公开(公告)号：EP0206044A1

公开(公告)日：1986-12-30

申请号：EP86107685

申请日：1986-06-05

Applicant: PHILLIPS PETROLEUM CO

Inventor： KOLTS JOHN HENRY ,  KIMBLE JAMES BAILEY

IPC: B01J23/10 ,  B01J23/14 ,  B01J27/06 ,  B01J27/08 ,  C07B31/00 ,  C07B33/00 ,  C07B61/00 ,  C07C1/00 ,  C07C2/84 ,  C07C11/04 ,  C07C67/00

CPC classification number: B01J23/10 ,  B01J23/14 ,  B01J27/06 ,  C07C2/84 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2527/06 ,  C07C2527/135 ,  Y10S585/943

Abstract: A solid composition of matter selected from the group consisting of:

(a) a component comprising: (1) an oxide of lanthanum and a component comprising: (2) at least one material selected from the group consisting of halogen ions, compounds containing halogen ions, tin and compounds containing tin; and
(b) a component comprising: (1) at least one material selected from the group consisting of Group IA metals and compounds containing said metals, a component comprising: (2) at least one metal selected from the group consisting of lanthanum and compounds containing lanthanum and, optionally, a component comprising: (3) at least one material selected from the group consisting of halogen ions, compounds containing halogen ions, tin and compounds containing tin,

and a method for the oxidative conversion of organic compounds to other organic compounds, particularly in the presence of a free oxygen containing gas. When the method is carried out in the presence of a free oxygen containing gas, a contact material including a Group IA metal, tin and, optionally, chloride ions has also been found to be effective.

公开(公告)号：EP0206042A1

公开(公告)日：1986-12-30

申请号：EP86107682

申请日：1986-06-05

Applicant: PHILLIPS PETROLEUM CO

Inventor： KOLTS JOHN HENRY ,  KIMBLE JAMES BAILEY

IPC: B01J23/02 ,  B01J23/04 ,  B01J23/14 ,  B01J27/10 ,  B01J27/135 ,  B01J27/138 ,  C07B61/00 ,  C07C1/00 ,  C07C2/84 ,  C07C9/02 ,  C07C11/02 ,  C07C67/00 ,  B01J27/06

CPC classification number: B01J27/10 ,  B01J23/02 ,  B01J23/04 ,  B01J23/14 ,  B01J27/138 ,  C07C2/84 ,  C07C2521/06 ,  C07C2523/04 ,  C07C2527/06 ,  Y10S585/943

Abstract: A solid composition of matter is disclosed consisting essentially of sodium, potassium, a Group IA metal or a Group IA metal and a Group IIA metal, titanium, oxygen and, optionally, at least one of a halogen and tin, in which at least one of the sodium, the potassium, the Group IA metal or the Group IIA metal is present in an amount in excess of any amount present in electrically neutral compounds of the metal, the titanium and oxygen.
The above compositions are particularly useful as solid contact materials for the oxidative conversion of feed organic compounds to product organic compounds, particularly in the presence of a free oxygen containing gas. A method for such conversion is also disclosed.
In a preferred embodiment a method for the oxidative conversion of methane, such as natural gas, to higher hydrocarbons, particularly ethylene and ethane, is disclosed in which the methane and a free oxygen containing gas are contacted with a Group IA metal, a Group IIA metal, or a Group IA metal and a Group IIA metal, titanium, oxygen and, optionally, a halogen and/or tin.

公开(公告)号：EP0206043A1

公开(公告)日：1986-12-30

申请号：EP86107684

申请日：1986-06-05

Applicant: PHILLIPS PETROLEUM CO

Inventor： KIMBLE JAMES BAILEY ,  KOLTS JOHN HENRY

IPC: B01J27/00 ,  C07B61/00 ,  C07C1/00 ,  C07C2/84 ,  C07C9/02 ,  C07C11/02 ,  C07C67/00

CPC classification number: C07C2/84 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2527/06 ,  C07C2527/167 ,  Y10S585/943

Abstract: Methane is converted to higher hydrocarbons, particularly ethylene and ethane, and most desirably ethylene, by:

contacting a feed comprising methane, such as natural gas, and a free oxygen containing gas, such as oxygen or air, with a solid contact material, comprising:

(a) a component comprising: at least one metal selected from the group consisting of Group IA and Group IIA metals;
(b) a component comprising: at least one material selected from the group consisting of phosphate radicals and compounds containing phosphate radicals; and
(c), optionally, at least one material selected from the group consisting of halogen ions and compounds containing halogen ions,


under oxidative conversion conditions sufficient to convert the methane to the higher hydrocarbons.

公开(公告)号：NO171015C

公开(公告)日：1993-01-13

申请号：NO862265

申请日：1986-06-06

Applicant: PHILLIPS PETROLEUM CO

Inventor： KIMBLE JAMES BAILEY ,  KOLTS JOHN HENRY

IPC: B01J23/10 ,  B01J23/14 ,  B01J27/06 ,  B01J27/08 ,  C07B31/00 ,  C07B33/00 ,  C07B61/00 ,  C07C1/00 ,  C07C2/84 ,  C07C11/04 ,  C07C67/00

Abstract: A solid composition of matter selected from the group consisting of:(a) a component comprising: (1) an oxide of lanthanum and a component comprising: (2) at least one material selected from the group consisting of halogen ions, compounds containing halogen ions, tin and compounds containing tin; and(b) a component comprising: (1) at least one material selected from the group consisting of Group IA metals and compounds containing said metals, a component comprising: (2) at least one metal selected from the group consisting of lanthanum and compounds containing lanthanum and, optionally, a component comprising: (3) at least one material selected from the group consisting of halogen ions, compounds containing halogen ions, tin and compounds containing tin,and a method for the oxidative conversion of organic compounds to other organic compounds, particularly in the presence of a free oxygen containing gas. When the method is carried out in the presence of a free oxygen containing gas, a contact material including a Group IA metal, tin and, optionally, chloride ions has also been found to be effective.

公开(公告)号：NO170576C

公开(公告)日：1992-11-04

申请号：NO861030

申请日：1986-03-18

Applicant: PHILLIPS PETROLEUM CO

Inventor： KOLTS JOHN HENRY ,  KIMBLE JAMES BAILEY

IPC: B01J23/06 ,  B01J23/14 ,  B01J27/10 ,  C07C2/84 ,  B01J23/04 ,  B01J27/135

Abstract: A solid composition of matter selected from the group consisting of:(a) a component comprising: (1) at least one material selected from the group consisting of Group IA metals and compounds containing said metals, a component comprising: (2) at least one material selected from the group consisting of zinc and compounds containing zinc, and a component comprising: (3) at least one material selected from the group consisting of chloride ions, compounds containing chloride ions; tin and compounds containing tin; and(b) a component comprising: (1) at least one material selected from the group consisting of Group IA metals and compounds containing said metals, a component comprising: (2) zinc oxide, and, optionally, a component comprising: (3) at least one material selected from the group consisting of chloride ions, compounds containing chloride ions tin and compounds containing tin.The above composition of matter is useful as a solid contact material adapted to convert feed organic compounds to product organic compounds, particularly, in the presence of a free oxygen containing gas.A method for the conversion of feed organic materials to product organic materials, particularly methane to ethylene, in the presence of a free oxygen containing gas, utilizing combinations of Group IA metals, zinc and, optionally, chloride ions and/or tin, is also disclosed.

公开(公告)号：MX162609A

公开(公告)日：1991-05-31

申请号：MX19524782

申请日：1982-11-18

Applicant: PHILLIPS PETROLEUM CO

Inventor： BRESSON CLARENCE RICHARD ,  PARLMAN ROBERT MYLES ,  KIMBLE JAMES BAILEY

IPC: B03D1/012 ,  C07C329/00 ,  C22B3/34

Abstract: The efficiency of metals separation using ore flotation is improved by the use of certain substituted hydrocarbylene trithiocarbonates as suppressants for undesired metals.

公开(公告)号：AU579014B2

公开(公告)日：1988-11-10

申请号：AU5788486

申请日：1986-05-23

Applicant: PHILLIPS PETROLEUM CO

Inventor： KOLTS JOHN HENRY ,  KIMBLE JAMES BAILEY

IPC: B01J23/10 ,  B01J23/14 ,  B01J27/06 ,  B01J27/08 ,  C07B31/00 ,  C07B33/00 ,  C07B61/00 ,  C07C1/00 ,  C07C2/84 ,  C07C11/04 ,  C07C67/00 ,  C07C9/06 ,  C07B37/00

Abstract: A solid composition of matter selected from the group consisting of:(a) a component comprising: (1) an oxide of lanthanum and a component comprising: (2) at least one material selected from the group consisting of halogen ions, compounds containing halogen ions, tin and compounds containing tin; and(b) a component comprising: (1) at least one material selected from the group consisting of Group IA metals and compounds containing said metals, a component comprising: (2) at least one metal selected from the group consisting of lanthanum and compounds containing lanthanum and, optionally, a component comprising: (3) at least one material selected from the group consisting of halogen ions, compounds containing halogen ions, tin and compounds containing tin,and a method for the oxidative conversion of organic compounds to other organic compounds, particularly in the presence of a free oxygen containing gas. When the method is carried out in the presence of a free oxygen containing gas, a contact material including a Group IA metal, tin and, optionally, chloride ions has also been found to be effective.

公开(公告)号：AU565537B2

公开(公告)日：1987-09-17

申请号：AU5650886

申请日：1986-04-23

Applicant: PHILLIPS PETROLEUM CO

Inventor： KOLTS JOHN HENRY ,  KIMBLE JAMES BAILEY ,  FIGARD JOSEPH EMERSON ,  KUBICEK DONALD HUBERT

IPC: B01J19/12 ,  C01B3/04

Abstract: Hydrogen is produced by irradiating a solution of H 2 S dissolved in alkaline liquid medium using light in the visible range.

公开(公告)号：AU5650886A

公开(公告)日：1987-02-19

申请号：AU5650886

申请日：1986-04-23

Applicant: PHILLIPS PETROLEUM CO

Inventor： KOLTS JOHN HENRY ,  KIMBLE JAMES BAILEY ,  FIGARD JOSEPH EMERSON ,  KUBICEK DONALD HUBERT

IPC: B01J19/12 ,  C01B3/04

Abstract: Hydrogen is produced by irradiating a solution of H 2 S dissolved in alkaline liquid medium using light in the visible range.

公开(公告)号：AU5435186A

公开(公告)日：1986-09-25

申请号：AU5435186

申请日：1986-03-06

Applicant: PHILLIPS PETROLEUM CO

Inventor： KOLTS JOHN HENRY ,  KIMBLE JAMES BAILEY

IPC: C07C2/84 ,  C07C11/04 ,  C07C9/06

Abstract: @ A method for the oxidative conversion of methane, to higher hydrocarbons, particularly ethylene and ethane, in which a methane-containing gas, such as natural gas, and a free oxygen containing gas are contacted with a contact material selected from the group consisting of:(a) a component comprising: (1) at least one oxide of a metal selected from the group consisting of calcium, strontium and barium and, optionally, a component comprising: (2) at least one material selected from the group consisting of chloride ions, compounds containing chloride ions, tin and compounds containing tin;(b) a component comprising: (1) at least one metal selected from the group consisting of sodium, potassium and compounds containing said metals, a component comprising: (2) at least one metal selected from the group consisting of Group IIA metals and compounds containing said metals, and, optionally, a component comprising: (3) at least one material selected from the group consisting of chloride ions, compounds containing chloride ions, tin and compounds containing tin; and(c) a component comprising: (1) at least one metal selected from the group consisting of Group IA metals and compounds containing said metals, a component comprising: (2) at least one metal selected from the group consisting of calcium, strontium, barium and compounds containing said metals and, optionally, a component comprising: (3) at least one material selected from the group consisting of chloride ions, compounds containing chloride ions, tin and compounds containing tin.