公开(公告)号：AU2002364478A1

公开(公告)日：2003-07-09

申请号：AU2002364478

申请日：2002-12-20

Applicant: RHODIA CHIMIE SA

Inventor： TAILLEFER MARC ,  CRISTAU HENRI-JEAN ,  CELLIER PASCAL ,  SPINDLER JEAN-FRANCIS

IPC: C07D295/02 ,  C07B37/04 ,  C07B41/04 ,  C07B43/00 ,  C07B61/00 ,  C07C41/01 ,  C07C43/263 ,  C07C269/06 ,  C07C271/28 ,  C07D209/08 ,  C07D231/12 ,  C07D233/58 ,  C07D263/22

Abstract: Process for the formation of a carbon-carbon or a carbon-heteroatom bond comprises reaction of an unsaturated compound having a leaving group with a nucleophilic compound having a carbon or heteroatom group capable of being substituted by the leaving group. Process for the formation of a carbon-carbon or a carbon-heteroatom bond comprises reaction of an unsaturated compound having a leaving group with a nucleophilic compound having a carbon or heteroatom group capable of being substituted by the leaving group. The reaction is conducted in the presence of a catalytic amount of a group (VIII), (Ib) or (IIb) metal and a ligand that is at least bidentate with at least two chelating atoms, one at least of which is O and one at least is N.

公开(公告)号：FR2840303B1

公开(公告)日：2005-07-15

申请号：FR0206717

申请日：2002-05-31

Applicant: RHODIA CHIMIE SA

Inventor： TAILLEFER MARC ,  CRISTAU HENRI JEAN ,  CELLIER PASCAL ,  SPINDLER JEAN FRANCIS

IPC: C07D209/08 ,  C07D213/53 ,  C07D231/12 ,  C07D233/06 ,  C07D233/58 ,  C07D521/00 ,  C07D403/10 ,  C07D403/04 ,  C07D213/643 ,  C07C43/29 ,  C07C43/285

Abstract: The present invention concerns a process for arylating or vinylating or alkynating a nucleophilic compound. More particularly, the invention concerns arylating nitrogen-containing organic derivatives. The arylating or vinylating or alkynating process of the invention consists of reacting a nucleophilic compound with a compound carrying a leaving group and is characterized in that the reaction is carried out in the presence of an effective quantity of a catalyst based on a metallic element M selected from groups (VIII), (Ib) and (IIb) of the periodic table and at least one ligand comprising at least one imine function and at least one supplemental nitrogen atom as the chelating atoms.

公开(公告)号：FR2840303A1

公开(公告)日：2003-12-05

申请号：FR0206717

申请日：2002-05-31

Applicant: RHODIA CHIMIE SA

Inventor： TAILLEFER MARC ,  CRISTAU HENRI JEAN ,  CELLIER PASCAL ,  SPINDLER JEAN FRANCIS

IPC: C07D209/08 ,  C07D213/53 ,  C07D231/12 ,  C07D233/06 ,  C07D233/58 ,  C07D521/00 ,  C07D403/10 ,  C07D403/04 ,  C07D213/643 ,  C07C43/29 ,  C07C43/285

Abstract: The present invention concerns a process for arylating or vinylating or alkynating a nucleophilic compound. More particularly, the invention concerns arylating nitrogen-containing organic derivatives. The arylating or vinylating or alkynating process of the invention consists of reacting a nucleophilic compound with a compound carrying a leaving group and is characterized in that the reaction is carried out in the presence of an effective quantity of a catalyst based on a metallic element M selected from groups (VIII), (Ib) and (IIb) of the periodic table and at least one ligand comprising at least one imine function and at least one supplemental nitrogen atom as the chelating atoms.

公开(公告)号：CA2470141A1

公开(公告)日：2003-07-03

申请号：CA2470141

申请日：2002-12-20

Applicant: RHODIA CHIMIE SA

Inventor： SPINDLER JEAN-FRANCIS ,  CRISTAU HENRI-JEAN ,  CELLIER PASCAL ,  TAILLEFER MARC

IPC: C07D295/02 ,  C07B37/04 ,  C07B41/04 ,  C07B43/00 ,  C07B61/00 ,  C07C41/01 ,  C07C43/263 ,  C07C269/06 ,  C07C271/28 ,  C07D209/08 ,  C07D231/12 ,  C07D233/58 ,  C07D263/22

Abstract: La présente invention a pour objet un procédé de création d'une liaison carbone-carbone ou carbone-hétéroatome par réaction d'un composé insaturé porteur d'un groupe partant et d'un composé nucléophile. L'invention vise notamment la créaction de liaison carbone-azote selon un procédé d'arylation de dérivés organiques azotés.Le procédé, selon l'invention, de création d'un e liaison carbone-carbone ou carbone-hétéroatome par réaction d'un composé insaturé porteur d'un groupe partant et d'un composé nucléophile apportant u n atome de carbone ou un hétéroatome (HE) susceptible de se substituer au grou pe partant créant ainsi une liaison C-C ou C-HE est caractérisé par le fait que la réaction a lieu en présence d'une quantité efficace d'un catalyseur ô bas e d'un élément métallique M choisi dans le groupe (VIII), (Ib) et (IIb) de la classification périodique des éléments et d'au moins un ligand au moins bidenté comprenant au moins deux atomes de chélation qui sont au moins un atome d'oxygène et au moins un atome d'azote.

公开(公告)号：FR2833947A1

公开(公告)日：2003-06-27

申请号：FR0116547

申请日：2001-12-20

Applicant: RHODIA CHIMIE SA

Inventor： TAILLEFER MARC ,  CRISTAU HENRI JEAN ,  CELLIER PASCAL ,  SPINDLER JEAN FRANCIS

IPC: C07D295/02 ,  C07B37/04 ,  C07B41/04 ,  C07B43/00 ,  C07B61/00 ,  C07C41/01 ,  C07C43/263 ,  C07C269/06 ,  C07C271/28 ,  C07D209/08 ,  C07D231/12 ,  C07D233/58 ,  C07D263/22 ,  C07D295/033

Abstract: Process for the formation of a carbon-carbon or a carbon-heteroatom bond comprises reaction of an unsaturated compound having a leaving group with a nucleophilic compound having a carbon or heteroatom group capable of being substituted by the leaving group. Process for the formation of a carbon-carbon or a carbon-heteroatom bond comprises reaction of an unsaturated compound having a leaving group with a nucleophilic compound having a carbon or heteroatom group capable of being substituted by the leaving group. The reaction is conducted in the presence of a catalytic amount of a group (VIII), (Ib) or (IIb) metal and a ligand that is at least bidentate with at least two chelating atoms, one at least of which is O and one at least is N.

公开(公告)号：FR2833947B1

公开(公告)日：2004-02-06

申请号：FR0116547

申请日：2001-12-20

Applicant: RHODIA CHIMIE SA

Inventor： TAILLEFER MARC ,  CRISTAU HENRI JEAN ,  CELLIER PASCAL ,  SPINDLER JEAN FRANCIS

IPC: C07D295/02 ,  C07B37/04 ,  C07B41/04 ,  C07B43/00 ,  C07B61/00 ,  C07C41/01 ,  C07C43/263 ,  C07C269/06 ,  C07C271/28 ,  C07D209/08 ,  C07D231/12 ,  C07D233/58 ,  C07D263/22 ,  C07D295/033

Abstract: Process for the formation of a carbon-carbon or a carbon-heteroatom bond comprises reaction of an unsaturated compound having a leaving group with a nucleophilic compound having a carbon or heteroatom group capable of being substituted by the leaving group. Process for the formation of a carbon-carbon or a carbon-heteroatom bond comprises reaction of an unsaturated compound having a leaving group with a nucleophilic compound having a carbon or heteroatom group capable of being substituted by the leaving group. The reaction is conducted in the presence of a catalytic amount of a group (VIII), (Ib) or (IIb) metal and a ligand that is at least bidentate with at least two chelating atoms, one at least of which is O and one at least is N.