公开(公告)号：DE1617699A1

公开(公告)日：1971-07-29

申请号：DEO0011846

申请日：1966-07-29

Applicant: OREAL

Inventor： KALOPISSIS GEORG DR ,  BUGAUT ANDREE

IPC: A61K8/00 ,  A01J25/11 ,  A01J25/16 ,  A61K8/40 ,  A61K8/41 ,  A61K8/49 ,  A61Q5/06 ,  A61Q5/10 ,  C07C215/14 ,  C07C215/16 ,  C07C311/00 ,  C07C311/15 ,  C07D209/48 ,  C07D295/13 ,  C09B51/00 ,  D06P3/14 ,  C07C143/78

Abstract: Hair-colouring compositions contain in aqs. soln. at least one nitroparaphenylenediamine dye of formula: (in which R, R' and R" are H, lower alkyl or lower hydroxyalkyl, and R''' is where the amino group may be quaternized, and R1 and R2 are H, lower alkyl or lower hydroxyalkyl, or form a heterocyclic ring with the adjacent N-atom, and n is 2-6 when the NO2 group is ortho to the NR'R" radical, one of R' and R" can be H; when the NO2 group is ortho to the NR'R''' radical and R is H, R1 and R2 are not both ethyl and R' and R" are not both H; when the NO2 group is ortho to the NR'R" radical and R is H, R1 and R2 cannot both be ethyl and R" is not methyl when R' is H. When NO2 is meta to NRR''' only of R' may be H.) The compositions contains 0.1-3.8% dye and have a pH of 6-10. They are applied at room temp. for 5-30 minutes, the hair being subsequently rinsed, shampooed and dried. The dyes show great resistance to light and washing, and they can be used in combination with thickeners, detergents, solvents and lacquers.

公开(公告)号：DE1617702A1

公开(公告)日：1971-05-13

申请号：DE1617702

申请日：1966-10-03

Applicant: OREAL

Inventor： KALOPISSIS GEORG DR ,  ROUSSOPOULOS PAUL ,  ZVIAK CHARLES

IPC: A45D7/04 ,  A61K8/46 ,  A61Q5/04

Abstract: 1,160,235. Detergent compositions; aerosol compositions. L'OREAL. 5 Oct., 1966 [5 Oct., 1965; 14 Jan., 1966], No. 44536/66. Headings C4X and C5D. [Also in Division D1] Aerosol compositions and detergent compositions for use in the treatment of hair comprise a basic composition comprising a mixture of at least one thiol and at least one disulphide of a thiol the mole ratio of disulphide to thiol being at least 1À5: 1. The thiol may be thioglycollic acid, thioglycerol, glycol thioglycollate, glycerol thioglycollate, glycol thiolaetate, #- mercaptoethanol, N-carboxymethyl-mercaptoacetamide, thiolactic acid or #-mercaptopropionic acid and the disulphide of a thiol may be a disulphide of one of these thiols although not necessarily the disulphide of the thiol being used. The pH of the composition may be adjusted, preferably to a pH of 9-10, by the addition of ammonia, sodium carbonate, monoethanolamine, diethanolamine or morpholine. The composition may be in the form of a liquid solution, cream or gel. Aerosol compositions may contain butane and Freon (Trade Mark). Shampoos may contain compounds containing polyethenoxy groups, sugar esters, lauryl sulphates, dodecyl benzene sulphonate, quaternary ammonium salts, salts of fatty amines or long chain amino acids, and may comprise 2-10% by weight of detergent 0À5-10% by weight of thiol and 3-50% by weight of thiol disulphide. The compositions may also contain perfumes, dyes, cationic products which facilitate the untangling of the hair and the application of the composition, swelling agents, e.g. urea, or sequestering agents.

公开(公告)号：DE1617698A1

公开(公告)日：1971-04-22

申请号：DE1617698

申请日：1966-07-29

Applicant: OREAL

Inventor： KALOPISSIS GEORG DR ,  BUGAUT ANDRE

IPC: A61K8/00 ,  A01J25/11 ,  A01J25/16 ,  A61K8/40 ,  A61K8/41 ,  A61K8/49 ,  A61Q5/06 ,  A61Q5/10 ,  C07C215/14 ,  C07C215/16 ,  C07C311/00 ,  C07C311/15 ,  C07D209/48 ,  C07D295/13 ,  C09B51/00 ,  D06P3/14

Abstract: Hair-colouring compositions contain in aqs. soln. at least one nitroparaphenylenediamine dye of formula: (in which R, R' and R" are H, lower alkyl or lower hydroxyalkyl, and R''' is where the amino group may be quaternized, and R1 and R2 are H, lower alkyl or lower hydroxyalkyl, or form a heterocyclic ring with the adjacent N-atom, and n is 2-6 when the NO2 group is ortho to the NR'R" radical, one of R' and R" can be H; when the NO2 group is ortho to the NR'R''' radical and R is H, R1 and R2 are not both ethyl and R' and R" are not both H; when the NO2 group is ortho to the NR'R" radical and R is H, R1 and R2 cannot both be ethyl and R" is not methyl when R' is H. When NO2 is meta to NRR''' only of R' may be H.) The compositions contains 0.1-3.8% dye and have a pH of 6-10. They are applied at room temp. for 5-30 minutes, the hair being subsequently rinsed, shampooed and dried. The dyes show great resistance to light and washing, and they can be used in combination with thickeners, detergents, solvents and lacquers.