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公开(公告)号：IN6715DEN2014A
公开(公告)日：2015-05-22
申请号：IN6715DEN2014
申请日：2014-08-11
Applicant: KAO CORP
Inventor： WATANABE MASAHIKO , YASHIRO KAI , NISHI TAKAFUMI
IPC: C07D307/46
Abstract: The present invention relates to: a method for producing 5 hydroxymethyl furfural (HMF) which comprises the steps a c described below; and a method for producing 5 hydroxymethyl furfural oxide which comprises the steps a d described below. Each of the methods simply and economically produces high purity 5 hydroxymethyl furfural or an oxide thereof from a starting sugar material. Step a: A step wherein the staring sugar material is subjected to a dehydration reaction in the presence of a reaction solvent thereby producing HMF in the reaction solvent and obtaining a reaction solvent containing HMF. Step b: A step wherein HMF is extracted from the reaction solvent containing HMF which has been obtained in step a into a hydrophobic solvent thereby obtaining a hydrophobic solvent containing HMF. Step c: A step wherein HMF is extracted from the hydrophobic solvent containing HMF which has been obtained in step b into water thereby obtaining an aqueous solution containing HMF. Step d: A step wherein HMF which has been obtained in step c is oxidized.
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2.发明公开
公开(公告)号：EP3048101A4
公开(公告)日：2017-04-26
申请号：EP14845684
申请日：2014-08-26
Applicant: KAO CORP
Inventor： YASHIRO KAI , NOMURA MASATO , OHMAE KAORU , TABUCHI YUKIKO
IPC: C07D307/68 , C07B61/00
CPC classification number: C07D307/68
Abstract: The present invention relates to a process for producing 2,5-furan dicarboxylic acid by subjecting 5-hydroxymethylfurfural to oxidation reaction in the presence of water, oxygen and an activated carbon-supported metal catalyst containing a noble metal, the process including the following steps (1) and (2) in which the steps (1) and (2) are carried out under a pressure of not less than 0.1 MPa and less than 1.0 MPa while maintaining a reaction solution at a pH of not more than 7, and an amount of the oxygen fed until a time at which the step (2) is terminated is not less than 120 mol% and not more than 140 mol% on the basis of the 5-hydroxymethylfurfural charged: step (1): conducting the oxidation reaction at a temperature of not lower than 50°C and not higher than 110°C until a content of the 5-hydroxymethylfurfural in the reaction solution falls within the range of not less than 0 mg/kg and not more than 1,000 mg/kg; and step (2): subjecting the reaction solution obtained after completion of the step (1) to the oxidation reaction at a temperature of not lower than 140°C and not higher than 250°C.
Abstract translation: 本发明涉及在水，氧气和含有贵金属的负载有活性炭的金属催化剂的存在下使5-羟甲基糠醛进行氧化反应来制造2,5-呋喃二羧酸的方法，所述方法包括以下步骤 （1）和（2），其中在不低于0.1MPa的压力下进行步骤（1）和（2），同时将反应溶液保持在不高于7的pH，并且 基于5-羟甲基糠醛加入的步骤（1），步骤（2）终止之前的供氧量不小于120摩尔％且不大于140摩尔％：步骤（1）：进行氧化 在不低于50℃且不高于110℃的温度下进行反应直至反应溶液中的5-羟甲基糠醛的含量落入不小于0mg / kg且不大于1,000mg / kg的范围内 ; 和步骤（2）：在完成步骤（1）后得到的反应溶液在不低于140℃且不高于250℃的温度下进行氧化反应。
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Patent Agency Ranking
公开(公告)号：JP2013212536A
公开(公告)日：2013-10-17
申请号：JP2013000592
申请日：2013-01-07
Inventor： MATSUO TOSHIKI , WATANABE MASAHIKO , YASHIRO KAI
IPC: B22C1/20 , B22C1/22 , C08K5/07 , C08L101/02
CPC classification number: B22C1/2246 , B22C1/224
Abstract: PROBLEM TO BE SOLVED: To provide a binder composition for producing a template capable of improving the final strength of the template, a binder composition for the mold using the same, and a method for producing the mold using the same.SOLUTION: A binder composition for producing a template which comprises a 5-hydroxymethylfurfural composition produced from molasses, and an acid-curable resin. Preferably, the 5-hydroxymethylfurfural composition is produced through a step of subjecting molasses to a dehydration reaction in a solvent in the presence of an acid catalyst to produce a reaction mixture, and a step of extracting the reaction mixture with an organic solvent to produce the 5-hydroxymethylfurfural composition.
Abstract translation: 要解决的问题：提供一种用于制造能够提高模板的最终强度的模板的粘合剂组合物，使用该模板的模具用粘合剂组合物，以及使用其的模具的制造方法。粘合剂组合物 用于制备由糖蜜制备的5-羟甲基糠醛组合物和酸固化树脂的模板。 优选地，5-羟甲基糠醛组合物是通过在酸催化剂的存在下，在溶剂中使糖蜜进行脱水反应以产生反应混合物的步骤制备的，以及用有机溶剂萃取反应混合物以产生 5-羟甲基糠醛组合物。
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公开(公告)号：JP2013116873A
公开(公告)日：2013-06-13
申请号：JP2011265550
申请日：2011-12-05
Inventor： YASHIRO KAI
Abstract: PROBLEM TO BE SOLVED: To provide an alkylether carboxylic acid type surfactant excellent in high foamability, high foam amount and high fresh feeling (stop feeling) at the time of rinsing, and high stability in aqueous solution to various metallic ions.SOLUTION: The surfactant is a polyoxyalkylene alkylether acetic acid expressed by general formula (1): RO-(EO)(PO)-CHCOOM or a salt thereof. In formula, R represents a 6-24C alkyl or alkenyl group; EO represents an ethyleneoxide group; PO represents a propyleneoxide group; m and n each denotes an average addition mole number of EO and PO, respectively, the total (m+n) of m and n is a number of 0.4 to 10, n denotes a number of 0.4-5, and M represents H, an alkali metal, alkaline earth metal (1/2 atom) or an amine.
Abstract translation: 要解决的问题：提供在漂洗时具有优异的高起泡性，高泡沫量和高清新感（停止感），在各种金属离子的水溶液中的稳定性优异的烷基醚羧酸型表面活性剂。 表面活性剂是由通式（1）表示的聚氧化烯烷基醚乙酸：RO-（EO）
（PO） n CO 2或其盐。 在式中，R代表6-24C烷基或链烯基; EO表示环氧乙烷基; PO表示环氧丙烷基; m和n分别表示EO和PO的平均加成摩尔数，m和n的总数（m + n）为0.4〜10的数，n表示数为0.4〜5，M表示H， 碱金属，碱土金属（1/2原子）或胺。 版权所有（C）2013，JPO＆INPIT -
公开(公告)号：JP2013203666A
公开(公告)日：2013-10-07
申请号：JP2012071119
申请日：2012-03-27
Inventor： YASHIRO KAI , WATANABE MASAHIKO , NISHI TAKAFUMI
IPC: C07D307/48 , C07B61/00 , C07D307/68
Abstract: PROBLEM TO BE SOLVED: To provide a method of easily and economically producing a highly pure 5-hydroxymethylfurfural oxide from sugar raw material.SOLUTION: A method of producing a 5-hydroxymethylfurfural oxide includes following processes a-d. In the process a: sugar raw material is subjected to a dehydration reaction in the presence of a reaction solvent to produce 5-hydroxymethylfurfural (HMF) in the reaction solvent, and the reaction solvent including HMF is obtained. In the process a: sugar raw material is subjected to a dehydration reaction in the presence of a reaction solvent to produce 5-hydroxymethylfurfural in the reaction solvent, and the reaction solvent including HMF is obtained. In the process b: HMF is extracted into a hydrophobic solvent from the reaction solvent including HMF obtained in the process a, and the hydrophobic solvent including HMF is obtained. In the process c: HMF is extracted into water from the hydrophobic solvent including HMF obtained in the process b, and an aqueous solution including HMF is obtained. In the process d: HMF obtained in the process c is oxidized.
Abstract translation: 要解决的问题：提供从糖原料中容易且经济地制备高纯度5-羟甲基糠醛氧化物的方法。解决方案：一种制备5-羟甲基糠醛氧化物的方法包括以下方法a-d。 在该方法中：糖原料在反应溶剂存在下进行脱水反应，在反应溶剂中生成5-羟甲基糠醛（HMF），得到包含HMF的反应溶剂。 在该方法中：糖原料在反应溶剂存在下进行脱水反应，在反应溶剂中反应生成5-羟甲基糠醛，得到HMF的反应溶剂。 在该方法中b：HMF从包括在方法a中获得的HMF的反应溶剂中提取到疏水溶剂中，并且获得包括HMF的疏水溶剂。 在方法c中：将HMF从包括在方法b中获得的HMF的疏水性溶剂中萃取到水中，得到包含HMF的水溶液。 在方法d中：在方法c中获得的HMF被氧化。
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公开(公告)号：JP2013203665A
公开(公告)日：2013-10-07
申请号：JP2012071113
申请日：2012-03-27
Inventor： WATANABE MASAHIKO , YASHIRO KAI , NISHI TAKAFUMI
IPC: C07D307/46
Abstract: PROBLEM TO BE SOLVED: To provide a method for manufacturing 5-hydroxymethylfurfural of high purity efficiently and economically by a simple method.SOLUTION: A manufacturing method for 5-hydroxymethylfurfural includes steps (a)-(c) below: (a) a step of subjecting a sugar raw material to a dehydration reaction in the presence of a reaction solvent thereby forming 5-hydroxymethylfurfural in the reaction solvent to obtain the reaction solvent containing 5-hydroxymethylfurfural; (b) a step of extracting 5-hydroxymethylfurfural from the reaction solvent containing 5-hydroxymethylfurfural obtained in the step (a) into a hydrophobic solvent to obtain the hydrophobic solvent containing 5-hydroxymethylfurfural; and (c) a step of extracting 5-hydroxymethylfurfural from the hydrophobic solvent containing 5-hydroxymethylfurfural obtained in the step (b) into water to obtain an aqueous solution containing 5-hydroxymethylfurfural.
Abstract translation: 要解决的问题：提供一种通过简单的方法有效和经济地制备高纯度5-羟甲基糠醛的方法。解决方案：5-羟甲基糠醛的制备方法包括以下步骤（a） - （c）：（a）步骤 在反应溶剂存在下使糖原料进行脱水反应，从而在反应溶剂中形成5-羟甲基糠醛，得到含有5-羟甲基糠醛的反应溶剂; （b）将由步骤（a）得到的含有5-羟甲基糠醛的反应溶剂中的5-羟甲基糠醛提取到疏水性溶剂中，得到含有5-羟甲基糠醛的疏水性溶剂; 和（c）从步骤（b）中得到的含有5-羟甲基糠醛的疏水性溶剂中提取5-羟甲基糠醛的步骤，得到含有5-羟甲基糠醛的水溶液。
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公开(公告)号：JP2013063882A
公开(公告)日：2013-04-11
申请号：JP2011204497
申请日：2011-09-20
Inventor： OKUBO MAKOTO , NAKA YOSHIHITO , YABE KENICHIRO , OKAUCHI NOBUAKI , YASHIRO KAI
Abstract: PROBLEM TO BE SOLVED: To provide a hydraulic composition excellent in initial flowability without causing a curing retardation.SOLUTION: The hydraulic composition contains water, hydraulic powder, a dispersant, and tartronic acid and/or its salt. The content of the tartronic acid and/or its salt is 0.007 to 0.15 pt.wt. based on 100 pts.wt. of the hydraulic composition.
Abstract translation: 要解决的问题：提供初始流动性优异的水硬性组合物，而不会导致固化延迟。 解决方案：水硬性组合物含有水，水硬性粉末，分散剂和丙醇二酸和/或其盐。 丙醇酸和/或其盐的含量为0.007至0.15重量份。 基于100重量 的水硬组合物。 版权所有（C）2013，JPO＆INPIT
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