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公开(公告)号：EP0909769A2
公开(公告)日：1999-04-21
申请号：EP98119282.6
申请日：1998-10-13
Applicant: PHILLIPS PETROLEUM COMPANY
Inventor： Martin, Joel Leonard , Bergmeister, Joseph John , Hsieh, Eric Tsu-Yin , McDaniel, Max Paul , Benham, Elizabeth Ann , Secora, Steven Joseph
IPC: C08F210/16 , C08F2/14 , C08F4/02
CPC classification number: C08F210/16 , C08F4/65916 , C08F110/02 , C08F4/659 , C08F4/42 , C08F2/14 , C08F2500/01 , C08F2500/18 , C08F2500/17 , C08F2500/12 , C08F210/14 , C08F2500/24 , C08F210/08
Abstract: A novel loop/slurry olefin polymerization process is provided which produces ultra high molecular weight ethylene homopolymers and ultra high molecular weight ethylene copolymers. Catalyst systems used are selected from the group consisting of inorganic oxide supported titanium-containing catalyst systems, inorganic oxide supported organo-zirconium catalyst systems and inorganic oxide supported organo-hafnium catalyst systems.
Abstract translation: 提供了一种产生超高分子量乙烯均聚物和超高分子量乙烯共聚物的新型环/淤浆烯烃聚合方法。 使用的催化剂体系选自无机氧化物负载的含钛催化剂体系，无机氧化物负载的有机锆催化剂体系和无机氧化物负载的有机铪催化剂体系。
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公开(公告)号：EP0570000B1
公开(公告)日：1996-12-27
申请号：EP93107880.2
申请日：1993-05-14
Applicant: PHILLIPS PETROLEUM COMPANY
Inventor： Stacy, Elizabeth Mary , Welch, Melvin Bruce , Martin, Shirley Jean , McDaniel, Max Paul , Pierce, Dale Eugene
CPC classification number: C08F10/00 , C08F210/16 , Y10S526/904 , C08F2/14 , C08F4/025 , C08F4/6092 , C08F210/14 , C08F2500/12 , C08F2500/07 , C08F2500/18 , C08F2500/14
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公开(公告)号：EP0524624A3
公开(公告)日：1993-05-05
申请号：EP92112582.9
申请日：1992-07-23
Applicant: PHILLIPS PETROLEUM COMPANY
Inventor： Alt, Helmut G., Prof.Dr. , Palackal, Syriac Jospeh, Dr. , Patsidis, Konstantinos , Welch, Marvin Bruce , Geerts, Rolf Leonard , Hsieh, Eric Tsu-Yin , McDaniel, Max Paul , Hawley, Gil R. , Smith, Paul David
IPC: C07F17/00 , C08F4/74 , C08F10/14 , C08F210/14
CPC classification number: B01J31/143 , B01J31/2295 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07C2601/10 , C07C2603/18 , C07F7/0809 , C07F7/0818 , C07F17/00 , C08F4/63912 , C08F4/63922 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C07C65/38 , C08F2500/12 , C08F2500/17 , C08F2500/20 , C08F2500/01 , C08F2500/08 , C08F210/14
Abstract: Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.
Abstract translation: 公开了含芴基金属茂以及用于制备金属茂的方法。 还公开了使用金属茂作为聚合催化剂的方法。 此外，公开了由这种聚合产生的聚合物。
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公开(公告)号：EP0533154A1
公开(公告)日：1993-03-24
申请号：EP92115909.1
申请日：1992-09-17
Applicant: PHILLIPS PETROLEUM COMPANY
Inventor： Coutant, William Richard , Welch, Melvin Bruce , Mozer, Larry Phelps , McDaniel, Max Paul , Martin, Joel Leonard
IPC: C08L23/04
CPC classification number: C08L23/06 , C08L23/0815 , C08L2207/20 , C08L2666/06
Abstract: Ethylene polymer blends of a virgin or recycled low molecular weight ethylene polymer produced from a chromium-based catalyst and a high molecular weight ethylene polymer produced from a titanium-based catalyst, exhibit excellent processing characteristics, environmental stress crack resistance and stiffness. These ethylene polymer blends are useful for use in bottle, film, pipe, and/or drum applications.
Abstract translation: 由铬基催化剂生产的原始或再循环的低分子量乙烯聚合物和由钛基催化剂生产的高分子量乙烯聚合物的乙烯聚合物共混物表现出优异的加工特性，耐环境应力开裂性和刚度。 这些乙烯聚合物共混物可用于瓶，膜，管和/或鼓应用中。
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5.发明公开Organometallic fluorenyl compounds, preparation, and use 失效Organometallische Fluorenylverbindungen，ihre Herstellung und ihre Verwendung。
公开(公告)号：EP0524624A2
公开(公告)日：1993-01-27
申请号：EP92112582.9
申请日：1992-07-23
Applicant: PHILLIPS PETROLEUM COMPANY
Inventor： Alt, Helmut G., Prof.Dr. , Palackal, Syriac Jospeh, Dr. , Patsidis, Konstantinos , Welch, Marvin Bruce , Geerts, Rolf Leonard , Hsieh, Eric Tsu-Yin , McDaniel, Max Paul , Hawley, Gil R. , Smith, Paul David
IPC: C07F17/00 , C08F4/74 , C08F10/14 , C08F210/14
CPC classification number: B01J31/143 , B01J31/2295 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07C2601/10 , C07C2603/18 , C07F7/0809 , C07F7/0818 , C07F17/00 , C08F4/63912 , C08F4/63922 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C07C65/38 , C08F2500/12 , C08F2500/17 , C08F2500/20 , C08F2500/01 , C08F2500/08 , C08F210/14
Abstract: Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.
Abstract translation: 公开了含芴基金属茂以及用于制备金属茂的方法。 还公开了使用金属茂作为聚合催化剂的方法。 此外，公开了由这种聚合产生的聚合物。
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Patent Agency Ranking
公开(公告)号：EP0480376A3
公开(公告)日：1992-05-27
申请号：EP91117138.7
申请日：1991-10-08
Applicant: PHILLIPS PETROLEUM COMPANY
Inventor： Benham, Elizabeth Ann , McDaniel, Max Paul
IPC: C08F210/02 , C08F4/69
CPC classification number: C08F210/02 , Y10S526/904 , C08F4/24 , C08F4/646
Abstract: A catalyst mixture is disclosed comprising (1) a particulate chromium-containing catalyst comprising inorganic oxide and chromium and (2) a particular type of particulate titanium-containing catalyst. Also disclosed is the use of this catalyst mixture to produce particularly novel olefin polymers.
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公开(公告)号：EP0480377A2
公开(公告)日：1992-04-15
申请号：EP91117139.5
申请日：1991-10-08
Applicant: PHILLIPS PETROLEUM COMPANY
CPC classification number: C08F210/16 , C08F10/00 , C08F110/02 , C08F4/69 , C08F2500/10 , C08F2500/08 , C08F2500/07 , C08F210/14
Abstract: This invention relates to a high-temperature slurry polymerization of ethylene where: the hexene is generated in situ; a chromium catalyst system is used; a trialkyl boron or a polyalkyl silane compound is used as a cocatalyst; the temperature of the reaction is above the foul curve temperature for a specific copolymer density; and where the polymerization takes place in a continuous loop reactor which has isobutane as a diluent. Additionally, hexene can be withdrawn, or added, to adjust the density.
Abstract translation: 本发明涉及乙烯的高温淤浆聚合，其中：原位产生己烯; 使用铬催化剂体系; 三烷基硼或多烷基硅烷化合物用作助催化剂; 对于特定的共聚物密度，反应温度高于恶劣曲线温度; 并且其中聚合在具有异丁烷作为稀释剂的连续回路反应器中进行。 此外，可以取出或加入己烯以调节密度。
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公开(公告)号：EP0279890B1
公开(公告)日：1992-03-18
申请号：EP87108679.9
申请日：1987-06-16
Applicant: PHILLIPS PETROLEUM COMPANY
Inventor： McDaniel, Max Paul , Klendworth, Douglas Dean , Norwood, Donald Dwight , Hsieh, Eric Tsu-Yin , Boggs, Elizabeth Ann
CPC classification number: C08F10/02 , C08F110/02 , C08F2410/04 , C08F4/69 , C08F2500/10 , C08F2500/12 , C08F4/025
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9.发明公开High strength linear, low density polyethylene polymerization process and film (phenomenal film) 失效一种用于高强度的线性低密度聚乙烯和由其（惊人膜）制成的膜的聚合过程。
公开(公告)号：EP0361363A2
公开(公告)日：1990-04-04
申请号：EP89117681.0
申请日：1989-09-25
Applicant: PHILLIPS PETROLEUM COMPANY
Inventor： Benham, Elizabeth Ann , McDaniel, Max Paul , Bailey, Fay Wallace
IPC: C08F210/02 , C08F4/623
CPC classification number: C08F10/00 , C08F110/02 , C08F210/16 , C08F4/69 , C08F2500/10 , C08F2500/08 , C08F2500/12 , C08F210/14 , C08F2500/26 , C08F210/08 , C08F4/025
Abstract: A copolymer of ethylene and a higher alpha-olefin, preferably 1-hexene and/or 4-methyl-1-pentene, can be produced using an activated and subsequently carbon monoxide reduced chromium containing catalyst and a trialkyl boran cocatalyst. The polymerization process must be carefully controlled to produce a copolymer resin that can be made into a tough, impact resistant film.
Abstract translation: 乙烯的共聚物和高级α-烯烃，优选1-己烯和/或4-甲基-1-戊烯中，可以使用在活化和随后一氧化碳还原的铬含催化剂和三烷基硼烷的助催化剂来生产。 聚合过程必须充分护理控制以产生共聚物树脂也可制作成坚韧的，耐冲击的成膜。
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公开(公告)号：EP0104374B1
公开(公告)日：1988-05-04
申请号：EP83107735.9
申请日：1983-08-05
Applicant: PHILLIPS PETROLEUM COMPANY
Inventor： McDaniel, Max Paul
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