公开(公告)号：KR870001409B1

公开(公告)日：1987-07-30

申请号：KR850003918

申请日：1985-06-05

Applicant: STAMICARBON

Inventor： BONGERS JOZEF J M ,  GEENEN ALBERT A VAN

IPC: C08G69/00 ,  C08G18/10 ,  C08G18/80 ,  C08G69/18 ,  C08G69/20

公开(公告)号：KR870001410B1

公开(公告)日：1987-07-30

申请号：KR850000719

申请日：1985-02-05

Applicant: STAMICARBON

Inventor： VRINSSEN CORNELISH ,  GENNEN ALBERT A VAN ,  BONGERS JOZEF J M

IPC: C08G69/18 ,  C08G18/80 ,  C08G69/00 ,  C08G69/16 ,  C08G69/20

公开(公告)号：CA1221364A

公开(公告)日：1987-05-05

申请号：CA461249

申请日：1984-08-17

Applicant: STAMICARBON

Inventor： VAN GEENEN ALBERT A ,  BONGERS JOZEF J M ,  VAN DER LOOS JOZEF L M ,  VRINSSEN CORNELIS H

IPC: C08G69/14 ,  C08G18/80 ,  C08G65/32 ,  C08G65/333 ,  C08G69/00 ,  C08G69/18 ,  C08G69/20 ,  C08G69/40 ,  C07D223/10

Abstract: The invention concerns N-substituted carbamoyl-lactam compounds of the formula where: - R is a polyol radical from a polyol having the formula R-(-OH)xi, where Xi is an integer ? 2, - R' is an alkyl, whether or not cyclic, aralkyl, alkaryl or aryl group, .gamma.i is an integer > O, - (-L) is an unopened lactam ring and - (-L-) is an opened lactam block. These compounds are useful in the preparation of highly impact resistant nylon block copolymers.

公开(公告)号：CA1318050C

公开(公告)日：1993-05-18

申请号：CA585042

申请日：1988-12-06

Applicant: STAMICARBON

Inventor： VAN GEENEN ALBERT A ,  BONGERS JOZEF J M ,  SCHROEDER CHRISTIAAN

IPC: C08G18/80 ,  C08G69/18

Abstract: 22772-1130 This invention relates to a process for the preparation of a nylon block copolymer in which two or more reaction streams consisting of molten lactam are combined in a mould, said reaction streams containing one or more polyols, lactam blocked polyisocyanates and catalysts, and the catalysts and polyisocyanates being in different streams, which reaction, streams having a temperature of 68.degree.C - 95.degree.C introduced into a mould having a temperature of 100.degree.C - 180.degree.C. The advantage of this process is that now the polyol is homogeneously distributed throughout the nylon matrix, and as a consequence a nylon block copolymer with excellent notched resistance is obtained.

公开(公告)号：CA1252091A

公开(公告)日：1989-04-04

申请号：CA497975

申请日：1985-12-18

Applicant: STAMICARBON

Inventor： VAN GEENEN ALBERT A ,  BONGERS JOZEF J M

IPC: C07D207/263 ,  C07D211/76 ,  C07D223/10 ,  C07D225/02 ,  C07D227/08 ,  C07D227/087 ,  C08G69/00 ,  C08G69/14 ,  C08G69/18 ,  C08G69/20 ,  C08G69/40 ,  C08G69/42 ,  C08G69/44 ,  C08G69/16

Abstract: The invention relates to the N-substituted acyl-lactam compound of the formula: where - R' is a bivalent cyclic or non-cyclic alkyl, aralkyl, alkaryl or aryl radical - R" a radical having the following general formula wherein - R'" is H, alkyl, cycloalkyl, aryl, alkaryl or aralkyl, - Riv is H, alkyl, cycloalkyl, aryl, alkaryl or aralkyl where - R'" and Riv may jointly form a substituted or non-substituted cycloalkyl residue - n is 0 or 1 - (-L) represents a non-opened lactam ring and - x a numer > 1. It has been found that this group of compounds is very suitable as activator in the preparation of nylon polymers, more specifically in the so-called RIM (Reaction Injection Moulding) or RRIM (reinforced RIM) systems, in which it is highly essential for the polymerization to take effect within a very short time.

公开(公告)号：CA1252089A

公开(公告)日：1989-04-04

申请号：CA497987

申请日：1985-12-18

Applicant: STAMICARBON

Inventor： VAN GEENEN ALBERT A ,  BONGERS JOZEF J M

IPC: C08G69/00 ,  C07D227/08 ,  C08G69/14 ,  C08G69/18 ,  C08G69/40 ,  C08G69/42 ,  C08G69/44 ,  C07D223/10 ,  C07D227/087 ,  C08G69/16

Abstract: The invention relates to a process for preparing an acyllactam compound characterized in that the reaction product of a lactam with a dicarboxylic acid anhydride is reacted with a polyol at a temperature of 150.degree.C at most. These acyl-lactam compounds are very suitable as activator in the preparation of nylon block copolymers, more specifically in the RIM or RRIM systems.

公开(公告)号：CA1252090A

公开(公告)日：1989-04-04

申请号：CA497988

申请日：1985-12-18

Applicant: STAMICARBON

Inventor： BONGERS JOZEF J M ,  VAN GEENEN ALBERT A

IPC: C07D207/263 ,  C07D211/76 ,  C07D223/08 ,  C07D223/10 ,  C07D225/02 ,  C07D227/08 ,  C07D227/087 ,  C08G18/10 ,  C08G63/685 ,  C08G63/91 ,  C08G65/32 ,  C08G69/00 ,  C08G69/14 ,  C08G69/18 ,  C08G69/20 ,  C08G69/40 ,  C08G69/42 ,  C08G69/44 ,  C08G77/32 ,  C08G77/388 ,  C08G85/00 ,  C08G69/16

Abstract: The invention relates to N-substituted acyl lactam compounds of the formula where - R is a polyol residue originating from a polyol with the formula R-(OH)X where x is a number > 2 - R' a bivalent cyclic or non-cyclic alkyl, aralkyl, alkaryl or aryl radical - R' a bivalent radical having the following general formula wherein - R" is H, alkyl, cycloalkyl, aryl, alkaryl or aralkyl, - Riv is H, alkyl, cycloalkyl, aryl, alkaryl or aralkyl where - R" and Riv may jointly form a substituted or non-substituted cycloalkyl residue - n is O or l and - (-L) represents a non-opened lactam ring of the formula wherein Y is a hydrocarbon residue with 3-11 carbon atoms. It has been found that this group of compounds is very suitable as activator in the preparation of nylon block copolymers, more specifically in the RIM or RRIM systems.

公开(公告)号：PL249231A1

公开(公告)日：1985-06-04

申请号：PL24923184

申请日：1984-08-17

Applicant: STAMICARBON

Inventor： VAN GEENEN ALBERT A ,  BONGERS JOZEF J M ,  VAN DER LOOS JOZEF L M ,  VRINSSEN CORNELIS H

IPC: C08G69/14 ,  C08G18/80 ,  C08G65/32 ,  C08G65/333 ,  C08G69/00 ,  C08G69/18 ,  C08G69/20 ,  C08G69/40 ,  C08G

Abstract: The invention concerns an N-substituted carbamoyl-lactam compound characterized by the formula:where in the formula:- R is a polyol radical from a polyol having the formula R-(OH) xi , where xi is an integer ≥ 2- R' is an alkyl, whether or not cyclic aralkyl, alkaryl or aryl group, xi is an integer > 0,- (-L) is an unopened lactam ring and- (-L-) is an opened lactam block. The compounds are highly suited for use as activators in preparing nylon block copolymers.