Abstract:
PROBLEM TO BE SOLVED: To provide an anode material for a lithium secondary battery having high discharge capacity, excellent cycle characteristic and high charge discharge efficiency, to provide a method for manufacturing the anode material, and to provide a lithium secondary battery including the material.SOLUTION: A positive active material for the lithium secondary battery is composed of a lithium manganese phosphate based compound including one metal element selected among Mg, Ti, Ni, Co, and Fe and having phosphorus a part of which is substituted with arsenic. The positive active material is manufactured by reacting a lithium oxide, a manganese oxide, a phosphorus oxide, a chelate agent, and water in a hydrothermal reactor, and adding a substitution product of the above elements and arsenic substitution to react together.
Abstract:
Offenbart sind Zusammensetzung und Verfahren zur Herstellung einer Kathode für einen Akkumulator, wobei ein Fluorophosphat der Formel LixNa2-xMnPO4F als ein Elektrodenmaterial verwendet wird. LixNa2-xMnPO4F wird durch partielle Substitution einer Natriumstelle mit Lithium durch ein chemisches Verfahren hergestellt. LixNa2-xMnPO4F, das gemäß der Erfindung hergestellt wird, stellt ein Kathodenmaterial für eine Lithiumbatterie mit verbesserter elektrochemischer Aktivität bereit.
Abstract:
PROBLEM TO BE SOLVED: To provide a positive electrode material for a secondary battery containing an electrode material composed of a manganese fluorophosphate containing lithium or sodium, and a method for manufacturing the same.SOLUTION: A positive electrode material for a secondary battery has a particle size of 1 nm or more and 100 nm or less, shows a potential flat part in the region of 3.7 to 4.0 V of the discharge curve, is coated with carbon to enhance conductivity, and contains a compound represented by the formula: AMnPOF, where A represents Li or Na, or a mixture thereof, and 0
Abstract:
PROBLEM TO BE SOLVED: To provide a positive electrode material for a lithium secondary battery containing a lithium manganese fluorophosphate (LiMnPOF), and a method for manufacturing the same.SOLUTION: The method for manufacturing the positive electrode material for a lithium secondary battery comprises the steps of: (i) synthesizing a positive electrode material NaMnPOF by applying pretreatment to a mixture obtained by homogeneously mixing a sodium (Na) oxide or a precursor thereof, a manganese (Mn) oxide or a precursor thereof, a phosphorus (P) oxide or a precursor thereof, and a fluoride (F) or a precursor thereof by means of a ball mill, and firing the mixture; and (ii) synthesizing LiMnPOF by intercalating lithium into the positive electrode material synthesized in the previous step, by an ion exchange method.
Abstract:
Ein Kathodenmaterial für einen Akkumulator und ein Herstellungsverfahren desselben sind offenbart. Das Kathodenmaterial enthält einen Lithiummanganphosphat LiMnPO4/Natriummanganfluorophosphat Na2MnPO4F-Verbundstoff, bei welchem LiMnPO4 und Na2MnPO4F verschiedene Kristallstrukturen aufweisen. Zudem kann das Verfahren zum Herstellen des Kathodenmaterials in einem einzigen Schritt durch eine Hydrothermalsynthese erfolgen, was die Produktionszeit und Produktionskosten erheblich verringert. Zudem liefert die Offenbarung, dass die elektrische Leitfähigkeit des Kathodenmaterials durch Kohlenstoffbeschichtung verbessert werden kann und liefert dadurch ein Kathodenmaterial mit einer ausgezeichneten elektrochemischen Aktivität.
Abstract:
The present invention relates to a cathode active material for a lithium secondary battery and a preparation method thereof, and particularly, to a cathode active material for a lithium secondary battery having improved battery characteristics because of manganese phosphate uniformly coated on the surface of a Ni-rich cathode active material, and a preparation method thereof. According to the present invention, because manganese phosphate is uniformly coated on the surface of the Ni-rich cathode active material, a side reaction of the electrolyte is inhibited and a lithium secondary battery having excellent power characteristics, high temperature cycle life characteristics, and thermal stability can be prepared.