C, in an amount of 1.0wt.% or more. A synthetic resin molded body composed of nylon or modified PPO is brought into contact with this solution and, thereafter, the surface of this synthetic resin molded body is exposed to pyrrole, thiophene, furan or a derivative thereof. By this method, even when spray is difficult because of the complicated shape of a synthetic resin, the surface of the synthetic resin can be easily made conductive.
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