6.
    发明专利
    未知

    公开(公告)号:DE1294654B

    公开(公告)日:1969-05-08

    申请号:DEM0040019

    申请日:1958-12-22

    Abstract: Alpha-olefins, or diolefins are polymerized in the presence of a catalyst prepared by either, (1) reacting together an amine, an organoaluminium compound, and a compound of a metal of Group IV to VI of the Periodic Table or, (2) by reacting an amine with the reaction product of the organoaluminium compound and a compound of a metal of Group IV to VI. The preparation of the catalyst and the polymerization is generally effected in an inert solvent or diluent. The amine may be monomethylamine, monoethylamine, trimethyhexylamine, aniline, benzylamine, beta-phenylethylamine, benzidine, sec.-di-3,5,5-trimethylhexylamine, tert.-tri-3,5,5-trimethylhexylamine, dimethylaniline, pyridine, piperidine, or quinoline. The organo-compound exemplified is aluminium triethyl, and the compound of Group IV to VI crystalline titanium trichloride. Olefins mentioned are propylene, butene-1, and butadiene. The Specification contains details of the structures of various polybutadienes.

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