公开(公告)号：US20220106521A1

公开(公告)日：2022-04-07

申请号：US17427728

申请日：2020-02-03

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Christopher Luke HEIN ,  Hao ZHOU ,  Bing ZHOU ,  Manojkumar CHELLAMUTHU ,  Duygu Deniz GUNBAS

IPC: C09K11/02 ,  C08L33/12 ,  C08L83/10 ,  C08L69/00 ,  C08J5/18

Abstract: A thermoplastic composition includes: a thermoplastic polymer including from about 30 wt % to about 90 wt % poly(methyl methacrylate) (PMMA) and from about 5 wt % to about 70 wt % of a poly(carbonate-siloxane) copolymer having a siloxane content of from about 20 wt % to about 60 wt %; and a plurality of photoluminescent materials including quantum dots.

公开(公告)号：US20210380809A1

公开(公告)日：2021-12-09

申请号：US17286873

申请日：2019-10-22

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Christopher Luke HEIN ,  Hao ZHOU ,  Bing ZHOU ,  Manojkumar CHELLAMUTHU ,  Peter VOLLENBERG

IPC: C08L83/10 ,  C08L33/12 ,  C08J5/18

Abstract: A thermoplastic composition includes from about 30 wt % to about 95 wt % poly(methyl methacrylate) (PMMA), and from about 5 wt % to about 70 wt % of a poly(carbonate-siloxane) copolymer having a siloxane content of from about 25 wt % to about 45 wt %. A method of making a thermoplastic composition includes: (a) combining from about 30 wt % to about 95 wt % poly(methyl methacrylate) (PMMA) and from about 5 wt % to about 70 wt % of a poly(carbonate-siloxane) copolymer having a siloxane content of from about 25 wt % to about 45 wt % to form a mixture; and melt processing the mixture to polymerize it and form the thermoplastic composition.

公开(公告)号：US20230044498A1

公开(公告)日：2023-02-09

申请号：US17783507

申请日：2020-12-30

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Mark A. SANNER ,  Raghavendra Raj MADDIKERI ,  Thomas Link GUGGENHEIM ,  Manojkumar CHELLAMUTHU

IPC: C08G73/10 ,  C08K5/526

Abstract: A polyetherimide composition comprises: a polyetherimide; and an organophosphorus stabilizer present in an amount effective to provide greater than 0.01 ppm to less than 20 ppm, preferably greater than 0.01 ppm to less than 10 ppm, and more preferably greater than 0.01 ppm to less than 4.8 ppm of phosphorus based on the total weight of the polyetherimide composition, the organophosphorus stabilizer having a molecular weight of 300 to 2,000 Daltons and a phosphorus content of 1 to 15 wt %; wherein a molded sample of the polyetherimide composition has a UL 94 V0 rating at a thickness of 1.5 mm.

公开(公告)号：US20210309847A1

公开(公告)日：2021-10-07

申请号：US17286597

申请日：2019-10-22

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Christopher Luke HEIN ,  Hao ZHOU ,  Bing ZHOU ,  Manojkumar CHELLAMUTHU ,  Peter VOLLENBERG

IPC: C08L33/12 ,  C08L83/10 ,  B29B9/10 ,  B29C45/00 ,  B29B13/02

Abstract: Thermoplastic compositions include: (a) from about 30 wt % to about 95 wt % poly(methyl methacrylate) (PMMA); and (b) from about 5 wt % to about 70 wt % of a poly(carbonate-siloxane) copolymer having a siloxane content of from about 25 wt % to about 45 wt %. Methods for making a molded article, include: (a) combining from about 30 wt % to about 95 wt % PMMA and from about 5 wt % to about 70 wt % of a poly(carbonate-siloxane) copolymer having a siloxane content of from about 25 wt % to about 45 wt % to form a blend; (b) melt processing and pelletizing the blend; and (c) injection molding the article from the melt processed and pelletized blend.

公开(公告)号：US20240317996A1

公开(公告)日：2024-09-26

申请号：US18609702

申请日：2024-03-19

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Manojkumar CHELLAMUTHU ,  James A. MAHOOD ,  Christopher Luke HEIN

IPC: C08L69/00 ,  C08K5/00

CPC classification number: C08L69/00 ,  C08K5/0066 ,  C08L2201/02 ,  C08L2201/10 ,  C08L2203/20 ,  C08L2205/025 ,  C08L2207/04

Abstract: A thermoplastic composition includes: a first branched polycarbonate copolymer end-capped with 4-hydroxybenzonitrile (4-HBN) having a molecular weight M1; and a second branched polycarbonate copolymer end-capped with 4-HBN having a molecular weight M2. M1 is less than M2. Methods for determining entanglement molecular weight (Me) of a polycarbonate copolymer include: preparing a sample of a branched polycarbonate copolymer including a 1,1,1-tris-hydroxy-phenylethane (THPE) branching agent and that is end-capped with 4-HBN; determining phase angle (∂) versus complex modulus (G*) of the sample using a small amplitude oscillatory rheology process at a specified temperature; determining a minima in the ∂ of the sample; determining a plateau modulus (GN) of the sample from the determined minima of ∂; and calculating the Me of the sample from the GN.

公开(公告)号：US20220089900A1

公开(公告)日：2022-03-24

申请号：US17418907

申请日：2020-03-25

Applicant: SHPP Global Technologies B.V.

Inventor： Rabeh Hosny ELLEITHY ,  Manojkumar CHELLAMUTHU ,  Alex R. DELANEY ,  Paul Dean SYBERT ,  Kim Loan Thi LY

IPC: C09D169/00 ,  B33Y10/00 ,  B33Y70/00 ,  B29C64/118

Abstract: An article includes at least two contiguous layers containing a composition that includes a branched polycarbonate, optionally a linear carbonate-containing polymer, and 0 to less than 5 weight percent filler. The composition is characterized by an average mole percent branching of 0.06 to 2.4 mole percent, which is calculated as 100 times moles of branched carbonate units in the branched polycarbonate divided by the sum of moles of linear carbonate units in the branched polycarbonate and the optional linear carbonate-containing polymer. The composition is further characterized by a melt flow rate of 1 to 20 grams per 10 minutes, determined according to ASTM D1238-13 at 300° C. and 1.2 kilogram load. Also described is a method of additive manufacturing utilizing the composition.