公开(公告)号：US20250043078A1

公开(公告)日：2025-02-06

申请号：US18717676

申请日：2022-12-09

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Roy Ray Odle ,  Ryan J. Mondschein ,  Joseph Michael Dennis ,  Clay Bradley Arrington ,  Timothy Edward Long

IPC: C08G73/10

Abstract: A self-branching polyetherimide comprising a first repeating unit derived from polymerization of the aromatic dianhydride and a first diamine, wherein the first diamine comprises a carboxyl-substituted C6-24 aromatic hydrocarbon group; and optionally, a second repeating unit derived from polymerization of an aromatic dianhydride and a second diamine, wherein the second diamine comprises a C1-30 divalent hydrocarbon group, optionally comprising 1 to 4 heteroatoms, wherein the self-branching polyetherimide is end-capped with phthalic anhydride.

公开(公告)号：US20250122340A1

公开(公告)日：2025-04-17

申请号：US18717814

申请日：2022-12-09

Applicant: SHPP GLOBAL TECHNOLOGIES B.V.

Inventor： Roy Ray Odle ,  Clay Bradley Arrington ,  Timothy Edward Long

IPC: C08G73/10 ,  C08L79/08

Abstract: A polyimide, comprising 1-100 mol % of repeating units of formula (1), based on 100 mol % of total repeating units of the polyimide, wherein each V is as defined herein; and each R1 is independently a divalent group of formula (3), wherein A is anionic, and each A is independently —O, —S, —S(O)2, —S(O)2O, —OS(O)2O, —OP(O) (OR)dO, —P(O)(Re)O, —P(O)(ORf)O, or —OP(O)(Rg)O; and X is cationic, and each X is independently Li, Na, K, Cs, Mg, Ca, Sr, Cr, Mn, Fe, Co, Ni, Cu, Ag, Zn, Cd, B, Al, Ga, In, Ge, Sn, Pb, As, Sb, phosphonium, imidazolium, guanidinium, or pyridinium; and Rd, Re, Rf, and Rg are each independently hydrogen, substituted or unsubstituted C1-8 alkyl, or substituted or unsubstituted C6-12 aryl.

公开(公告)号：US11142643B2

公开(公告)日：2021-10-12

申请号：US16533922

申请日：2019-08-07

Applicant: SHPP Global Technologies B.V.

Inventor： Mani Raj Chaulagain ,  Roy Ray Odle

IPC: C08L81/06 ,  C08G65/40 ,  C08G75/23 ,  C08L81/00 ,  C08G75/00 ,  C08K5/08 ,  C08K5/13 ,  C08K5/3417

Abstract: A method of manufacture of a polyetherimide copolymer composition includes contacting a substituted phthalic anhydride and an organic diamine in the presence of diphenyl sulfone, sulfolane, or a combination comprising at least one of the foregoing solvents at a temperature of greater than 130° C. to provide a bis(phthalimide) composition comprising diphenyl sulfone, sulfolane, or a combination comprising at least one of the foregoing solvents and a bis(phthalimide); and copolymerizing the bis(phthalimide), a substituted aromatic compound, and an alkali metal salt of a dihydroxy aromatic compound in the presence of diphenyl sulfone, sulfolane, or a combination comprising at least one of the foregoing to form a polyetherimide copolymer. The method does not require any catalyst either for the imidization or the polymerization.

公开(公告)号：US11970608B2

公开(公告)日：2024-04-30

申请号：US17265172

申请日：2019-07-31

Applicant: SHPP Global Technologies B.V.

Inventor： Wei Zhao ,  Roy Ray Odle ,  Paul Dean Sybert

IPC: C08L69/00 ,  C08G64/12 ,  C08K3/32 ,  C08K5/42 ,  C08K5/524

CPC classification number: C08L69/00 ,  C08G64/12 ,  C08K3/32 ,  C08K5/42 ,  C08K5/524 ,  C08K2003/329 ,  C08L2201/08 ,  C08L2201/10

Abstract: Provided are copolycarbonate compositions including a stabilizer package which comprise a phosphorous-containing acid, an ester of phosphorous-containing acid, and an organosulfonic stabilizer where the phosphorous-containing acid and the ester of a phosphorous-containing acid are present in a molar ratio of 1 to 2. The total stabilization package is for example, in the amount by weight of 4 to 32 ppm, 8 to 24 ppm, or 8 to 16 ppm and the organosulfonic stabilizer is, e.g., of 2 to 30 ppm, or 4 to 24 ppm, or 8 to 16 ppm.