PROCESS FOR PRODUCING PRODUCT OF HYDROGENOLYSIS OF POLYHYDRIC ALCOHOL

    公开(公告)号:MY147359A

    公开(公告)日:2012-11-30

    申请号:MYPI20084478

    申请日:2008-11-07

    Applicant: KAO CORP

    Abstract: PROCESS FOR PRODUCING PRODUCT OF HYDROGENOLYSIS OF POLYHYDRIC ALCOH ABSTRACT THE PRESENT INVENTION RELATES TO A PROCESS FOR PRODUCING HYDROGENOLYSIS PRODUCTS OF POLYHYDRIC ALCOHOLS WITH A HIGH SELECTIVITY AS WELL AS HYDROGENOLYSIS CATALYSTS USED IN THE HYDROGENOLYSIS REACTION. THE PRESENT INVENTION PROVIDES 5 A PROCESS FOR PRODUCING A HYDROGENOLYSIS PRODUCT OF A POLYHYDRIC ALCOHOL WHICH INCLUDES THE STEP OF REACTING THE POLYHYDRIC ALCOHOL WITH HYDROGEN IN THE PRESENCE OF A CATALYST CONTAINING (A) A PLATINUM-SUPPORTING HETEROGENEOUS CATALYST COMPONENT AND W AT LEAST ONE CATALYST COMPONENT SELECTED FROM THE GROUP CONSISTING OF TUNGSTEN COMPONENTS AND MOLYBDENUM COMPONENTS, OR IN 10 THE PRESENCE OF A CATALYST CONTAINING A HETEROGENEOUS CATALYST COMPONENT FORMED BY SUPPORTING (A') PLATINUM AND THE ABOVE CATALYST COMPONENT (B), ON A COMMON CARRIER; AS WELL AS CATALYSTS FOR HYDROGENOLYSIS OF POLYHYDRIC ALCOHOLS. 15

    METHOD FOR PRODUCING HYDROGENOLYSIS PRODUCT OF POLYHYDRIC ALCOHOL
    6.
    发明公开
    METHOD FOR PRODUCING HYDROGENOLYSIS PRODUCT OF POLYHYDRIC ALCOHOL 有权
    用于生产多元醇的氢

    公开(公告)号:EP2239247A4

    公开(公告)日:2013-11-06

    申请号:EP08871698

    申请日:2008-12-26

    Applicant: KAO CORP

    CPC classification number: C07C29/60 C07C31/205

    Abstract: The present invention relates to a process for producing a hydrogenolysis product of a polyhydric alcohol in the presence of a catalyst in which a conversion rate of the polyhydric alcohol as well as a selectivity to the hydrogenolysis product, in particular, a selectivity of glycerol to propanediols, can be enhanced. The process for producing a hydrogenolysis product of a polyhydric alcohol according to the present invention includes the step of subjecting a polyhydric alcohol solution having a water content of less than 10% by mass to hydrogenolysis by a fixed-bed continuous liquid phase reaction method in the presence of a hydrogenation catalyst.

    Method of manufacturing desulfurized fatty acid ester
    8.
    发明专利
    Method of manufacturing desulfurized fatty acid ester 审中-公开
    制造脱脂脂肪酸酯的方法

    公开(公告)号:JP2014129291A

    公开(公告)日:2014-07-10

    申请号:JP2012288434

    申请日:2012-12-28

    Abstract: PROBLEM TO BE SOLVED: To provide a method of manufacturing novel desulfurized fatty acid ester, and to provide a method of manufacturing alcohol using the desulfurized fatty acid ester obtained by the manufacturing method as a raw material.SOLUTION: There are provided [1] a method of manufacturing desulfurized fatty acid ester containing following process 1 and process 2, [2] a method of manufacturing alcohol by hydrogenation reaction to the desulfurized fatty acid ester obtained by the manufacturing method described in [1]. Process 1: a process of contacting crude fatty acid ester containing fatty acid ester and sulfur content with hydrogen peroxide of over 100 mass times to the sulfur content in the crude fatty acid ester in a presence of fatty acid having 10 to 14 carbon atoms of 2 to 10 mass% based on the crude fatty acid at a temperature of 20 to 200°C. Process 2: a process of conducting (a) an adsorption treatment with adsorbent or (b) a washing treatment with a polar solvent after the process 1.

    Abstract translation: 要解决的问题:提供一种制造新型脱硫脂肪酸酯的方法,提供使用通过制造方法得到的脱硫脂肪酸酯作为原料制造醇的方法。解决方案:提供[1] a 含有以下方法1和方法2的脱硫脂肪酸酯的制备方法[2]通过氢化反应制备通过[1]所述的制造方法得到的脱硫脂肪酸酯的方法。 方法1:使含有脂肪酸酯的粗脂肪酸酯和硫含量与过氧化氢接触超过100质量倍的方法使粗脂肪酸酯中的硫含量在10-14个碳原子的脂肪酸存在下 至10质量%,基于粗脂肪酸,温度为20〜200℃。 方法2:进行(a)用吸附剂进行吸附处理或(b)在处理1之后用极性溶剂进行洗涤处理的方法1。

    Method of manufacturing amide compound
    9.
    发明专利
    Method of manufacturing amide compound 有权
    制备酰胺化合物的方法

    公开(公告)号:JP2007308410A

    公开(公告)日:2007-11-29

    申请号:JP2006138207

    申请日:2006-05-17

    Abstract: PROBLEM TO BE SOLVED: To provide a method of manufacturing amide compound which reacts a carboxylic acid derivative with an amine to manufacture an amide compound, and which can reduce the generation of by-produced in-molecular imide compounds.
    SOLUTION: The method of manufacturing amide compound is for manufacturing the amide compound by reacting the carboxylic acid derivative with the amine, and comprises a process for aging the reaction mixture of the carboxylic acid derivative and the amine at a temperature of their melting points or lower after the reaction.
    COPYRIGHT: (C)2008,JPO&INPIT

    Abstract translation: 待解决的问题:提供一种制备酰胺化合物的方法,其使羧酸衍生物与胺反应以制备酰胺化合物,并且可以减少副产物的分子内酰亚胺化合物的产生。 解决方案:酰胺化合物的制造方法是通过使羧酸衍生物与胺反应来制造酰胺化合物,并且包括在其熔融温度下使羧酸衍生物和胺的反应混合物老化的方法 反应后点或更低。 版权所有(C)2008,JPO&INPIT

    Method for producing dicarboxylic acid, lactone, or mixture thereof
    10.
    发明专利
    Method for producing dicarboxylic acid, lactone, or mixture thereof 有权
    生产二羧酸,乳酸酯或其混合物的方法

    公开(公告)号:JP2011046672A

    公开(公告)日:2011-03-10

    申请号:JP2009198591

    申请日:2009-08-28

    Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a dicarboxylic acid or lactone efficiently which uses a glycerol compound which is a renewable resource as a raw material.
    SOLUTION: The method for producing a dicarboxylic acid, lactone or the mixture thereof comprises the following. (A) A catalyst which contains at least one kind of a metal atom selected from the group consisting of a group 8 metal, group 9 metal, and group 10 metal of the periodic table and (B) a halogen compound are made to be present so that the atomic number ratio of the halogen atom in the halogen compound (B) to the metal atom contained in the catalyst (A) may be 0.1 or more and less than 40, and a glycerol compound expressed by formula (1) is allowed to react with carbon monoxide. In the formula, R
    1 -R
    3 each independently denotes a hydrogen atom, a 1-20C alkyl group or alkenyl group of a straight or branched chain, a -COR
    4 group, or a 1-20C alkyl group or alkenyl group of a straight or branched chain substituted by a specific substituent. R
    4 denotes a 1-20C alkyl group or alkenyl group of a straight or branched chain or a 1-20C alkyl group or alkenyl group of a straight or branched chain substituted by a specific substituent.
    COPYRIGHT: (C)2011,JPO&INPIT

    Abstract translation: 待解决的问题:提供一种使用作为可再生资源的甘油化合物作为原料的有效制备二羧酸或内酯的方法。 解决方案:二羧酸,内酯或其混合物的制备方法包括以下。 (A)含有选自元素周期表第8族金属,第9族金属和第10族金属中的至少一种金属原子的催化剂和(B)卤素化合物存在 使得卤素化合物(B)中的卤素原子与催化剂(A)中所含的金属原子的原子数比可以为0.1以上且小于40,并且允许由式(1)表示的甘油化合物 与一氧化碳反应。 在该式中,R 1和R 2各自独立地表示氢原子,直链或支链的1-20C烷基或链烯基,-COR < SP> 4 基团或由特定取代基取代的直链或支链的1-20C烷基或烯基。 R 4表示直链或支链的1-20C烷基或烯基或被特定取代基取代的直链或支链的1-20C烷基或烯基。 版权所有(C)2011,JPO&INPIT

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