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公开(公告)号:WO2010028267A2
公开(公告)日:2010-03-11
申请号:PCT/US2009056076
申请日:2009-09-04
Applicant: LUMMUS TECHNOLOGY INC , BASF CATALYSTS LLC , RAMACHANDRAN BALA , CHOI SUKWON , GARTSIDE ROBERT J , KLEINDIENST SHANE , RUETTINGER WOLFGANG , ALERASOOL SAEED
Inventor: RAMACHANDRAN BALA , CHOI SUKWON , GARTSIDE ROBERT J , KLEINDIENST SHANE , RUETTINGER WOLFGANG , ALERASOOL SAEED
CPC classification number: B01J27/236 , B01J23/007 , B01J23/30 , B01J35/0006 , B01J37/0201 , B01J37/04 , C07C5/2512 , C07C6/04 , C07C2521/04 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/10 , C07C2523/20 , C07C2523/22 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2523/44 , C07C2523/46 , C07C2523/755 , C07C2527/24 , Y02P20/52 , C07C11/08 , C07C11/06
Abstract: A process for the production of propylene, the process including: contacting ethylene and a hydrocarbon stream comprising 1-butene and 2-butene with a bifunctional isomerization-metathesis catalyst to concurrently isomerizes 1-butene to 2-butene and to form a metathesis product comprising propylene; wherein the bifunctional isomerization- metathesis catalyst comprises: a catalyst compound may include at least one element selected from tungsten, tantalum, niobium, molybdenum, nickel, palladium, osmium, iridium, rhodium, vanadium, ruthenium, and rhenium for providing metathesis activity on a support comprising at least one element from Group IA, HA, HB, and IIIA of the Periodic Table of the Elements; wherein an exposed surface area of the support provides both isomerization activity for the isomerization of 1 -butene to 2-butene; and reactive sites for the adsorption of catalyst compound poisons. In other embodiments, the catalyst compound may include at least one element selected from aluminum, gallium, iridium, iron, molybdenum, nickel, niobium, osmium, palladium, phosphorus, rhenium, rhodium, ruthenium, tantalum, titanium, tungsten, and vanadium.
Abstract translation: 一种生产丙烯的方法,所述方法包括:使乙烯和包含1-丁烯和2-丁烯的烃流与双功能异构化复分解催化剂接触以同时异构化1-丁烯成2-丁烯并形成复分解产物,所述复分解产物包含 丙烯; 其中所述双功能异构化复分解催化剂包含:催化剂化合物可包括选自钨,钽,铌,钼,镍,钯,锇,铱,铑,钒,钌和铼中的至少一种元素, 包含至少一种元素周期表IA,IIA,IIB和IIIA族元素的载体; 其中载体的暴露表面积为1-丁烯异构化为2-丁烯提供了异构化活性; 和用于吸附催化剂化合物毒物的反应位点。 在其他实施方案中,催化剂化合物可以包括选自铝,镓,铱,铁,钼,镍,铌,锇,钯,磷,铼,铑,钌,钽,钛,钨和钒中的至少一种元素。
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公开(公告)号:BRPI0918229A2
公开(公告)日:2016-03-01
申请号:BRPI0918229
申请日:2009-09-04
Applicant: BASF CORP E BASF AG , LUMMUS TECHNOLOGY INC
Inventor: RAMACHANDRAN BALA , GARTSIDE ROBERT J , ALERASOOL SAEED , KLEINDIENST SHANE , CHOI SUKWON , RUETTINGER WOLFGANG
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公开(公告)号:AR078212A1
公开(公告)日:2011-10-26
申请号:ARP090103421
申请日:2009-09-04
Applicant: BASF CATALYSTS LLC , LUMMUS TECHNOLOGY INC
Inventor: GARTSIDE ROBERT J , KLEINDIENST SHANE , ALERASOOL SAEED , RUETTINGER WOLFGANG , CHOI SUKWON , RAMACHANDRA BALA
Abstract: Un proceso para la produccion de propileno, que incluye: poner en contacto etileno y una corriente de hidrocarburo que comprende 1-buteno y 2-buteno con un catalizador para isomerizacion y metátesis bifuncional para - de manera concurrente - isomerizar 1-buteno a 2-buteno y para formar un producto de metátesis que comprende propileno; en donde el catalizador para isomerizacion y metátesis bifuncional comprende: un compuesto catalizador que comprende al menos un elemento seleccionado de tungsteno, tántalo, niobio, molibdeno, níquel, paladio, osmio, iridio, rodio, vanadio, rutenio y renio para proveer actividad de metátesis sobre un soporte que comprende al menos un elemento del Grupo IA, IIA, IIB y IIIA de la Tabla Periodica de los Elementos; en donde un área de superficie expuesta del soporte provee tanto actividad de isomerizacion para la isomerizacion de 1-buteno a 2-buteno, como sitios reactivos para la adsorcion de los toxicos de los compuestos catalizadores. En otras formas de realizacion, el compuesto catalizador puede incluir al menos un elemento seleccionado de aluminio, galio, iridio, hierro, molibdeno, níquel, niobio, osmio, paladio, fosforo, renio, rodio, rutenio, tántalo, titanio, tungsteno y vanadio.
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公开(公告)号:MX2011002087A
公开(公告)日:2011-06-09
申请号:MX2011002087
申请日:2009-09-04
Applicant: LUMMUS TECHNOLOGY INC
Inventor: GARTSIDE ROBERT J , RAMACHANDRAN BALA , CHOI SUKWON , KLEINDIENST SHANE , RUETTINGER WOLFGANG , ALERASOOL SAEED
Abstract: Se describe un proceso para la producción de propileno, el proceso incluye: poner en contacto etileno y una corriente de hidrocarburo que comprende 1-buteno y 2-buteno con un catalizador, de isomerización-metátesis bifuncional para isomerizar concurrentemente 1-buteno a 2-buteno y para formar un producto de metátesis que comprende propileno; en donde el catalizador de isomerización-metátesis bifuncional comprende: un compuesto catalítico que puede. incluir por lo menos un elemento seleccionado de tungsteno, tantalio, niobio, molibdeno, níquel, paladio, osmio, iridio, rodio, vanadio, rutenio y renio para proveer actividad de metátesis sobre un soporte que comprende por lo menos un elemento del Grupo lA, IIA, lIB y lIlA de la Tabla Periódica de los Elementos; en donde el área superficial expuesta del soporte provee tanto actividad de isomerización para la isomerización de 1-buteno a 2-buteno y sitios reactivos para la adsorción de veneno de compuesto catalítico. En otras modalidades, el compuesto catalítico puede incluir por lo menos un elemento seleccionado de aluminio, galio, iridio, hierro, molibdeno, níquel, niobio, osmio, paladio, fósforo, renio, rodio, rutenio, tantalio, titanio, tungsteno y vanadio.
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公开(公告)号:CL2009001815A1
公开(公告)日:2009-12-04
申请号:CL2009001815
申请日:2009-09-04
Applicant: LUMMUS TECHNOLOGY INC , BASF CORP
Inventor: GARTSIDE ROBERT J , RAMACHANDRAN BALA , CHOI SUKWON , KLEINDIENST SHANE , RUETTINGER WOLFGANG , ALERASOOL SAEED
Abstract: Proceso para la producción de propileno que comprende poner en contacto etileno y una corriente de hidrocarburo que comprende 1-buteno y 2-buteno con un catalizador para isomerización y metátesis bifuncional; el catalizador en sí; y proceso para su preparación.
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公开(公告)号:PH12015500054A1
公开(公告)日:2018-02-05
申请号:PH12015500054
申请日:2015-01-09
Applicant: LUMMUS TECHNOLOGY INC
Inventor: RAMACHANDRAN BALA , CHOI SUKWON , GARTSIDE ROBERT J , KLEINDIENST SHANE , RUETTINGER WOLFGANG , ALERASOOL SAEED
Abstract: A process for the production of propylene, the process including: contacting ethylene and a hydrocarbon stream comprising 1-butene and 2-butene with a bifunctional isomerization-metathesis catalyst to concurrently isomerizes 1-butene to 2-butene and to form a metathesis product comprising propylene; wherein the bifunctional isomerization- metathesis catalyst comprises: a catalyst compound may include at least one element selected from tungsten, tantalum, niobium, molybdenum, nickel, palladium, osmium, iridium, rhodium, vanadium, ruthenium, and rhenium for providing metathesis activity on a support comprising at least one element from Group IA, HA, HB, and IIIA of the Periodic Table of the Elements; wherein an exposed surface area of the support provides both isomerization activity for the isomerization of 1 -butene to 2-butene; and reactive sites for the adsorption of catalyst compound poisons. In other embodiments, the catalyst compound may include at least one element selected from aluminum, gallium, iridium, iron, molybdenum, nickel, niobium, osmium, palladium, phosphorus, rhenium, rhodium, ruthenium, tantalum, titanium, tungsten, and vanadium.
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公开(公告)号:MY180736A
公开(公告)日:2020-12-08
申请号:MYPI2014001226
申请日:2009-09-04
Applicant: LUMMUS TECHNOLOGY INC , BASF CORP
Inventor: RUETTINGER WOLFGANG , GARTSIDE ROBERT J , RAMACHANDRAN BALA , KLEINDIENST SHANE , ALERASOOL SAEED , CHOI SUKWON
Abstract: A process for the production of propylene, the process including: contacting ethylene and a hydrocarbon stream comprising 1-butene and 2-butene with a bifunctional isomerization-metathesis catalyst to concurrently isomerizes 1-butene to 2-butene and to form a metathesis product comprising propylene; wherein the bifunctional isomerization- metathesis catalyst comprises: a catalyst compound may include at least one element selected from tungsten, tantalum, niobium, molybdenum, nickel, palladium, osmium, iridium, rhodium, vanadium, ruthenium, and rhenium for providing metathesis activity on a support comprising at least one element from Group IA, IIA, IIB, and IIIA of the Periodic Table of the Elements; wherein an exposed surface area of the support provides both isomerization activity for the isomerization of 1-butene to 2-butene; and reactive sites for the adsorption of catalyst compound poisons. In other embodiments, the catalyst compound may include at least one element selected from aluminum, gallium, iridium, iron, molybdenum, nickel, niobium, osmium, palladium, phosphorus, rhenium, rhodium, ruthenium, tantalum, titanium, tungsten, and vanadium. (Figure 1)
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公开(公告)号:PH12015500054B1
公开(公告)日:2018-02-05
申请号:PH12015500054
申请日:2015-01-09
Applicant: LUMMUS TECHNOLOGY INC
Inventor: RAMACHANDRAN BALA , CHOI SUKWON , GARTSIDE ROBERT J , KLEINDIENST SHANE , RUETTINGER WOLFGANG , ALERASOOL SAEED
Abstract: A process for the production of propylene, the process including: contacting ethylene and a hydrocarbon stream comprising l-butene and 2-butene with a bifunctional isomerization-metathesis catalyst to concurrently isomerizes 1-butene to 2- butene and to form a metathesis product comprising propylene; wherein the bifunctional isomerization-metathesis catalyst comprises: a catalyst compound may include at least one element selected from tungsten, tantalum,niobium, molybdenum, nickel, palladium, osmium, iridium, rhodium, vanadium, ruthenium, and rhenium for providing metathesis activity on a support comprising at least one element from Group IA, IIA, IIB, and IIIA of the Periodic Table of the Elements; wherein an exposed surface area of the support provides both isomerization activity for the isomerization of 1-butene to 2-butene; and reactive sites for the adsorption of catalyst compound poisons. In other embodiments, the catalyst compound may include at least one element selected from aluminum, gallium, iridium, iron, molybdenum, nickel, niobium, osmium, palladium, phosphorus, rhenium, rhodium, ruthenium, tantalum, titanium, tungsten, and vanadium.
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公开(公告)号:CA2733601C
公开(公告)日:2014-08-05
申请号:CA2733601
申请日:2009-09-04
Applicant: LUMMUS TECHNOLOGY INC , BASF CORP
Inventor: RAMACHANDRAN BALA , CHOI SUKWON , GARTSIDE ROBERT J , KLEINDIENST SHANE , RUETTINGER WOLFGANG , ALERASOOL SAEED
Abstract: A process for the production of propylene, the process including: contacting ethylene and a hydrocarbon stream comprising 1-butene and 2-butene with a bifunctional isomerization-metathesis catalyst to concurrently isomerizes 1-butene to 2-butene and to form a metathesis product comprising propylene; wherein the bifunctional isomerization- metathesis catalyst comprises: a catalyst compound may include at least one element selected from tungsten, tantalum, niobium, molybdenum, nickel, palladium, osmium, iridium, rhodium, vanadium, ruthenium, and rhenium for providing metathesis activity on a support comprising at least one element from Group IA, HA, HB, and IIIA of the Periodic Table of the Elements; wherein an exposed surface area of the support provides both isomerization activity for the isomerization of 1-butene to 2-butene; and reactive sites for the adsorption of catalyst compound poisons. In other embodiments, the catalyst compound may include at least one element selected from aluminum, gallium, iridium, iron, molybdenum, nickel, niobium, osmium, palladium, phosphorus, rhenium, rhodium, ruthenium, tantalum, titanium, tungsten, and vanadium.
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公开(公告)号:ZA201102479B
公开(公告)日:2011-12-28
申请号:ZA201102479
申请日:2011-04-04
Applicant: LUMMUS TECHNOLOGY INC , BASF CORP
Inventor: RAMACHANDRAN BALA , CHOI SUKWON , GARTSIDE ROBERT J , KLEINDIENST SHANE , RUETTINGER WOLFGANG , ALERASOOL SAEED
IPC: B01J20060101 , C07C20060101
Abstract: A process for the production of propylene, the process including: contacting ethylene and a hydrocarbon stream comprising 1-butene and 2-butene with a bifunctional isomerization-metathesis catalyst to concurrently isomerizes 1-butene to 2-butene and to form a metathesis product comprising propylene; wherein the bifunctional isomerization-metathesis catalyst comprises: a catalyst compound may include at least one element selected from tungsten, tantalum, niobium, molybdenum, nickel, palladium, osmium, iridium, rhodium, vanadium, ruthenium, and rhenium for providing metathesis activity on a support comprising at least one element from Group IA, IIA, IIB, and IIIA of the Periodic Table of the Elements; wherein an exposed surface area of the support provides both isomerization activity for the isomerization of 1-butene to 2-butene; and reactive sites for the adsorption of catalyst compound poisons. In other embodiments, the catalyst compound may include at least one element selected from aluminum, gallium, iridium, iron, molybdenum, nickel, niobium, osmium, palladium, phosphorus, rhenium, rhodium, ruthenium, tantalum, titanium, tungsten, and vanadium.
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