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公开(公告)号:BR7707742A
公开(公告)日:1978-08-08
申请号:BR7707742
申请日:1977-11-22
Applicant: PHILAGRO SA
IPC: C07D207/40 , C07D207/404 , C07D207/44 , C07D207/448 , C07D207/452 , C07D211/40 , C07D203/22 , C07D205/04 , C07D207/02 , C07D207/24 , C07D209/48
Abstract: A process of preparing a N-substituted imide as disclosed, which is carried out in accordance with the equation: wherein R is an alkyl radical containing 1 to 8 carbon atoms, or an aryl radical having 1 or 2 phenyl rings bearing up to 5 substituents selected from the group consisting of 1 to 3 atoms of halogen, 1 to 2 nitro, amino, or hydroxy groups, 1 to 4 alkyl radicals, and 1 to 2 alkoxy or alkylthiol radicals each containing 1 to 4 carbon atoms, or a hexyl radical, optionally substituted; R' is a single bond or a hydrocarbon chain containing from 1 to 4 carbon atoms, in which two contiguous carbons may belong to a phenyl ring, said hydrocarbon chain being saturated or unsaturated and optionally substituted and R'' is a hydrogen atom, an alkaline metal atom, an ammonium atom or a lower alkyl having 1 to 4 carbon atoms, wherein the cyclization of the amic acid, R-NH-CO-R'-COOR'' is carried out in the presence of a mixed catalyst which results from the association of the formula, A B, in which A is a strong inorganic or organic acid and B is a Lewis base.
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公开(公告)号:DK515477A
公开(公告)日:1978-06-30
申请号:DK515477
申请日:1977-11-21
Applicant: PHILAGRO SA
IPC: C07D207/40 , C07D207/404 , C07D207/44 , C07D207/448 , C07D207/452 , C07D
Abstract: A process of preparing a N-substituted imide as disclosed, which is carried out in accordance with the equation: wherein R is an alkyl radical containing 1 to 8 carbon atoms, or an aryl radical having 1 or 2 phenyl rings bearing up to 5 substituents selected from the group consisting of 1 to 3 atoms of halogen, 1 to 2 nitro, amino, or hydroxy groups, 1 to 4 alkyl radicals, and 1 to 2 alkoxy or alkylthiol radicals each containing 1 to 4 carbon atoms, or a hexyl radical, optionally substituted; R' is a single bond or a hydrocarbon chain containing from 1 to 4 carbon atoms, in which two contiguous carbons may belong to a phenyl ring, said hydrocarbon chain being saturated or unsaturated and optionally substituted and R'' is a hydrogen atom, an alkaline metal atom, an ammonium atom or a lower alkyl having 1 to 4 carbon atoms, wherein the cyclization of the amic acid, R-NH-CO-R'-COOR'' is carried out in the presence of a mixed catalyst which results from the association of the formula, A B, in which A is a strong inorganic or organic acid and B is a Lewis base.
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公开(公告)号:LU78561A1
公开(公告)日:1979-06-13
申请号:LU78561
申请日:1977-11-21
Applicant: PHILAGRO SA
IPC: C07D207/40 , C07D207/404 , C07D207/44 , C07D207/448 , C07D207/452 , C07D , C07C
Abstract: A process of preparing a N-substituted imide as disclosed, which is carried out in accordance with the equation: wherein R is an alkyl radical containing 1 to 8 carbon atoms, or an aryl radical having 1 or 2 phenyl rings bearing up to 5 substituents selected from the group consisting of 1 to 3 atoms of halogen, 1 to 2 nitro, amino, or hydroxy groups, 1 to 4 alkyl radicals, and 1 to 2 alkoxy or alkylthiol radicals each containing 1 to 4 carbon atoms, or a hexyl radical, optionally substituted; R' is a single bond or a hydrocarbon chain containing from 1 to 4 carbon atoms, in which two contiguous carbons may belong to a phenyl ring, said hydrocarbon chain being saturated or unsaturated and optionally substituted and R'' is a hydrogen atom, an alkaline metal atom, an ammonium atom or a lower alkyl having 1 to 4 carbon atoms, wherein the cyclization of the amic acid, R-NH-CO-R'-COOR'' is carried out in the presence of a mixed catalyst which results from the association of the formula, A B, in which A is a strong inorganic or organic acid and B is a Lewis base.
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