公开(公告)号：FR2691458A1

公开(公告)日：1993-11-26

申请号：FR9206391

申请日：1992-05-20

Applicant: RHONE POULENC CHIMIE ,  RHONE POULENC CHIMIE

Inventor： GUBELMANN MICHEL ,  GUBELMANN MICHEL ,  PERNOT HELENE ,  MALIVERNEY CHRISTIAN ,  MALIVERNEY CHRISTIAN ,  PERNOT HELENE

IPC: C07C253/30 ,  C07C255/07

Abstract: La présente invention concerne un procédé de déshydrocyanation de dinitriles aliphatiques en phase vapeur. Elle consiste plus précisément en un procédé de déshydrocyanation de dinitriles saturés, ramifiés, caractérisé en ce que des vapeurs d'un ou plusieurs desdits dinitriles saturés ramifiés sont mises en contact avec un échangeur de cation partiellement ou complètement acidifié. Les dinitriles saturés ramifiés qui sont soumis à la déshydrocyanation selon le présent procédé sont plus particulièrement le 2-méthyl-glutaronitrile, le 2-éthyl-succinonitrile, leurs mélanges entre eux ou les mélanges industriels les contenant.

公开(公告)号：ES2092793T3

公开(公告)日：1996-12-01

申请号：ES93420184

申请日：1993-05-07

Applicant: RHONE POULENC CHIMIE

Inventor： GUBELMANN MICHEL ,  MALIVERNEY CHRISTIAN ,  PERNOT HELENE

IPC: C07C253/30 ,  C07C255/07

Abstract: The present invention relates to a process for the dehydrocyanation of aliphatic dinitriles in the vapour phase. More precisely, it consists of a process for the dehydrocyanation of branched, saturated dinitriles, characterised in that vapours of one or more of the said branched, saturated dinitriles are brought into contact with a partially or completely acidified cation exchanger. The branched, saturated dinitriles which are subjected to the dehydrocyanation according to the present process are more particularly 2-methylglutaronitrile, 2-ethylsuccinonitrile, their mixtures with each other or industrial mixtures containing them.

公开(公告)号：CA2035573A1

公开(公告)日：1991-08-03

申请号：CA2035573

申请日：1991-02-01

Applicant: RHONE POULENC CHIMIE

Inventor： DOUSSAIN CLAUDE ,  GUBELMANN MICHEL ,  TIREL PHILIPPE-JEAN ,  PERNOT HELENE ,  GILBERT LAURENT ,  POPA JEAN-MICHEL

IPC: B01J27/18 ,  C01B25/26 ,  C01G1/00 ,  C07C17/16 ,  C07C21/18 ,  C07C29/124 ,  C07C31/34 ,  C01B25/12 ,  C01B13/14 ,  B01J27/14 ,  C07C29/58

Abstract: L'invention vise des composés chimiques et leurs utilisations. Ces composés chimiques répondent à la formule suivante sur sec : (EO4M), (Imp)p (I) avec E choisi dans le groupe des éléments de la colonne VB à l'exception de l'azote, de préférence le phosphore, - où M est un métal ou un mélange de métaux. Imp correspond à un composé d'imprégnation basique constitué de métal alcalino-terreux Alt, de préférence de métal alcalin Alc et leurs mélanges associés à un contreanion pour assurer la neutralité électrique. Le coefficient p est compris entre 10-2 et 1/3. Application à la catalyse de la solvolyse des halogénures d'alcoyle. Figure 1a.

公开(公告)号：FI910492A0

公开(公告)日：1991-02-01

申请号：FI910492

申请日：1991-02-01

Applicant: RHONE POULENC CHIMIE

Inventor： DOUSSAIN CLAUDE ,  GILBERT LAURENT ,  GUBELMANN MICHEL ,  PERNOT HELENE ,  POPA JEAN-MICHEL ,  TIREL PHILIPPE-JEAN

IPC: B01J27/18 ,  C01B25/26 ,  C01G1/00 ,  C07C17/16 ,  C07C21/18 ,  C07C29/124 ,  C07C31/34 ,  B01J

Abstract: The invention relates to chemical compounds and their use as catalysts in the solvolysis of alkyl halides. The chemical compounds, when dry, have formula (I): (EO4M)x(Imp)p(I) wherein E is selected from the group consisting of phosphorus, arsenic, antimony and bismuth, and is preferably phosphorus, and M is a metal or a mixture of metals. Imp corresponds to a basic impregnating compound consisting of alkaline earth metal, or preferably alkali metal, and their mixtures in combination with a counter-anion to ensure electrical neutrality. The coefficient p is between 10-2 and 1/3.

公开(公告)号：DE69304606T2

公开(公告)日：1997-04-03

申请号：DE69304606

申请日：1993-05-07

Applicant: RHONE POULENC CHIMIE

Inventor： GUBELMANN MICHEL ,  MALIVERNEY CHRISTIAN ,  PERNOT HELENE

IPC: C07C253/30 ,  C07C255/07

Abstract: The present invention relates to a process for the dehydrocyanation of aliphatic dinitriles in the vapour phase. More precisely, it consists of a process for the dehydrocyanation of branched, saturated dinitriles, characterised in that vapours of one or more of the said branched, saturated dinitriles are brought into contact with a partially or completely acidified cation exchanger. The branched, saturated dinitriles which are subjected to the dehydrocyanation according to the present process are more particularly 2-methylglutaronitrile, 2-ethylsuccinonitrile, their mixtures with each other or industrial mixtures containing them.

公开(公告)号：DE69304606D1

公开(公告)日：1996-10-17

申请号：DE69304606

申请日：1993-05-07

Applicant: RHONE POULENC CHIMIE

Inventor： GUBELMANN MICHEL ,  MALIVERNEY CHRISTIAN ,  PERNOT HELENE

IPC: C07C253/30 ,  C07C255/07

Abstract: The present invention relates to a process for the dehydrocyanation of aliphatic dinitriles in the vapour phase. More precisely, it consists of a process for the dehydrocyanation of branched, saturated dinitriles, characterised in that vapours of one or more of the said branched, saturated dinitriles are brought into contact with a partially or completely acidified cation exchanger. The branched, saturated dinitriles which are subjected to the dehydrocyanation according to the present process are more particularly 2-methylglutaronitrile, 2-ethylsuccinonitrile, their mixtures with each other or industrial mixtures containing them.

公开(公告)号：CA2096612C

公开(公告)日：1998-08-11

申请号：CA2096612

申请日：1993-05-19

Applicant: RHONE POULENC CHIMIE

Inventor： GUBELMANN MICHEL ,  MALIVERNEY CHRISTIAN ,  PERNOT HELENE

IPC: C07C253/30 ,  C07C255/09

Abstract: La présente invention concerne un procédé de déshydrocyanation de dinitriles aliphatiques en phase vapeur. Elle consiste plus précisément en un procédé de déshydrocyanation de dinitriles aliphatiques saturés ramifiés, caractérisé en ce que des vapeurs d'un ou plusieurs desdits dinitriles aliphatiques saturés ramifiés sont mises en contact avec un catalyseur comprenant un échangeur de cation partiellement ou complètement acidifié, à une température allant de 300.degree.C à 600.degree.C. Les dinitriles aliphatiques saturés ramifiés qui sont soumis à la déshydrocyanation selon le présent procédé sont plus particulièrement le 2-méthyl-glutaronitrile, le 2-éthyl-succinonitrile, leurs mélanges entre eux ou les mélanges industriels les contenant.

公开(公告)号：SG45345A1

公开(公告)日：1998-01-16

申请号：SG1996004149

申请日：1993-05-07

Applicant: RHONE POULENC CHIMIE

Inventor： GUBELMANN MICHEL ,  MALIVERNEY CHRISTIAN ,  PERNOT HELENE

IPC: C07C253/30 ,  C07C255/07

Abstract: The present invention relates to a process for the dehydrocyanation of aliphatic dinitriles in the vapour phase. More precisely, it consists of a process for the dehydrocyanation of branched, saturated dinitriles, characterised in that vapours of one or more of the said branched, saturated dinitriles are brought into contact with a partially or completely acidified cation exchanger. The branched, saturated dinitriles which are subjected to the dehydrocyanation according to the present process are more particularly 2-methylglutaronitrile, 2-ethylsuccinonitrile, their mixtures with each other or industrial mixtures containing them.

公开(公告)号：AU7021391A

公开(公告)日：1991-08-08

申请号：AU7021391

申请日：1991-02-01

Applicant: RHONE POULENC CHIMIE

Inventor： DOUSSAIN CLAUDE ,  GILBERT LAURENT ,  GUBELMANN MICHEL ,  PERNOT HELENE ,  POPA JEAN-MICHEL ,  TIREL PHILIPPE-JEAN

IPC: B01J27/18 ,  C01B25/26 ,  C01G1/00 ,  C07C17/16 ,  C07C21/18 ,  C07C29/124 ,  C07C31/34 ,  C01G28/02 ,  C01G29/00 ,  C01G30/02 ,  C01D17/00 ,  C01B25/45 ,  C01B25/30 ,  B01J27/16 ,  B01J23/18

Abstract: The invention relates to chemical compounds and their use as catalysts in the solvolysis of alkyl halides. The chemical compounds, when dry, have formula (I): (EO4M)x(Imp)p(I) wherein E is selected from the group consisting of phosphorus, arsenic, antimony and bismuth, and is preferably phosphorus, and M is a metal or a mixture of metals. Imp corresponds to a basic impregnating compound consisting of alkaline earth metal, or preferably alkali metal, and their mixtures in combination with a counter-anion to ensure electrical neutrality. The coefficient p is between 10-2 and 1/3.

公开(公告)号：FR2691458B1

公开(公告)日：1994-07-08

申请号：FR9206391

申请日：1992-05-20

Applicant: RHONE POULENC CHIMIE

Inventor： GUBELMANN MICHEL ,  MALIVERNEY CHRISTIAN ,  PERNOT HELENE

IPC: C07C253/30 ,  C07C255/07

Abstract: The present invention relates to a process for the dehydrocyanation of aliphatic dinitriles in the vapour phase. More precisely, it consists of a process for the dehydrocyanation of branched, saturated dinitriles, characterised in that vapours of one or more of the said branched, saturated dinitriles are brought into contact with a partially or completely acidified cation exchanger. The branched, saturated dinitriles which are subjected to the dehydrocyanation according to the present process are more particularly 2-methylglutaronitrile, 2-ethylsuccinonitrile, their mixtures with each other or industrial mixtures containing them.