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公开(公告)号:KR20180026448A
公开(公告)日:2018-03-12
申请号:KR20187000365
申请日:2016-06-30
Applicant: SHELL INT RESEARCH
Inventor: NACHIAPPAN ESWARAMURTHI , ELEVELD MICHIEL BAREND
IPC: C08G18/48 , C08G18/76 , C08G65/26 , C08G101/00
CPC classification number: C08G18/4812 , C08G18/4841 , C08G18/4866 , C08G18/7621
Abstract: 가요성폴리우레탄포옴을제조하는방법으로서, 상기방법은상기폴리우레탄포옴을제공하기위해폴리에테르폴리올을포옴-형성반응물과반응시키는단계를포함하고, 여기서상기폴리에테르폴리올은적어도 50 ppm의잠재적알데하이드함량을포함하고/하거나, 상기폴리에테르폴리올은적어도 200 ppm의유리알데하이드함량을포함하는알킬렌옥사이드의개환중합으로부터얻어질수 있다. 본방법에의해얻어질수 있는포옴, 및폴리에테르폴리올의용도가또한개시된다.
Abstract translation: 一种制造软质聚氨酯泡沫的方法,包括使聚醚多元醇与泡沫形成反应物反应以提供聚氨酯泡沫,其中聚醚多元醇具有至少50ppm的潜伏醛 和/或聚醚多元醇可以由包含至少200ppm的游离醛含量的烯化氧的开环聚合获得。 还公开了可以通过本发明方法获得的泡沫和聚醚多元醇的用途。
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公开(公告)号:WO2011026989A3
公开(公告)日:2011-10-27
申请号:PCT/EP2010063080
申请日:2010-09-07
Applicant: SHELL INT RESEARCH , VAN EETVELDE ELS , ELEVELD MICHIEL BAREND , MINEUR WALTHERUS PETRUS CASPARUS , SWAN CHRISTOPHE MARTIN , TAN TIEW IMM
Inventor: VAN EETVELDE ELS , ELEVELD MICHIEL BAREND , MINEUR WALTHERUS PETRUS CASPARUS , SWAN CHRISTOPHE MARTIN , TAN TIEW IMM
CPC classification number: C08G18/4866 , C08G65/2663 , C08G2101/00
Abstract: The invention relates to a process for preparing a polyurethane foam, wherein a polyether polyol and a polyisocyanate are reacted in the presence of: a blowing agent; of from 1 to 30 ppmw, based on the polyether polyol, of metals derived from a composite metal cyanide complex catalyst; and of from 0.5 to 100 ppmw, based on the polyether polyol, of a phosphoric acid compound comprising a phosphoric acid selected from orthophosphoric acid, polyphosphoric acid and polymetaphosphoric acid, and/or a partial ester of such a phosphoric acid.
Abstract translation: 本发明涉及一种制备聚氨酯泡沫的方法,其中聚醚多元醇和多异氰酸酯在发泡剂存在下反应; 基于聚醚多元醇1至30ppmw的衍生自复合金属氰化物配合物催化剂的金属; 和基于聚醚多元醇的0.5至100ppmw的包含选自正磷酸,多磷酸和聚偏磷酸的磷酸的磷酸化合物和/或这种磷酸的偏酯。
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3.
公开(公告)号:WO9940144A8
公开(公告)日:2000-01-20
申请号:PCT/EP9900857
申请日:1999-02-09
Applicant: SHELL INT RESEARCH , ELEVELD MICHIEL BAREND , KARZIJN WILLEM , KEMPEN RONALD VAN
Inventor: ELEVELD MICHIEL BAREND , KARZIJN WILLEM , VAN KEMPEN RONALD
IPC: C08G65/32 , C08F283/06 , C08F290/06 , C08G18/40 , C08G18/63 , C08G65/14 , C08G65/332
CPC classification number: C08G18/636 , C08F290/061 , C08G18/635 , C08G65/14 , C08G65/3324
Abstract: Process for the preparation of a macromer suitable as a stabiliser precursor in a polymer polyol, which process comprises reacting a polyol with a cyclic dicarboxylic acid anhydride not containing any polymerizable double bond, and subsequently reacting the adduct thus obtained with an epoxide compound containing a polymerisable double bond. The resulting macromer has a nominal molecular weight of at least 4000 and can be applied for the preparation of a polymer polyol by polymerizing in a base polyol at least one ethylenically unsaturated monomer in the presence of a polymerization initiator and a macromer. The polymer polyol thus obtained is very suitable for manufacturing flexible polyurethane foams.
Abstract translation: 用于制备适合作为聚合物多元醇中的稳定剂前体的大分子单体的方法,该方法包括使多元醇与不含任何可聚合双键的环状二羧酸酐反应,然后使由此获得的加合物与含有可聚合的环氧化合物 双键。 得到的大分子单体的标称分子量至少为4000,可以通过在聚合引发剂和大分子单体的存在下在基础多元醇中聚合至少一种烯属不饱和单体来应用聚合物多元醇的制备。 由此获得的聚合物多元醇非常适用于制造柔性聚氨酯泡沫体。
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公开(公告)号:RU2734761C2
公开(公告)日:2020-10-23
申请号:RU2018125874
申请日:2016-12-19
Applicant: SHELL INT RESEARCH
Inventor: PRADHAN PRANAYA MAN SINGH , NACHIAPPAN ESWARAMURTHI , ELEVELD MICHIEL BAREND , DHANAPAL PREM KUMAR
Abstract: Настоящееизобретениеотноситсяк полиуретановойпене, имеющейэластичностьпоменьшеймере 50%, ик способуееполучения. Указанныйспособвключаетреакцию: (i) первогополиэфирполиола, (ii) второгополиэфирполиолаи (iii) одногоилиболееароматическихполиизоцианатовв присутствииодногоилиболеекатализаторовгелеобразованияи/иливспенивания. Первыйполиэфирполиолимеетполиэфирныецепи, содержащиедолюэтиленоксиданеболее 20%, гдеостатокдолиалкиленоксидав полиэфирнойцепиполученизпропилен- и/илибутиленоксида. Доляпервичныхгидроксильныхгруппв первомполиэфирполиолесоставляетнеболеечем 20%, гидроксильноечислопоменьшеймере 40 иноминальнаяфункциональностьпоменьшеймереот 2,5 инеболее 3,0. Второйполиэфирполиолимеетполиэфирныецепи, содержащиедолюэтиленоксидапоменьшеймере 50%, гдеостатокдолиалкиленоксидав полиэфирнойцепиполученизпропилен- и/илибутиленоксида. Настоящийспособявляетсяулучшеннымспособомполучениявысокоэластичнойполиуретановойпеныизполиэфирполиола, получаемогос помощьюДМЦ-катализируемогопроцессабезпотребностив отдельнойпериодическойКОН-катализированнойстадиипривитияэтиленоксида. 2 н. и 6 з.п. ф-лы, 2 табл., 2 пр.
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公开(公告)号:SG11201707371PA
公开(公告)日:2017-10-30
申请号:SG11201707371P
申请日:2016-04-06
Applicant: SHELL INT RESEARCH
Abstract: A polyether polyol containing composite metal cyanide complex catalyst residue, said polyether polyol having a functionality in the range of from 2.9 to 4.5, a hydroxyl value in the range of from 28 to 42 and containing in the range of from 8 to 60 wt % ethylene oxide moieties randomly distributed throughout the polyether chains.
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6.
公开(公告)号:BR112013019934A2
公开(公告)日:2016-12-13
申请号:BR112013019934
申请日:2012-02-23
Applicant: SHELL INT RESEARCH
IPC: C08G65/00
Abstract: processo para a preparação de um poliéter poliol, e, sistema de reator para a preparação de polióis a presente invenção provê um processo para a preparação de um poliéter poliol, referido processo compreendendo polimerizar um ou mais óxido de alquileno na presença de um catalisador de complexo de cianeto multimetálico e de um composto iniciador, em que o processo é realizado em um vaso de reator equipado com meios para agitar seu conteúdo e o um ou mais óxidos de alquileno são introduzidos em uma mistura agitada compreendendo o catalisador de complexo de cianeto multimetálico e o iniciador via um dispositivo de entrada de alimentação, referido dispositivo de entrada de alimentação compreendendo um difusor. a presente invenção também se refere a um sistema de reator para a preparação de polióis, referido sistema de reator compreendendo: (a) um vaso de reator; (b) meios para agitar o conteúdo do vaso do reator; (c) um tubo de entrada apropriado para fornecer o inciador e catalisador para o sistema de reator; (d) um tubo de saída para remover o material do sistema de reator; e (e) um dispositivo de entrada de alimentação para a adição de óxidos de alquileno para o vaso do reator, referido dispositivo de entrada de alimentação compreendendo um difusor.
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公开(公告)号:SG192049A1
公开(公告)日:2013-08-30
申请号:SG2013055272
申请日:2012-02-23
Applicant: SHELL INT RESEARCH
Abstract: The present invention provides a process for the preparation of a polyether polyol, said process comprising polymerisingone or more alkylene oxides in the presence of a multimetal cyanide complex catalyst and an initiator compound, wherein the process is carried out in a reactor vessel equipped with means for agitating its contents and the one or more alkylene oxides are supplied to an agitated mixture comprising the multimetal cyanide complex catalyst and the initiator via a feed inlet device, said feed inlet device comprising a sparger. The present invention also provides a reactor system for the preparation of polyols, said reactor system comprising: (a)a reactor vessel; (b)means for agitating the contents of the reactor vessel; (c)an inlet tube suitable for supplying initiator and catalyst to the reactor system; (d)an outlet tube for removing material from the reactor system; and (e) a feed inlet device for the addition of alkylene oxides to the reactor vessel, said feed inlet device comprising a sparger.
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公开(公告)号:SG178950A1
公开(公告)日:2012-04-27
申请号:SG2012014742
申请日:2010-09-07
Applicant: SHELL INT RESEARCH
Inventor: VAN EETVELDE ELS , ELEVELD MICHIEL BAREND , MINEUR WALTHERUS PETRUS CASPARUS , SWAN CHRISTOPHE MARTIN , TAN TIEW IMM
Abstract: The invention relates to a process for preparing a polyurethane foam, wherein a polyether polyol and a polyisocyanate are reacted in the presence of: a blowing agent; of from 1 to 30 ppmw, based on the polyether polyol, of metals derived from a composite metal cyanide complex catalyst; and of from 0.5 to 100 ppmw, based on the polyether polyol, of a phosphoric acid compound comprising a phosphoric acid selected from orthophosphoric acid, polyphosphoric acid and polymetaphosphoric acid, and/or a partial ester of such a phosphoric acid.
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公开(公告)号:ES2327722T3
公开(公告)日:2009-11-03
申请号:ES02790396
申请日:2002-11-18
Applicant: SHELL INT RESEARCH
Inventor: ELEVELD MICHIEL BAREND , MEURS JAN HERMEN HENDRIK
Abstract: El procedimiento que comprende poner en contacto un iniciador con óxido de alquileno en presencia de fluoruro de hidrógeno y un catalizador doble de complejo de cianuro metálico.
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公开(公告)号:AT373685T
公开(公告)日:2007-10-15
申请号:AT05752515
申请日:2005-06-08
Applicant: SHELL INT RESEARCH
Inventor: DUIJGHUISEN HENRICUS PETRUS BE , ELEVELD MICHIEL BAREND
Abstract: Process of preparing odour-lean polyether polyol from crude polyether polyol prepared with the help of double metal cyanide complex catalyst which process comprises stripping the crude polyether polyol in a vessel at a temperature of from 50 to 200° C., at a ratio of total amount of stripping gas introduced into the vessel to total amount of polyol introduced into the vessel of from 20 to 600x10 -3 m 3 of inert gas per kg of polyol and at a residence time of the polyol of from 0.5 to 120 minutes.
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