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公开(公告)号：JPH107899A
公开(公告)日：1998-01-13
申请号：JP8301097
申请日：1997-04-01
Applicant: SHELL INT RESEARCH
Inventor： MODIC MICHAEL JOHN
Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition which comprises a polyphenylene ether and a specific elastomer block copolymer and has a good cold shock resistance and excellent melt-flow properties. SOLUTION: (A) Apolyphenylene ether [suitably poly(2,6-dimehyl-1-4phenylene) ether], (B) a styrene resin (suitably polystyrene) and (C) an elastomer block copolymer comprising an intermediate block of ethylene/propylene copolymer and both terminal blocks of styrene polymer are formulated so that the component (C) amounts to 2-40wt.% based on the whole weight of the composition. the component (C) is preferably a linear styrene-ethylene/propylene-styrene block copolymer. The weight ratio of the components (A)/(B) is preferably 75/25 to 50/50. These components (A), (B) and (C) are preferably mixed in their molten state. When necessary, the objective composition is prevented from deterioration by adding small amounts of stabilizers.
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公开(公告)号：JPH10101895A
公开(公告)日：1998-04-21
申请号：JP25903997
申请日：1997-09-24
Applicant: SHELL INT RESEARCH
Inventor： MODIC MICHAEL JOHN
Abstract: PROBLEM TO BE SOLVED: To obtain a thermoplastic elastomer composition excellent in adhesion to polar matrices such as polycarbonate and suitable for over-molded molding materials by including a specific elastomeric block copolymer, a specific rubber and a plasticizer. SOLUTION: This elastomer composition contains (A) preferably 32-65wt.% hydrogenated elastomeric block copolymer having two or more resinous endblocks of polymerized monovinyl aromatic compound such as styrene and an elastomeric midblock of polymerized conjugated diene such as 1,3-butadiene, (B) preferably 20-45wt.% plasticizer such as oil, (C) preferably 5-20% ethylene- propylene-diene monomer rubber grafted with styrene-acrylonitrile and (D) 3-10wt.% fluidity promoter derived from α-methylstyrene. Furthermore, the composition is preferably extruded onto a polar polymer to produce an over- molded polar polymer molding product.
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公开(公告)号：JPH11148006A
公开(公告)日：1999-06-02
申请号：JP26856598
申请日：1998-09-22
Applicant: SHELL INT RESEARCH
Inventor： CENENS JOZEF LUCIEN RUDOLF , COIGNOUL EMANUELLE , KADRI ILHAM , MASSE MICHAEL ALAN , MODIC MICHAEL JOHN
IPC: C08G18/10 , C08G18/62 , C08K5/01 , C08L75/04 , C08L101/00
Abstract: PROBLEM TO BE SOLVED: To provide a compounded rubber composition having excellent stability to heat, UV and hydrolysis and excellent low-temperature mechanical properties. SOLUTION: The subject rubber composition is composed of (A) a polyurethane produced by using a hydrogenated polydiene diol as a base and having a hard segment content of >=10% and (B) 10-400 phr of a nonpolar extender oil and/or (C) 5-100 phr of one or more kinds of thermoplastic resins.
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公开(公告)号：JPH1077382A
公开(公告)日：1998-03-24
申请号：JP20345797
申请日：1997-07-29
Applicant: SHELL INT RESEARCH
Inventor： HIMES GLENN ROY , MODIC MICHAEL JOHN , SHAFER DAVID LEE
Abstract: PROBLEM TO BE SOLVED: To provide an oily gel composition which has high operating temperature properties and is peelable and pumpable. SOLUTION: This is an oily gel composition having high operating temperature properties, can be peelable, and comprises (a) 100 pts.wt. of a hydrogenated vinyl aromatic hydrocarbon-butadiene-vinyl aromatic hydrocarbon block copolymer having the whole weight average molecular weight of 30,000-300,000, the weight-average molecular weight of the vinyl aromatic hydrocarbon block of 4,000-35,000 and has the vinyl content of at least 45wt.%, and (b) 900-4,900 pts.wt. of an oil or a mixture thereof with a polyolefin wax and/or an extender liquid.
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公开(公告)号：JPH10287805A
公开(公告)日：1998-10-27
申请号：JP9439498
申请日：1998-04-07
Applicant: SHELL INT RESEARCH
Inventor： MODIC MICHAEL JOHN
Abstract: PROBLEM TO BE SOLVED: To obtain a polymer composition having high toughness as well as excellent processability by compounding a modifying agent containing a specific block copolymer and a low-density polyolefin to a polyphenylene ether/ polystyrene blend. SOLUTION: A polyphenylene ether(PPE)/polystyrene(PS) blend is compounded with a modifying agent containing (A) a hydrogenated elastomeric block copolymer containing at least two dendrite terminal blocks composed of a polymerizable monovinyl aromatic compound (preferably styrene) and an elastomeric middle block composed of a polymerizable conjugated diene (preferably butadiene) and (B) a polyolefin having a density of
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Patent Agency Ranking
公开(公告)号：JPH10130453A
公开(公告)日：1998-05-19
申请号：JP25903897
申请日：1997-09-24
Applicant: SHELL INT RESEARCH
Inventor： MODIC MICHAEL JOHN
Abstract: PROBLEM TO BE SOLVED: To obtain a soft rubberlike thermoplastic elastomer compsn. which strongly adheres to a rigid (polar) substrate such as a polycarbonate or ABS by compounding a hydrogenated elastomeric block copolymer having a specified structure with a plasticiazer, an olefin-acrylate polymer, and a polyolefin. SOLUTION: The hydrogenated elastomeric block copolymer has terminal resin blocks each formed from at least two kinds of monovinylarom. compd. and a central elastomer block formed from a conjugated diene. The compsn. pref. contains 15-60wt.% block copolymer, 15-45wt.% plasticizer, 5-20wt.% olefin- acrylate polymer (pref. an ethylene-acrylate polymer), and 0.1-20wt.% polyolefin (pref. polypropylene).
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7.发明公开
公开(公告)号：EP0799857A3
公开(公告)日：1997-12-29
申请号：EP97200971
申请日：1997-04-02
Applicant: SHELL INT RESEARCH
Inventor： MODIC MICHAEL JOHN
CPC classification number: C08L25/06 , C08L53/025 , C08L71/123 , C08L2666/02 , C08L2666/14 , C08L2666/04
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公开(公告)号：DE69708815D1
公开(公告)日：2002-01-17
申请号：DE69708815
申请日：1997-09-23
Applicant: SHELL INT RESEARCH
Inventor： MODIC MICHAEL JOHN
Abstract: The present invention relates to A thermoplastic elastomer composition comprising: a hydrogenated elastomeric block copolymer having at least two resinous endblocks of polymerized monovinyl aromatic compound and an elastomeric midblock of polymerized conjugated diene; a plasticizer; and an ethylene-propylene-diene monomer rubber grafted with styrene-acrylonitrile. The present invention further relates to a process for the preparation of an overmoulded polar polymer shape; to an overmoulded polar polymer shape; and to articles containing the overmoulded polar polymer shape.
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公开(公告)号：ES2158444T3
公开(公告)日：2001-09-01
申请号：ES97202911
申请日：1997-09-23
Applicant: SHELL INT RESEARCH
Inventor： MODIC MICHAEL JOHN
Abstract: A thermoplastic elastomer composition comprises: (a) a hydrogenated elastomeric block copolymer having at least two resinous end-blocks of polymerised monovinyl aromatic compound and an elastomeric mid-block of polymerised conjugated diene; (b) a mid-block plasticiser; (c) an ethylene-acrylate polymer; (d) a polypropylene; and (e) a stabiliser. Also claimed is a process for improving adhesion of a thermoplastic elastomer to a polar matrix which comprises: (a) mixing a hydrogenated elastomeric block copolymer as above with polypropylene and white mineral oil to form a first mixture; (b) mixing an ethylene-acrylate polymer with the first mixture to form a second mixture; (c) extruding the second mixture; (d) moulding a plaque comprising a polar polymer; and (e) moulding the extrudate onto the polar plaque. Further claimed is a thermoplastic elastomer made by the above process.
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公开(公告)号：DE69704597D1
公开(公告)日：2001-05-23
申请号：DE69704597
申请日：1997-09-23
Applicant: SHELL INT RESEARCH
Inventor： MODIC MICHAEL JOHN
Abstract: A thermoplastic elastomer composition comprises: (a) a hydrogenated elastomeric block copolymer having at least two resinous end-blocks of polymerised monovinyl aromatic compound and an elastomeric mid-block of polymerised conjugated diene; (b) a mid-block plasticiser; (c) an ethylene-acrylate polymer; (d) a polypropylene; and (e) a stabiliser. Also claimed is a process for improving adhesion of a thermoplastic elastomer to a polar matrix which comprises: (a) mixing a hydrogenated elastomeric block copolymer as above with polypropylene and white mineral oil to form a first mixture; (b) mixing an ethylene-acrylate polymer with the first mixture to form a second mixture; (c) extruding the second mixture; (d) moulding a plaque comprising a polar polymer; and (e) moulding the extrudate onto the polar plaque. Further claimed is a thermoplastic elastomer made by the above process.
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