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公开(公告)号：WO2018204575A1
公开(公告)日：2018-11-08
申请号：PCT/US2018/030786
申请日：2018-05-03
Applicant: LEHIGH TECHNOLOGIES, INC.
Inventor： ROSENMAYER, Charles
Abstract: Thermoplastic elastomers comprising micronized or pulverized rubber powders are disclosed having physical properties equivalent to those of virgin thermoplastic elastomers. For example, the use of finer mesh MRP (e.g., particles of size that would pass through 40 mesh or smaller) to manufacture thermoplastic elastomers results in thermoplastic elastomers that have physical properties equivalent to those of virgin thermoplastic elastomers. Similarly, the use of an glycidyl functional terpolymer (optionally in combination with trimellitic anhydride or "TMA") to manufacture thermoplastic elastomers comprising MRP results in thermoplastic elastomers that have physical properties equivalent to those of virgin thermoplastic elastomers. Moreover, the use of styrene-ethylene/butylene-styrene thermoplastic (e.g., "SEBS") in place of the base polypropylene thermoplastic elastomer to manufacture thermoplastic elastomers comprising MRP also results in thermoplastic elastomers that have physical properties equivalent to those of virgin thermoplastic elastomers.
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2.发明申请METHODS OF FUNCTIONALIZING RECLAIMED ELASTOMER MATERIAL AND COMPOSITIONS COMPRISING THE SAME 审中-公开功能化回收的弹性体材料的方法及其组合物
公开(公告)号：WO2014071181A1
公开(公告)日：2014-05-08
申请号：PCT/US2013/068051
申请日：2013-11-01
Applicant: LEHIGH TECHNOLOGIES, INC.
Inventor： ROSENMAYER, Charles , PAPP, Frank , BARTON, Alan , MURTHY, Kedar
CPC classification number: C08L9/06 , C08J11/10 , C08J11/28 , C08J2319/00 , C08J2321/00 , C08K3/013 , C08K5/0025 , C08L17/00 , C08L19/003 , C08L21/00 , Y02W30/702 , Y02W30/706 , C08K3/0033
Abstract: A method of functionalizing reclaimed elastomer material is described. The method involves subjecting particles of the reclaimed elastomer material to shear at temperatures less than 100 C such that inter-chain bonds of the reclaimed elastomer material are cleaved wherein the particles of the reclaimed elastomer material have a size of 60 mesh or smaller. The reclaimed elastomer material can be subjected to shear in the presence of a modifier which selectively promotes the cleavage of inter-chain bonds in the reclaimed elastomer material. A functionalized reclaimed elastomer material made by a method as described above and an elastomer compound which comprises the functionalized reclaimed elastomer material are also described.
Abstract translation: 描述了回收弹性体材料的官能化方法。 该方法包括使回收的弹性体材料的颗粒在低于100℃的温度下剪切，使得再生的弹性体材料的链间断裂，其中再生弹性体材料的颗粒具有60目或更小的尺寸。 回收的弹性体材料可以在选择性地促进再生弹性体材料中的链间键断裂的改性剂存在下进行剪切。 还描述了通过上述方法制备的官能化再生弹性体材料和包含官能化再生弹性体材料的弹性体化合物。
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Patent Agency Ranking3.发明申请ELASTOMERIC COMPOSITIONS COMPRISING RECLAIMED VULCANIZED ELASTOMER PARTICLES OF BROAD SIZE DISTRIBUTION AND CHEMICALLY MODIFIED VULCANIZED ELASTOMER PARTICLES 审中-公开包含大尺寸分布和化学改性的弹性体弹性体颗粒的回收的弹性体弹性体颗粒的弹性组合物
公开(公告)号：WO2012170932A1
公开(公告)日：2012-12-13
申请号：PCT/US2012/041727
申请日：2012-06-08
Applicant: LEHIGH TECHNOLOGIES, INC. , ROSENMAYER, Charles , PAPP, Frank
Inventor： ROSENMAYER, Charles , PAPP, Frank
IPC: B29B9/00
CPC classification number: C08L9/06 , B29B17/0408 , B29K2021/00 , B32B5/16 , B32B25/042 , B32B2605/00 , C08J3/12 , C08J2321/02 , C08K3/013 , C08L7/00 , C08L9/00 , C08L9/02 , C08L17/00 , C08L19/003 , C08L21/00 , Y02W30/625 , Y10T428/2982 , C08K3/0033
Abstract: Elastomer compositions comprising uncured elastomer and reclaimed elastomer are described. In one embodiment, the compositions comprise reclaimed elastomer material (micronized rubber powder) of broad particle size distribution, which is less expensive than traditional reclaimed elastomer material with narrow particle size distribution. Further, compositions comprising reclaimed elastomer materials with broad particle size distribution perform comparably to those comprising reclaimed elastomer materials with narrow particle size distribution. In other embodiments, the compositions comprise both vulcanized and devulcanized elastomer materials. Advantageously, by using a combination of vulcanized and devulcanized material, it is possible to incorporate a greater percentage by weight of reclaimed material in to an elastomer composition, thus providing additional cost savings while maintaining high levels of mechanical properties. Further, the use of the reclaimed material reduces landfill waste resulting in a more environmentally friendly product.
Abstract translation: 描述了包含未固化的弹性体和再生弹性体的弹性体组合物。 在一个实施方案中，组合物包含具有宽粒度分布的再生弹性体材料（微粉化橡胶粉末），其比具有窄粒度分布的传统回收弹性体材料便宜。 此外，包含具有宽粒度分布的再生弹性体材料的组合物与包含具有窄粒度分布的再生弹性体材料的组合物相当。 在其它实施方案中，组合物包含硫化和脱硫弹性体材料。 有利地，通过使用硫化和脱硫材料的组合，可以将更大百分比的回收材料加入到弹性体组合物中，从而在保持高水平的机械性能的同时提供额外的成本节约。 此外，回收材料的使用减少了填埋废物，从而产生了更环保的产品。
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4.发明公开
公开(公告)号：EP2718075A1
公开(公告)日：2014-04-16
申请号：EP12797606.6
申请日：2012-06-08
Applicant: Lehigh Technologies, Inc.
Inventor： ROSENMAYER, Charles , PAPP, Frank
IPC: B29B9/00
CPC classification number: C08L9/06 , B29B17/0408 , B29K2021/00 , B32B5/16 , B32B25/042 , B32B2605/00 , C08J3/12 , C08J2321/02 , C08K3/013 , C08L7/00 , C08L9/00 , C08L9/02 , C08L17/00 , C08L19/003 , C08L21/00 , Y02W30/625 , Y10T428/2982 , C08K3/0033
Abstract: Elastomer compositions comprising uncured elastomer and reclaimed elastomer are described. In one embodiment, the compositions comprise reclaimed elastomer material (micronized rubber powder) of broad particle size distribution, which is less expensive than traditional reclaimed elastomer material with narrow particle size distribution. Further, compositions comprising reclaimed elastomer materials with broad particle size distribution perform comparably to those comprising reclaimed elastomer materials with narrow particle size distribution. In other embodiments, the compositions comprise both vulcanized and devulcanized elastomer materials. Advantageously, by using a combination of vulcanized and devulcanized material, it is possible to incorporate a greater percentage by weight of reclaimed material in to an elastomer composition, thus providing additional cost savings while maintaining high levels of mechanical properties. Further, the use of the reclaimed material reduces landfill waste resulting in a more environmentally friendly product.
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公开(公告)号：EP2718075B1
公开(公告)日：2018-08-15
申请号：EP12797606.6
申请日：2012-06-08
Applicant: Lehigh Technologies, Inc.
Inventor： ROSENMAYER, Charles , PAPP, Frank
IPC: B29B9/00
CPC classification number: C08L9/06 , B29B17/0408 , B29K2021/00 , B32B5/16 , B32B25/042 , B32B2605/00 , C08J3/12 , C08J2321/02 , C08K3/013 , C08L7/00 , C08L9/00 , C08L9/02 , C08L17/00 , C08L19/003 , C08L21/00 , Y02W30/625 , Y10T428/2982 , C08K3/0033
Abstract: Elastomer compositions comprising uncured elastomer and reclaimed elastomer are described. In one embodiment, the compositions comprise reclaimed elastomer material (micronized rubber powder) of broad particle size distribution, which is less expensive than traditional reclaimed elastomer material with narrow particle size distribution. Further, compositions comprising reclaimed elastomer materials with broad particle size distribution perform comparably to those comprising reclaimed elastomer materials with narrow particle size distribution. In other embodiments, the compositions comprise both vulcanized and devulcanized elastomer materials. Advantageously, by using a combination of vulcanized and devulcanized material, it is possible to incorporate a greater percentage by weight of reclaimed material in to an elastomer composition, thus providing additional cost savings while maintaining high levels of mechanical properties. Further, the use of the reclaimed material reduces landfill waste resulting in a more environmentally friendly product.
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6.发明授权
公开(公告)号：EP2914635B1
公开(公告)日：2020-06-24
申请号：EP13851543.2
申请日：2013-11-01
Applicant: Lehigh Technologies, Inc.
Inventor： ROSENMAYER, Charles , PAPP, Frank , BARTON, Alan , MURTHY, Kedar
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7.发明公开METHODS OF FUNCTIONALIZING RECLAIMED ELASTOMER MATERIAL AND COMPOSITIONS COMPRISING THE SAME 审中-公开恢复的弹性体材料和组合物的方法官能THEREFORE
公开(公告)号：EP2914635A1
公开(公告)日：2015-09-09
申请号：EP13851543.2
申请日：2013-11-01
Applicant: Lehigh Technologies, Inc.
Inventor： ROSENMAYER, Charles , PAPP, Frank , BARTON, Alan , MURTHY, Kedar
Abstract: A method of functionalizing reclaimed elastomer material is described. The method involves subjecting particles of the reclaimed elastomer material to shear at temperatures less than 100° C. such that inter-chain bonds of the reclaimed elastomer material are cleaved wherein the particles of the reclaimed elastomer material have a size of 60 mesh or smaller. The reclaimed elastomer material can be subjected to shear in the presence of a modifier which selectively promotes the cleavage of inter-chain bonds in the reclaimed elastomer material. A functionalized reclaimed elastomer material made by a method as described above and an elastomer compound which comprises the functionalized reclaimed elastomer material are also described.
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