PROCESS FOR PRODUCING WOOD-BASED MOULDINGS OF PLASTIC CHARACTER

    公开(公告)号:GB2200917A

    公开(公告)日:1988-08-17

    申请号:GB8801561

    申请日:1988-01-25

    Abstract: The process for producing a plastic-like cured woody molding, which comprises applying a pressure necessary for plasticizing at least a woody component at temperature of from 120 DEG C. to 180 DEG C. to a composition comprising (A) an oligoesterified woody material obtained by alternately adding a polybasic acid anhydride and a monoepoxy compound having unsaturated double bond to the hydroxy groups of a woody material and (B) an oligomer obtained from a polybasic acid anhydride and a monoepoxy compound having unsaturated double bond with the addition of (C) a radical polymerization initiator to simultaneously perform the plasticization and crosslinking by the polymerization of the unsaturated double bonds. The plastic-like cured woody moldings thus obtained have dense and glossy surfaces and are particularly excellent in dimensional stability, mechanical properties and heat distortion temperature.

    3.
    发明专利
    未知

    公开(公告)号:DE3406237C2

    公开(公告)日:1994-11-17

    申请号:DE3406237

    申请日:1984-02-21

    Abstract: An industrially advantageous woody molding is produced by adding a dibasic acid anhydride to a woody material such as a wood meal in the presence or absence of a catalyst such as sodium carbonate, whereby the dibasic acid anhydride is bonded to the hydroxy group of the woody material to form an esterified woody material, adding thereto a compound having at least two epoxy groups in the molecule thereof, kneading well the mixture, and then heat and press molding the kneaded mixture at a temperature higher than 120 DEG C. and a pressure greater than 60 kg/cm2. The product thus obtained by the process of this invention has a smooth and lustrous surface, has good water resistance and dimensional stability, and also is excellent in mechanical strength and hardness.

    4.
    发明专利
    未知

    公开(公告)号:DE3723724C2

    公开(公告)日:1994-02-03

    申请号:DE3723724

    申请日:1987-07-17

    Abstract: A process of producing modified wood by impregnating dried wood with a mixed solution composed of phthalic anhydride as a polybasic acid anhydride and epichlorohydrin as an epoxy compound at a mol ratio of 1:1 to 1:30 by dipping the wood in the mixed solution, withdrawing the impregnated wood from the mixed solution, and heating the wood to a temperature of from 60 DEG C. to 180 DEG C. to simultaneously adding phthalic anhydride and epichlorohydrin to the hydroxyl groups of the wood. By the process of this invention, excellent dimensional stability and weather resistance can be imparted to the wood while retaining the properties specific to the wood.

    PROCESS FOR PRODUCING WOODY MOULDINGS

    公开(公告)号:GB2136004B

    公开(公告)日:1986-11-19

    申请号:GB8400806

    申请日:1984-01-12

    Abstract: An industrially advantageous woody molding is produced by adding a dibasic acid anhydride to a woody material such as a wood meal in the presence or absence of a catalyst such as sodium carbonate, whereby the dibasic acid anhydride is bonded to the hydroxy group of the woody material to form an esterified woody material, adding thereto a compound having at least two epoxy groups in the molecule thereof, kneading well the mixture, and then heat and press molding the kneaded mixture at a temperature higher than 120 DEG C. and a pressure greater than 60 kg/cm2. The product thus obtained by the process of this invention has a smooth and lustrous surface, has good water resistance and dimensional stability, and also is excellent in mechanical strength and hardness.

    6.
    发明专利
    未知

    公开(公告)号:DE3802075A1

    公开(公告)日:1988-08-11

    申请号:DE3802075

    申请日:1988-01-25

    Abstract: The process for producing a plastic-like cured woody molding, which comprises applying a pressure necessary for plasticizing at least a woody component at temperature of from 120 DEG C. to 180 DEG C. to a composition comprising (A) an oligoesterified woody material obtained by alternately adding a polybasic acid anhydride and a monoepoxy compound having unsaturated double bond to the hydroxy groups of a woody material and (B) an oligomer obtained from a polybasic acid anhydride and a monoepoxy compound having unsaturated double bond with the addition of (C) a radical polymerization initiator to simultaneously perform the plasticization and crosslinking by the polymerization of the unsaturated double bonds. The plastic-like cured woody moldings thus obtained have dense and glossy surfaces and are particularly excellent in dimensional stability, mechanical properties and heat distortion temperature.

    7.
    发明专利
    未知

    公开(公告)号:DE3406237A1

    公开(公告)日:1984-08-23

    申请号:DE3406237

    申请日:1984-02-21

    Abstract: An industrially advantageous woody molding is produced by adding a dibasic acid anhydride to a woody material such as a wood meal in the presence or absence of a catalyst such as sodium carbonate, whereby the dibasic acid anhydride is bonded to the hydroxy group of the woody material to form an esterified woody material, adding thereto a compound having at least two epoxy groups in the molecule thereof, kneading well the mixture, and then heat and press molding the kneaded mixture at a temperature higher than 120 DEG C. and a pressure greater than 60 kg/cm2. The product thus obtained by the process of this invention has a smooth and lustrous surface, has good water resistance and dimensional stability, and also is excellent in mechanical strength and hardness.

    8.
    发明专利
    未知

    公开(公告)号:DE3802075C2

    公开(公告)日:1997-04-24

    申请号:DE3802075

    申请日:1988-01-25

    Abstract: The process for producing a plastic-like cured woody molding, which comprises applying a pressure necessary for plasticizing at least a woody component at temperature of from 120 DEG C. to 180 DEG C. to a composition comprising (A) an oligoesterified woody material obtained by alternately adding a polybasic acid anhydride and a monoepoxy compound having unsaturated double bond to the hydroxy groups of a woody material and (B) an oligomer obtained from a polybasic acid anhydride and a monoepoxy compound having unsaturated double bond with the addition of (C) a radical polymerization initiator to simultaneously perform the plasticization and crosslinking by the polymerization of the unsaturated double bonds. The plastic-like cured woody moldings thus obtained have dense and glossy surfaces and are particularly excellent in dimensional stability, mechanical properties and heat distortion temperature.

    PROCESS FOR PRODUCING WOOD-BASED MOULDINGS OF PLASTIC CHARACTER

    公开(公告)号:GB2200917B

    公开(公告)日:1990-02-28

    申请号:GB8801561

    申请日:1988-01-25

    Abstract: The process for producing a plastic-like cured woody molding, which comprises applying a pressure necessary for plasticizing at least a woody component at temperature of from 120 DEG C. to 180 DEG C. to a composition comprising (A) an oligoesterified woody material obtained by alternately adding a polybasic acid anhydride and a monoepoxy compound having unsaturated double bond to the hydroxy groups of a woody material and (B) an oligomer obtained from a polybasic acid anhydride and a monoepoxy compound having unsaturated double bond with the addition of (C) a radical polymerization initiator to simultaneously perform the plasticization and crosslinking by the polymerization of the unsaturated double bonds. The plastic-like cured woody moldings thus obtained have dense and glossy surfaces and are particularly excellent in dimensional stability, mechanical properties and heat distortion temperature.

    10.
    发明专利
    未知

    公开(公告)号:DE3723724A1

    公开(公告)日:1988-06-23

    申请号:DE3723724

    申请日:1987-07-17

    Abstract: A process of producing modified wood by impregnating dried wood with a mixed solution composed of phthalic anhydride as a polybasic acid anhydride and epichlorohydrin as an epoxy compound at a mol ratio of 1:1 to 1:30 by dipping the wood in the mixed solution, withdrawing the impregnated wood from the mixed solution, and heating the wood to a temperature of from 60 DEG C. to 180 DEG C. to simultaneously adding phthalic anhydride and epichlorohydrin to the hydroxyl groups of the wood. By the process of this invention, excellent dimensional stability and weather resistance can be imparted to the wood while retaining the properties specific to the wood.

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