公开(公告)号：JPH11152238A

公开(公告)日：1999-06-08

申请号：JP23853098

申请日：1998-08-25

Applicant: SHELL INT RESEARCH

Inventor： ARNOLDY PETER ,  BOLINGER CORNELIS MARK ,  MUL WILHELM PETRUS

IPC: B01J27/228 ,  C07B61/00 ,  C07C27/22 ,  C07C29/16 ,  C07C45/50

Abstract: PROBLEM TO BE SOLVED: To provide a method for hydroformylating an ethylene-based unsaturated compound. SOLUTION: In this method for hydroformylating an ethylene unsaturated compound with carbon monoxide and hydrogen in the presence of a catalyst system composed of (a) a platinum group cation, (b) a nonhalide, (c) at least one bidentate ligand of the formula; R R M RM R R (in the formula, M and M are each independently phosphorus, arsenic or antimony atom; Ra bifunctional cross-linking group containing 1-4 atoms) and (d) a halide anion selected from the group consisting of a chloride, an iodide, a bromide and its mixture, water in an amount larger than 0.6 wt.% based on the total of the reaction mixture and equal to or smaller than the solubility limit under the reaction conditions.

公开(公告)号：DE69803258T2

公开(公告)日：2002-07-25

申请号：DE69803258

申请日：1998-08-26

Applicant: SHELL INT RESEARCH

Inventor： ARNOLDY PETER ,  BOLINGER CORNELIS MARK ,  MUL WILHELM PETRUS

IPC: B01J27/228 ,  C07B61/00 ,  C07C27/22 ,  C07C29/16 ,  C07C45/50

Abstract: A process for the hydroformylation of ethylenically unsaturated compounds with carbon monoxide and hydrogen in the presence of a catalyst system comprising a) a source of platinum group metal cations; b) a source of non-halide anions; c) a source of at least one bidentate ligand of the formula R R M RM R R wherein M and M independently represent a phosphorus, arsenic or antimony atom, R represents a bivalent bridging group containing from 1-4 atoms in the bridge, R and R independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M , and R and R independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M ; and d) a source of halide anions chosen from the group of chloride, iodide and bromide and mixtures thereof, characterised by the additional presence of water, in an amount of more than 0.6 wt% based on the total of the reaction mixture and up to its solubility limit under the reaction conditions.

公开(公告)号：DE69803258D1

公开(公告)日：2002-02-21

申请号：DE69803258

申请日：1998-08-26

Applicant: SHELL INT RESEARCH

Inventor： ARNOLDY PETER ,  BOLINGER CORNELIS MARK ,  MUL WILHELM PETRUS

IPC: B01J27/228 ,  C07B61/00 ,  C07C27/22 ,  C07C29/16 ,  C07C45/50

Abstract: A process for the hydroformylation of ethylenically unsaturated compounds with carbon monoxide and hydrogen in the presence of a catalyst system comprising a) a source of platinum group metal cations; b) a source of non-halide anions; c) a source of at least one bidentate ligand of the formula R R M RM R R wherein M and M independently represent a phosphorus, arsenic or antimony atom, R represents a bivalent bridging group containing from 1-4 atoms in the bridge, R and R independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M , and R and R independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M ; and d) a source of halide anions chosen from the group of chloride, iodide and bromide and mixtures thereof, characterised by the additional presence of water, in an amount of more than 0.6 wt% based on the total of the reaction mixture and up to its solubility limit under the reaction conditions.

公开(公告)号：CA2245486C

公开(公告)日：2008-01-08

申请号：CA2245486

申请日：1998-08-25

Applicant: SHELL INT RESEARCH

Inventor： BOLINGER CORNELIS MARK ,  MUL WILHELM PETRUS ,  ARNOLDY PETER

IPC: B01J27/228 ,  C07C31/02 ,  C07B61/00 ,  C07C27/22 ,  C07C29/16 ,  C07C45/50 ,  C07C47/02

Abstract: A process for the hydroformylation of ethylenically unsaturated compounds with carbon monoxide and hydrogen in the presence of a catalyst system comprising a) a source of platinum group metal cations; b) a source of non-halide anions; c) a source of at least one bidentate ligand of the formula R1R2M1RM2R3R4 (I) wherein M1 and M2 independently represent a phosphorus, arsenic or antimony atom, R represents a bivalent bridging group containing from 1-4 atoms in the bridge, R1 and R2 independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M1, and R3 and R4 independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M2% and d) a source of halide anions chosen from the group of chloride, iodide and bromide and mixtures thereof, characterised by the additional presence of water, in an amount of more than 0.6 wt% based on the total of the reaction mixture and up to its solubility limit under the reaction conditions.

公开(公告)号：CA2245486A1

公开(公告)日：1999-02-27

申请号：CA2245486

申请日：1998-08-25

Applicant: SHELL INT RESEARCH

Inventor： ARNOLDY PETER ,  MUL WILHELM PETRUS ,  BOLINGER CORNELIS MARK

IPC: B01J27/228 ,  C07B61/00 ,  C07C27/22 ,  C07C29/16 ,  C07C45/50 ,  C07C31/02 ,  C07C47/02

Abstract: A process for the hydroformylation of ethylenically unsaturated compounds with carbon monoxide and hydrogen in the presence of a catalyst system comprising a) a source of platinum group metal cations; b) a source of non-halide anions; c) a source of at least one bidentate ligand of the formula R1R2M1RM2R3R4 (I) wherein M1 and M2 independently represent a phosphorus, arsenic or antimony atom, R represents a bivalent bridging group containing from 1-4 atoms in the bridge, R1 and R2 independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M1, and R3 and R4 independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M2; and d) a source of halide anions chosen from the group of chloride, iodide and bromide and mixtures thereof, characterised by the additional presence of water, in an amount of more than 0.6 wt% based on the total of the reaction mixture and up to its solubility limit under the reaction conditions.

公开(公告)号：ZA9807663B

公开(公告)日：1999-02-24

申请号：ZA9807663

申请日：1998-08-25

Applicant: SHELL INT RESEARCH

Inventor： ARNOLDY PETER ,  BOLINGER CORNELIS MARK ,  MUL WILHELM PETRUS

IPC: B01J27/228 ,  C07B61/00 ,  C07C27/22 ,  C07C29/16 ,  C07C45/50 ,  C07C

CPC classification number: C07C45/50 ,  C07C29/16 ,  C07C31/125 ,  C07C47/02

公开(公告)号：ES2163839T3

公开(公告)日：2002-02-01

申请号：ES98202880

申请日：1998-08-26

Applicant: SHELL INT RESEARCH

Inventor： ARNOLDY PETER ,  BOLINGER CORNELIS MARK ,  MUL WILHELM PETRUS

IPC: B01J27/228 ,  C07B61/00 ,  C07C27/22 ,  C07C29/16 ,  C07C45/50

Abstract: A process for the hydroformylation of ethylenically unsaturated compounds with carbon monoxide and hydrogen in the presence of a catalyst system comprising a) a source of platinum group metal cations; b) a source of non-halide anions; c) a source of at least one bidentate ligand of the formula R R M RM R R wherein M and M independently represent a phosphorus, arsenic or antimony atom, R represents a bivalent bridging group containing from 1-4 atoms in the bridge, R and R independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M , and R and R independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M ; and d) a source of halide anions chosen from the group of chloride, iodide and bromide and mixtures thereof, characterised by the additional presence of water, in an amount of more than 0.6 wt% based on the total of the reaction mixture and up to its solubility limit under the reaction conditions.

公开(公告)号：ZA987663B

公开(公告)日：1999-02-24

申请号：ZA987663

申请日：1998-08-25

Applicant: SHELL INT RESEARCH

Inventor： ARNOLDY PETER ,  BOLINGER CORNELIS MARK ,  MUL WILHELM PETRUS

IPC: B01J27/228 ,  C07B61/00 ,  C07C27/22 ,  C07C29/16 ,  C07C45/50 ,  C07C

Abstract: A process for the hydroformylation of ethylenically unsaturated compounds with carbon monoxide and hydrogen in the presence of a catalyst system comprising a) a source of platinum group metal cations; b) a source of non-halide anions; c) a source of at least one bidentate ligand of the formula R R M RM R R wherein M and M independently represent a phosphorus, arsenic or antimony atom, R represents a bivalent bridging group containing from 1-4 atoms in the bridge, R and R independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M , and R and R independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M ; and d) a source of halide anions chosen from the group of chloride, iodide and bromide and mixtures thereof, characterised by the additional presence of water, in an amount of more than 0.6 wt% based on the total of the reaction mixture and up to its solubility limit under the reaction conditions.