Abstract:
A polyacetal resin composition which, when formed into a molded article, minimizes degradation caused by contact with a fuel. This resin composition contains 100 parts by weight of a polyacetal copolymer resin, 0.1-1.0 parts by weight of a hindered phenol-based antioxidant, 0.1-2.0 parts by weight of a divalent metal oxide, and 0.5-3.0 parts by weight of an alkylene oxide adduct of an alkylamine and/or an alkylene oxide adduct of an alkylene diamine Component contains magnesium oxide and/or zinc oxide, and component is one or more of general formulae (1) to (3). In these general formulae, X represents (C2H4O)m(C3H6O)nH, and m and n are each an integer of 0 or higher. In addition, R1 is an alkyl group having 12-18 carbon atoms, and R2 is an alkylene group having 2 or 3 carbon atoms.
Abstract:
A polyacetal resin composition which not only is highly inhibited from making creaking sounds but also has satisfactory performances with respect to other properties. The polyacetal resin composition includes 100 parts by weight of a polyacetal resin, 0.01-1 part by weight of a hindered phenolic antioxidant, 0.01-1 part by weight of a nitrogenous compound, 0.1-1 part by weight of a graft copolymer, 0.1-1 part by weight of a fatty acid ester, 0.5-5 parts by weight of a silicone oil, and 0.1-1 part by weight of calcium carbonate. The nitrogenous compound may be an aminotriazine compound, the graft copolymer includes an olefin-based polymer as the main chain and a vinyl-based polymer as side chains, the fatty acid ester includes a C12-32 fatty acid and a C2-30 mono- or polyhydric alcohol, and the calcium carbonate has an average particle diameter of 1 μm or smaller.
Abstract:
A polyoxymethylene (POM) resin composition which is used for a resin molded article having an excellent sliding characteristic and wear resistance property and also having an excellent surface property and peeling resistance property. This POM resin composition contains: (A) 100 parts by mass of a POM resin; (B) 0.01-1 parts by mass of a hindered phenolic antioxidant; (C) 0.05-1 parts by mass inclusive of a nitrogen-containing compound; (D) 0.5-10 parts by mass of a modified olefin polymer which is an olefin polymer that has been modified by an unsaturated carboxylic acid or the like; (E) 0.01-5 parts by mass of an alkylene glycol polymer that has a primary or secondary amino group and a number average molecular weight of 400-500,000; (F) 0.1-20 parts by mass of calcium carbonate which has a BET specific surface area of 15 m2/g or less, has a mean particle size of 50-200 nm or less, is surface-untreated, and is substantially cubic; (G) 0.1-10 parts by mass of a partial ester of a divalent to tetravalent alcohol; and (H) 0.1-10 parts by mass of an α-olefin oligomer.
Abstract:
A polyacetal resin composition makes it possible, when formed into a molded article, to minimize deterioration during contact with sulfur-containing fuel or an acidic detergent. The polyacetal resin composition contains (A) 100 parts by weight of polyacetal resin, (B) 0.1-1.0 parts by weight of hindered phenolic antioxidant, (C) 0.1-2.0 parts by weight of alkaline earth metal oxide, (D) 0.5-3.0 parts by weight of polyalkylene glycol, and (E) 0.01-1.0 parts by weight of polyvalent fatty acid full ester. This polyacetal resin composition minimizes reductions in the weight of a molded article even after the molded article has been immersed in sulfur-containing fuel.
Abstract:
A polyacetal resin composition which is suppressed low in formaldehyde generation, while having high stiffness and high toughness. The resin is produced by a method including blending from 0.1 part by weight to 2 parts by weight (inclusive) of a polyacetal copolymer having a branched or crosslinked structure, which is a copolymer of a trioxane, a compound having from 3 to 4 (inclusive) cyclic ether units in each molecule and a compound having one cyclic ether unit in each molecule, per 100 parts by weight of a linear polyacetal copolymer which contains an oxymethylene unit as a main constituent, while containing, as a comonomer unit, an oxyalkylene unit at a ratio of from 0.4% by mole to 0.9% by mole (inclusive) relative to the constituents of the linear polyacetal copolymer, the linear polyacetal copolymer being obtained by copolymerization wherein a heteropolyacid or the like is used as a polymerization catalyst.
Abstract:
A polyoxymethylene (POM) resin composition which is used for a resin molded article having a superior sliding characteristic. This POM resin composition contains: (A) 100 parts by mass of a POM resin; (B) 0.01-1 parts by mass of a hindered phenolic antioxidant; (C) 0.05-1 parts by mass of a nitrogen-containing compound; (D) 0.5-10 parts by mass of a modified olefin polymer; (E) 0.01-5 parts by mass of an alkylene glycol polymer; (F) 0.1-20 parts by mass of calcium carbonate; (G) 0.1-10 parts by mass of a partial ester of a polyhydric alcohol; and (H) 0.1-10 parts by mass of an α-olefin oligomer.
Abstract:
A polyoxymethylene (POM) resin composition which is used for a resin molded article having a superior sliding characteristic. The POM resin composition contains: (A) 100 parts by mass of a POM resin; (B) 0.01-1 parts by mass of a hindered phenolic antioxidant; (C) 0.05-1 parts by mass of a nitrogen-containing compound; (D) 0.5-10 parts by mass of a modified olefin polymer; (E) 0.01-5 parts by mass of an alkylene glycol polymer; (F) 0.1-20 parts by mass of calcium carbonate; (G) 0.1-10 parts by mass of a partial ester of a polyhydric alcohol; and (H) 0.1-10 parts by mass of an a-olefin oligomer. An ISO tensile test piece, which is obtained by injection molding at a die temperature of 90° C. and a cylinder temperature of 200° C., is crushed, Soxhlet extraction is performed for 3 hours at 70° C. using methanol, and the alkylene glycol polymer is measured. The weight of the alkylene glycol polymer is 0.001 wt % or less relative to 100 wt % of the test piece.