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公开(公告)号:KR840000373B1
公开(公告)日:1984-03-27
申请号:KR800003172
申请日:1980-08-09
Applicant: MITSUI TOATSU CHEMICALS
Inventor: KAWAI YOICHI , MAKI MASAMI , MIYAMOTO MASAYOSHI , SASAGAWA KATSUYOSHI , UEDA HOZMI
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公开(公告)号:FR2554821A1
公开(公告)日:1985-05-17
申请号:FR8417149
申请日:1984-11-09
Applicant: MITSUI TOATSU CHEMICALS , MITSUI TOATSU CHEMICALS
Inventor: KANEMURA YOSHINOBU , IMAI MASAO , YOSHINOBU KANEMURA MASAO IMAI ET KATSUYOSHI SASAGAWA , SASAGAWA KATSUYOSHI
IPC: C08F18/00 , C08F18/02 , C08F212/00 , C08F212/08 , C08F218/00 , C08F218/10 , C08F218/12 , C08F220/10 , C08F220/12 , G02B1/04 , C08F218/04 , C08F220/18
Abstract: L'INVENTION CONCERNE UNE RESINE POUR DES LENTILLES A HAUTE REFRACTIVITE, FORMEE PAR COPOLYMERISATION D'AU MOINS UN CARBONATE REPRESENTE PAR LA FORMULE GENERALE : (CF DESSIN DANS BOPI) OU X EST PAR EXEMPLE UN ATOME D'HYDROGENE, ET R EST PAR EXEMPLE UN ATOME D'HYDROGENE, AVEC AU MOINS UN MONOMERE MONOFONCTIONNEL REPRESENTE PAR LA FORMULE GENERALE : (CF DESSIN DANS BOPI) OU R EST PAR EXEMPLE UN ATOME D'HYDROGENE ET Y REPRESENTE PAR EXEMPLE UN RADICAL : (CF DESSIN DANS BOPI) OU X EST PAR EXEMPLE UN ATOME DE CHLORE, Q EST UN ENTIER DE 0 A 5, AINSI QUE DES LENTILLES A REFRACTIVITE ELEVEE FABRIQUEES A PARTIR D'UNE TELLE RESINE.
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公开(公告)号:DE69028329T2
公开(公告)日:1997-03-20
申请号:DE69028329
申请日:1990-03-01
Applicant: MITSUI TOATSU CHEMICALS
Inventor: SUZUKI TOSHIYUKI , SASAGAWA KATSUYOSHI , IMAI MASAO , KANEMURA YOSHINOBU
IPC: C07C333/04 , C07D251/34 , C07D493/10 , C08F212/14 , C08F212/34 , G02B1/04 , G11B7/253 , C09D125/18 , C07C271/06 , G03C11/08 , G11B7/24
Abstract: The present invention relates to a high surface hardness transparent resin having excellent scratch resistance, heat resistance and chemical resistance, a glazing material, a protective cover for display devices, an optical lens and a hard coat material comprising the aforesaid resin, and a novel polymerizable monomer which is useful as a raw material of the above-mentioned resin. The monomer is represented by the formula (I) (wherein R is an aliphatic residue having or not having an halogen atom, an oxygen atom, an alicyclic ring, a heterocyclic ring or an aromatic ring, an alicyclic residue, or a heterocyclic residue, n is an interger of 1 to 4, when n = 1 X is oxygen or sulfur, when n>/=2, X's are all oxygen or all sulfur, one X is oxygen while the other X or X's are sulfur, one X is sulfur while the other X or X's are oxygen, or two X's are oxygen while the other X's are sulfur). The aforesaid high surface hardness transparent resin comprises a crosslinked polymer prepared by copolymerizing a monomer (A) represented by the formula (I) and a monomer (B) having, in one molecule, m functional groups of at least one kind selected from the group consisting of CH2=CH-C(O)-O-, CH2=C(CH3)-C(O)-O- and where (n+m) is an integer of 3 or more. s
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公开(公告)号:DE69205764T2
公开(公告)日:1996-06-27
申请号:DE69205764
申请日:1992-08-05
Applicant: MITSUI TOATSU CHEMICALS
Inventor: KANEMURA YOSHINOBU , SASAGAWA KATSUYOSHI , KOBAYASHI SEIISHI
IPC: C07C321/14 , C08G18/38 , G02B1/04 , C07C319/14
Abstract: A mercapto compound represented by the following formula (1): is obtained by reacting, in the presence of a mineral acid, thiourea with a compound represented by the following formula (2): wherein X means a hydroxyl group or a chlorine or bromine atom, and then adding a base to alkalinize the reaction mixture so that the reaction product is hydrolyzed. Further, a sulfur-containing urethane resin obtained by reacting a mercapto compound represented by the formula (1) with at least one cyanate compound selected from the group consisting of polyisocyanate compounds, polyisothiocyanate compounds and isocyanategroup-containing isothiocyanate compounds and a lens made of the resin are colorless and transparent, have high refractive index and low dispersion characteristics, and are excellent especially in heat resistance.
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公开(公告)号:DE69021127D1
公开(公告)日:1995-08-31
申请号:DE69021127
申请日:1990-05-18
Applicant: MITSUI TOATSU CHEMICALS
Inventor: HASEYAMA RYUJI , HAYASHI KOUZOU , KURODA KAZUYUKI , SASAGAWA KATSUYOSHI , KANO TAISAKU , SHIKAI KIYOSHI
IPC: C07D251/34 , C08G18/62 , C08G18/76 , C08G18/79 , C08L75/02
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公开(公告)号:DE69011796T2
公开(公告)日:1995-04-20
申请号:DE69011796
申请日:1990-10-04
Applicant: MITSUI TOATSU CHEMICALS
Inventor: KANEMURA YOSHINOBU , SASAGAWA KATSUYOSHI , IMAI MASAO , SUZUKI TOSHIYUKI
Abstract: A resin for urethane lenses is here disclosed which is obtained by reacting an alicyclic isocyanate compound represented by the formula (I) and/or an alicyclic isocyanate compound represented by the formula (II) with at least one active hydrogen compound selected from polyol compounds, polythiol compounds except 1,2-bis[(2-mercaptoethyl)thio]-3-mercaptopropane, and thiol compounds having a hydroxyl group. In addition, lenses comprising this resin and processes for the preparation of the resin and the lenses are also disclosed herein.
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公开(公告)号:DE3784020T2
公开(公告)日:1993-07-01
申请号:DE3784020
申请日:1987-11-05
Applicant: MITSUI TOATSU CHEMICALS
Inventor: KANEMURA YOSHINOBU , SASAGAWA KATSUYOSHI , IMAI MASAO , NAGATA TERUYUKI , KAJIMOTO NOBUYUKI
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公开(公告)号:DE68906476D1
公开(公告)日:1993-06-17
申请号:DE68906476
申请日:1989-06-07
Applicant: MITSUI TOATSU CHEMICALS
Inventor: SASAGAWA KATSUYOSHI , KANEMURA YOSHINOBU , IMAI MASAO , SUZUKI TOSHIYUKI
IPC: B41M5/26 , C07C269/02 , C07C271/10 , C07C271/12 , C07D263/24 , C08F12/00 , C08F12/28 , C08F12/34 , C08F20/34 , C08F20/36 , C08F20/38 , C08F290/00 , C08F299/00 , G02B1/04
Abstract: Polyfunctional monomers are disclosed that yield transparent resins having high transparency and excellent surface hardness and heat resistance. The present polyfunctional monomers are represented by the general formula (I): wherein R represents a group having a carbamido group or an oxazolidone group that will be bonded to the dimethylbenzyl group of the formula (I) and an acryl group or methacryl group at the other end. Control of the polymerization of the polyfunctional monomers is easy, and polymerization of the polyfunctional monomers yield the resins having excellent surface hardness, heat resistance, and workability, and having high transparency. The resins are well adapted for use as glazing materials, optical lenses, and optical disc substrates.
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公开(公告)号:AU616763B2
公开(公告)日:1991-11-07
申请号:AU3617189
申请日:1989-06-08
Applicant: MITSUI TOATSU CHEMICALS
Inventor: SASAGAWA KATSUYOSHI , KANEMURA YOSHINOBU , IMAI MASAO , SUZUKI TOSHIYUKI
IPC: B41M5/26 , C07C269/02 , C07C271/10 , C07C271/12 , C07D263/24 , C08F12/00 , C08F12/28 , C08F12/34 , C08F20/34 , C08F20/36 , C08F20/38 , C08F290/00 , C08F299/00 , G02B1/04 , C08J5/18 , C08F112/12 , C08F122/38
Abstract: Polyfunctional monomers are disclosed that yield transparent resins having high transparency and excellent surface hardness and heat resistance. The present polyfunctional monomers are represented by the general formula (I): wherein R represents a group having a carbamido group or an oxazolidone group that will be bonded to the dimethylbenzyl group of the formula (I) and an acryl group or methacryl group at the other end. Control of the polymerization of the polyfunctional monomers is easy, and polymerization of the polyfunctional monomers yield the resins having excellent surface hardness, heat resistance, and workability, and having high transparency. The resins are well adapted for use as glazing materials, optical lenses, and optical disc substrates.
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公开(公告)号:AU613757B2
公开(公告)日:1991-08-08
申请号:AU3540589
申请日:1989-05-01
Applicant: MITSUI TOATSU CHEMICALS
Inventor: KANEMURA YOSHINOBU , SASAGAWA KATSUYOSHI , IMAI MASAO
Abstract: This invention relates to a polysulfide resin lens and a method of its production comprising cast polymerisation of a mixture of an epoxy/episulfide resin having at least two epoxy groups and/or episulfide groups in one molecule, at least bifunctional polythiol and an internal mold releasing agent. The present invention provides a lens having excellent optical characteristics and high planar accuracy.
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