Abstract:
Process for forming a multi-layer electrochromic structure, the process comprising depositing a film of a liquid mixture onto a surface of a substrate, and treating the deposited film to form an anodic electrochromic layer, the liquid mixture comprising a continuous phase and a dispersed phase, the dispersed phase comprising metal oxide particles, metal alkoxide particles, metal alkoxide oligomers, gels or particles, or a combination thereof having a number average size of at least 5 nm.
Abstract:
Multi-layer electrochromic structures comprising an anodic electrochromic layer comprising a lithium nickel oxide composition on a first substrate, the anodic electrochromic layer comprising lithium, nickel and a Group 6 metal selected from molybdenum, tungsten and a combination thereof, wherein (i) the atomic ratio of lithium to the combined amount of nickel, molybdenum, and tungsten in the anodic electrochromic layer is at least 0.4:1, respectively, (ii) the atomic ratio of the combined amount of molybdenum and tungsten to the combined amount of nickel, molybdenum and tungsten in the anodic electrochromic layer is at least about 0.025:1, respectively, and (iii) the anodic electrochromic layer exhibits an interplanar distance (d-spacing) of at least 2.5 as measured by X-ray diffraction (XRD), comprises at least 0.05 wt.% carbon, and/or has a coloration efficiency absolute value of at least 19 cm2/C.
Abstract:
Multi-layer electrochromic structures comprising an anodic electrochromic layer comprising a lithium nickel oxide composition on a first substrate, the anodic electrochromic layer comprising lithium, nickel and a Group 5 metal selected from niobium, tantalum and a combination thereof, wherein (i) the atomic ratio of lithium to the combined amount of nickel, niobium and tantalum in the anodic electrochromic layer is at least 0.4:1, respectively, (ii) the atomic ratio of the combined amount of niobium and tantalum to the combined amount of nickel, niobium and tantalum in the anodic electrochromic layer is at least about 0.025:1, respectively, and (iii) the anodic electrochromic layer exhibits an interplanar distance (d-spacing) of at least 2.5 as measured by X-ray diffraction (XRD), comprises at least 0.05 wt.% carbon, and/or has a coloration efficiency absolute value of at least 19 cm 2 /C.
Abstract:
An electrochromic multi-layer stack is provided. The multi-layer stack includes an electrochromic multi-layer stack having a first substrate, a first electrically conductive layer, a first electrode layer, an ion conductor layer, a second substrate, a second electrically conductive layer, and a second electrode layer. The multi-layer stack includes a redox element, wherein the redox element is electrically isolated from the first and second electrically conductive layers and the first and second electrode layer and is laterally adjacent to either the first electrically conductive layer and the first electrode, or the second electrically conductive layer and the second electrode layer. A method for controlling an electrochromic device is also provided.
Abstract:
Process for forming a multi-layer electrochromic structure, the process comprising depositing a film of a liquid mixture onto a surface of a substrate, and treating the deposited film to form an anodic electrochromic layer, the liquid mixture comprising a continuous phase and a dispersed phase, the dispersed phase comprising metal oxide particles, metal hydroxide particles, metal alkoxide particles, metal alkoxide oligomers, gels or particles, or a combination thereof having a number average size of at least 5 nm.
Abstract:
Multi-layer devices comprising a layer of an electrochromic lithium nickel oxide composition on a first substrate, the lithium nickel oxide composition comprising lithium, nickel and a Group 5 metal selected from niobium, tantalum and a combination thereof.
Abstract:
An electrochromic multi-layer stack is provided. The multi-layer stack includes an electrochromic multi-layer stack having a first substrate, a first electrically conductive layer, a first electrode layer, an ion conductor layer, a second substrate, a second electrically conductive layer, and a second electrode layer. The multi-layer stack includes a redox element, wherein the redox element is electrically isolated from the first and second electrically conductive layers and the first and second electrode layer and is laterally adjacent to either the first electrically conductive layer and the first electrode, or the second electrically conductive layer and the second electrode layer. A method for controlling an electrochromic device is also provided.