公开(公告)号：US3671582A

公开(公告)日：1972-06-20

申请号：US78159468

申请日：1968-12-05

Applicant: RHONE POULENC SA

Inventor： DAVID REGINALD ,  ESTIENNE JEAN

IPC: C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C51/32

CPC classification number: C07C45/36 ,  C07C45/34 ,  C07C45/35 ,  C07C47/22

Abstract: Aldehydes, ketones and carboxylic acids are made by the oxidation of organic compounds, especially olefines, with oxygen in the presence of a Group VIII metal catalyst and in a liquid medium comprising dimethylsulphoxide alone or mixed with water.

Abstract translation: 醛，酮和羧酸通过在第VIII族金属催化剂存在下，在含有二甲基亚砜或与水混合的液体介质中通过氧化有机化合物，特别是烯烃与氧来制备。

公开(公告)号：US3929870A

公开(公告)日：1975-12-30

申请号：US47382874

申请日：1974-05-28

Applicant: RHONE POULENC SA

Inventor： DAVID REGINALD ,  ESTIENNE JEAN

IPC: C07C69/675 ,  A23L29/10 ,  B01F17/00 ,  B01F17/36 ,  B01F17/38 ,  C07C69/68

CPC classification number: B01F17/0021 ,  A23L29/10

Abstract: Emulsifiers are made by esterifying one or two of the carboxyl groups of citric acid with a hydroxy-ester formed from a long chain alcohol and an acid of formula:

in which R1 and R2 are each hydrogen or methyl.

Abstract translation: 乳化剂是通过将柠檬酸的一个或两个羧基与由长链醇和下式的酸形成的羟基酯酯化：R1 | HO-C-COOH | R2，其中R1和R2各自为氢或 甲基。

公开(公告)号：US3624147A

公开(公告)日：1971-11-30

申请号：US3624147D

申请日：1969-05-20

Applicant: RHONE POULENC SA

Inventor： DAVID REGINALD ,  ESTIENNE JEAN

IPC: C07C51/25 ,  C07C57/04

CPC classification number: C07C51/252 ,  C07C57/04

Abstract: Acrylic acid is prepared by oxidizing propylene with air in the presence of water and a platinum, rhodium, rutheniun or palladium metal catalyst at a temperature above 50* C. and a pressure exceeding 5 bars gauge. A supported palladium catalyst is preferred. Acrylic acid is obtained in about 60 percent yield based on propylene converted and the small amounts of acrolein obtained may be oxidized to acrylic acid.

公开(公告)号：CA754178A

公开(公告)日：1967-03-07

申请号：CA754178D

Applicant: RHONE POULENC SA

Inventor： ACHARD RENE V J ,  ESTIENNE JEAN ,  DAVID REGINALD

公开(公告)号：DE1255102B

公开(公告)日：1967-11-30

申请号：DER0041937

申请日：1965-11-09

Applicant: RHONE POULENC SA

Inventor： ACHARD RENE VICTOR JULIEN ,  DAVID REGINALD ,  ESTIENNE JEAN

IPC: C07C67/055 ,  C07C69/01 ,  C07C69/12

公开(公告)号：GB1223783A

公开(公告)日：1971-03-03

申请号：GB2577469

申请日：1969-05-20

Applicant: RHONE POULENC SA

Inventor： DAVID REGINALD ,  ESTIENNE JEAN

IPC: C07C51/25

Abstract: 1,223,783. Acrylic acid. RHONE-POULENC S.A. 20 May, 1969 [21 May, 1968], No. 25774/69. Heading C2C. Acrylic acid is prepared by oxidizing propylene with molecular oxygen or a gas containing molecular oxygen in the presence of water and a noble metal of Group VIII of the Periodic Table at a temperature above 50‹ C. and under a pressure exceeding 5 bars gauge. The catalyst may be deposited on a carrier such as alumina, silica gel, aluminium oxide, aluminium silicate, pumice, active charcoal or bentonite. Examples describe the use of palladium on carbon black or alumina.

公开(公告)号：CA706422A

公开(公告)日：1965-03-23

申请号：CA706422D

Applicant: RHONE POULENC SA

Inventor： ESTIENNE JEAN ,  BO GILBERT ,  DAVID REGINALD ,  ACHARD RENE

公开(公告)号：DE2430862A1

公开(公告)日：1975-01-16

申请号：DE2430862

申请日：1974-06-27

Applicant: RHONE POULENC SA

Inventor： DAVID REGINALD ,  ESTIENNE JEAN

IPC: C08K5/00 ,  A21D2/14 ,  A23L29/10 ,  C07C69/67 ,  C08K5/10 ,  C08K5/11 ,  C08L1/00 ,  C08L27/00 ,  C09K23/36 ,  C07C69/44 ,  B01F17/36

Abstract: The esters have formula:- where n is 1-2, R1R2 are H or CH3, R is 14-22C sat. or unsat. aliphatic, Y is X or H, alkali metal or -NH4 and are prepd. by reaction of an ester of hydroxycarboxylic acid HO-X with adipic acid in mol. ratio 0.8:1-1.2:1 or 1.8:1-2.2:1 at 150-230 pref. 200-220 degrees C or by reacting 1-2 moles hydroxycarboxylic acid and 0.8-1.2 or 1.8-2.2 moles alcohol R-OH and 1 mole adipic acid simultaneously. R is hexadecyl or octadecyl e.g. product is di- or mono adipic ester(s) of hexa(octa)decyl lactate.

公开(公告)号：CA823690A

公开(公告)日：1969-09-23

申请号：CA823690D

Applicant: RHONE POULENC SA

Inventor： ESTIENNE JEAN ,  DAVID REGINALD

公开(公告)号：DE1813182A1

公开(公告)日：1969-09-04

申请号：DE1813182

申请日：1968-12-06

Applicant: RHONE POULENC SA

Inventor： DAVID REGINALD ,  ESTIENNE JEAN

IPC: C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C27/12

Abstract: Aldehydes, ketones and carboxylic acids are made by the oxidation of organic compounds, especially olefines, with oxygen in the presence of a Group VIII metal catalyst and in a liquid medium comprising dimethylsulphoxide alone or mixed with water.