公开(公告)号：WO2023091154A1

公开(公告)日：2023-05-25

申请号：PCT/US2021/060346

申请日：2021-11-22

Applicant: PHILLIPS 66 COMPANY

Inventor： NIELSEN, Laura ,  EISENHART, Reed ,  SUDING, Victoria ,  PAN, Hualong ,  CHINEN-MENDEZ, Alyssa

IPC: C08G61/00 ,  C08L65/00 ,  H01L51/54

Abstract: A composition comprising Formula (I). In this composition Ar1 is independently selected from the group consisting of: Formula (II) and Formula (III), and Ar2 is selected from Formula (IV). Additionally in this composition, R1, R5, R6, R7, R8, R9, R11, and R12 are independently selected from F, Cl, H, unsubstituted or substituted branched alkyls with 1 to 60 carbon atoms, and unsubstituted or substituted linear alkyls with 1 to 60 carbon atoms; and the compositional ratio of x/y ranges from about 1/99 to about 99/1, and n ranges from 1 to 1,000,000.

公开(公告)号：WO2020018257A1

公开(公告)日：2020-01-23

申请号：PCT/US2019/039896

申请日：2019-06-28

Applicant: PHILLIPS 66 COMPANY

Inventor： WOODY, Kathy ,  NIELSEN, Laura ,  PAN, Hualong

IPC: C08G61/12 ,  H01L51/46 ,  H01L51/54

Abstract: A novel AB-type copolymer for use in organic photovoltaics. The AB-type copolymer comprises a unit A, where the unit A is Formula (I), where R 1 is a carbon chain from about 1 to about 30 units and where Y is selected from CN, F and Cl. The B unit of the AB-type copolymer is selected from is selected from: Formula (II) wherein X 1 , X 2 , X 3 , and X 4 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkylthiol, alkoxy, ester, ketone, amide and aryl groups.

公开(公告)号：WO2023091152A1

公开(公告)日：2023-05-25

申请号：PCT/US2021/060336

申请日：2021-11-22

Applicant: PHILLIPS 66 COMPANY

Inventor： NIELSEN, Laura ,  EISENHART, Reed ,  SUDING, Victoria ,  PAN, Hualong ,  CHINEN-MENDEZ, Alyssa

IPC: C08G61/00 ,  C08L65/00 ,  H01L51/54

Abstract: A composition comprising (I) wherein the compositional ratio of x/y ranges from about 1/99 to about 99/1, and n ranges from 1 to 1,000,000. Additionally, in this composition, R' and R'' are independently selected from: H, unsubstituted or substituted branched alkyls with 1 to 60 carbon atoms, or unsubstituted or substituted linear alkyls with 1 to 60 carbon atoms.

公开(公告)号：WO2019023022A8

公开(公告)日：2019-01-31

申请号：PCT/US2018/042711

申请日：2018-07-18

Applicant: PHILLIPS 66 COMPANY

Inventor： NIELSEN, Laura ,  WOODY, Kathy ,  EARNMME, Taeshik

IPC: C07D471/04 ,  C07D471/06 ,  C07D495/04 ,  H01L29/786 ,  H01L51/00 ,  H01L51/05

Abstract: A copolymer comprising a repeat unit A, wherein repeat unit A comprises a 1,2,5,6-naphthalenediimide monomer and at least one repeat unit B, wherein repeat unit B comprises an aryl group. The copolymer can be regio-random or regio-regular.

公开(公告)号：WO2019023022A1

公开(公告)日：2019-01-31

申请号：PCT/US2018/042711

申请日：2018-07-18

Applicant: PHILLIPS 66 COMPANY

Inventor： NIELSEN, Laura ,  WOODY, Kathy ,  EARNMME, Taeshik

IPC: C07D471/04 ,  C07D471/06 ,  C07D495/04 ,  H01L29/786 ,  H01L51/00 ,  H01L51/05

Abstract: A copolymer comprising a repeat unit A, wherein repeat unit A comprises a 1,2,5,6-naphthalenediimide monomer and at least one repeat unit B, wherein repeat unit B comprises an aryl group. The copolymer can be regio-random or regio-regular.

公开(公告)号：WO2023091153A1

公开(公告)日：2023-05-25

申请号：PCT/US2021/060340

申请日：2021-11-22

Applicant: PHILLIPS 66 COMPANY

Inventor： NIELSEN, Laura ,  EISENHART, Reed ,  SUDING, Victoria ,  PAN, Hualong ,  CHINEN-MENDEZ, Alyssa

IPC: C08G61/00 ,  C08L65/00 ,  H01L51/54

Abstract: A method of reacting (I) with (II) to produce (III). In this method Y1 and Y2 are independently selected from the group consisting of: H, Cl, Br, I, and combinations thereof. Additionally in this method M is selected from the group consisting of H, trialkylstannane, boronate, or ZnX, wherein X is Cl, Br, or I. Furthermore in this method Z is a divalent linking group selected from the group consisting of: (IV), (V), (VI), (VII), or (VIII). Lastly, in this method R1 is selected from: H, unsubstituted or substituted branched alkyls with 1 to 60 carbon atoms or unsubstituted or substituted linear alkyls with 1 to 60 carbon atoms.

公开(公告)号：WO2023091151A1

公开(公告)日：2023-05-25

申请号：PCT/US2021/060331

申请日：2021-11-22

Applicant: PHILLIPS 66 COMPANY

Inventor： NIELSEN, Laura ,  EISENHART, Reed ,  SUDING, Victoria ,  PAN, Hualong ,  CHINEN-MENDEZ, Alyssa

IPC: C08G61/00 ,  C08L65/00 ,  H01L51/54

Abstract: A method to produce Formula (I).

公开(公告)号：WO2019023025A1

公开(公告)日：2019-01-31

申请号：PCT/US2018/042724

申请日：2018-07-18

Applicant: PHILLIPS 66 COMPANY

Inventor： NIELSEN, Laura ,  WOODY, Kathy ,  PAN, Hualong ,  EARNMME, Taeshik

IPC: C08F234/04 ,  C08G61/12 ,  C08G75/00

Abstract: A copolymer comprising a repeat unit (A), wherein repeat unit (A) comprises a repeat unit (B), wherein repeat unit (B) comprises and at least one optional repeat unit (D), wherein repeat unit (D comprises an aryl group. In this copolymer, X 1 , X 2 , X 3 , and X 4 are independently selected from the group consisting of: H, CI, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups and R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are independently selected from the group consisting of: H, CI, F, CN, alkyl, al koxy, ai kylthio, ester, ketone and aryl groups.

公开(公告)号：WO2020018442A1

公开(公告)日：2020-01-23

申请号：PCT/US2019/041842

申请日：2019-07-15

Applicant: PHILLIPS 66 COMPANY

Inventor： WOODY, Kathy ,  NIELSEN, Laura ,  PAN, Hualong

IPC: C07D409/00 ,  C08G61/12 ,  H01L51/46

Abstract: A novel AB-type copolymer for use in organic photovoltaics. The AB-type copolymer comprises a unit A, where the unit A is (Formula), where R 1 is a carbon chain from about 1 to about 30 units and where Y is selected from CN, F and Cl. The B unit of the AB-type copolymer is selected from is selected from: (formulas) wherein X 1 , X 2 , X 3 , and X 4 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkylthiol, alkoxy, ester, ketone, amide and aryl groups.

公开(公告)号：WO2019023021A1

公开(公告)日：2019-01-31

申请号：PCT/US2018/042705

申请日：2018-07-18

Applicant: PHILLIPS 66 COMPANY

Inventor： NIELSEN, Laura ,  WOODY, Kathy

IPC: C07D471/04 ,  C07D471/06 ,  C07D495/04 ,  H01L29/786 ,  H01L51/00 ,  H01L51/05

Abstract: A method comprising converting 2, 6-naphthalene diol to produce a 1, 2, 5, 6-naphthalenediimide monomer, wherein the method occurs at temperatures less than 250° C and NDI monomers are produced safely.