公开(公告)号：CS235073B2

公开(公告)日：1985-04-16

申请号：CS876078

申请日：1978-12-21

Applicant: STANDARD OIL CO

Inventor： QUICK LEONARD M ,  HENSLEY ALBERT L

IPC: C10G49/04

公开(公告)号：CA1129839A

公开(公告)日：1982-08-17

申请号：CA347887

申请日：1980-03-18

Applicant: STANDARD OIL CO

Inventor： HENSLEY ALBERT L JR ,  QUICK LEONARD M ,  HOPKINS P DONALD

IPC: B01J21/12 ,  B01J35/10 ,  C10G45/08 ,  B01J23/85

Abstract: A process for hydrotreating a hydrocarbon stream to remove nitrogen and sulfur which process comprises contacting a hydrocarbon stream comprising a stream selected from petroleum distillate, tar sands distillate, and shale oil, with hydrogen and a catalyst comprising a porous refractory inorganic oxide and deposited thereon hydrogenation components comprising chromium, molybdenum and at least one Group VIII metal, said catalyst having a pore volume distribution comprising 20-50% of pore volume in pores with diameters of 0-50 Angstrom units, 30-70% of pore volume in pores with diameters of 50-100 Angstrom units, 0-20% of pore volume in pores with diameters of 100-150 Angstrom units, and 0-10% of pore volume in pores with diameters greater than 150 Angstrom units.

公开(公告)号：PL223797A1

公开(公告)日：1981-10-30

申请号：PL22379780

申请日：1980-04-26

Applicant: STANDARD OIL CO

Inventor： HENSLEY ALBERT L ,  QUICK LEONARD M ,  HOPKINS PAUL D

IPC: B01J20060101 ,  B01J23/85 ,  C10G20060101 ,  C10G45/08 ,  C10G ,  B01J

公开(公告)号：DD145541A5

公开(公告)日：1980-12-17

申请号：DD21463979

申请日：1979-07-26

Applicant: STANDARD OIL CO

Inventor： LLOYD JUN HENSLEY A ,  QUICK LEONARD M

IPC: B01J21/04 ,  B01J23/24 ,  B01J23/28 ,  B01J23/40 ,  B01J23/64 ,  B01J23/74 ,  B01J23/84 ,  B01J27/02 ,  B01J35/10 ,  C10G45/04 ,  C10G45/08 ,  C10G65/04

Abstract: Disclosed is a two-stage catalytic process for hydrodemetallation and hydrodesulfurization of heavy hydrocarbon streams containing asphaltenes and a substantial amount of metals. The first stage of this process comprises contacting the feedstock in a first reaction zone with hydrogen and a demetallation catalyst comprising hydrogenation metal selected from Group VIB and/or Group VIII deposed on a large-pore, high surface area inorganic oxide support; the second stage of the process comprises contacting the effluent from the first reaction zone with a catalyst consisting essentially of hydrogenation metal selected from Group VIB deposed on a smaller pore, catalytically active support comprising alumina, said second stage catalyst having a surface area within the range of about 150 m2/gm to about 300 m2/gm, having a majority of its pore volume in pore diameters within the range of about 80 A to about 130 A, and the catalyst has a pore volume within the range of about 0.4 cc/gm to about 0.9 cc/gm.

公开(公告)号：PL212811A1

公开(公告)日：1980-06-16

申请号：PL21281179

申请日：1979-01-15

Applicant: STANDARD OIL CO

Inventor： QUICK LEONARD M ,  HENSLEY JUN ALBERT L

IPC: C10G20060101 ,  C10G

公开(公告)号：CA1132078A

公开(公告)日：1982-09-21

申请号：CA330830

申请日：1979-06-29

Applicant: STANDARD OIL CO

Inventor： HENSLEY ALBERT L JR ,  QUICK LEONARD M

IPC: B01J21/04 ,  B01J23/24 ,  B01J23/28 ,  B01J23/40 ,  B01J23/64 ,  B01J23/74 ,  B01J23/84 ,  B01J27/02 ,  B01J35/10 ,  C10G45/04 ,  C10G45/08 ,  C10G65/04

Abstract: PROCESS FOR DEMETALLATION AND DESULFURIZATION OF HEAVY HYDROCARBONS Disclosed is a multiple-stage catalytic process for hydrodemetallation and hydrodesulfurization of heavy hydrocarbon streams containing asphaltenes and a substantial amount of metals. The first stage of this process comprises contacting the feedstock in a first reaction zone with hydrogen and a demetallation catalyst comprising hydrogenation metal selected from Group VIB and/or Group VIII deposed on a large-pore, high surface area inorganic oxide support; the second stage of the process comprises contacting the effluent from the first reaction zone with a catalyst consisting essentially of hydrogenation metal selected from Group VIB deposed on a smaller pore, catalytically active support comprising alumina, said second stage catalyst having a surface area within the range of about 150 m2/gm to about 300 m2/gm, an average pore diameter within the range of about 90 .ANG. to about 160 .ANG., and the catalyst has a pore volume within the range of about 0.4 cc/gm to about 0.9 cc/gm.

公开(公告)号：CA1040124A

公开(公告)日：1978-10-10

申请号：CA227610

申请日：1975-05-23

Applicant: STANDARD OIL CO

Inventor： MCCOLLUM JOHN D ,  QUICK LEONARD M

IPC: C10G1/00

Abstract: This invention involves a process for recovering upgraded hydrocarbon products from a carbonaceous material selected from the class consisting of oil shale solids, tar sands solids, coal solids and a hydrocarbon fraction by contacting the carbonaceous material with a dense-water-containing fluid at a temperature in the range of from about 600.degree.F. to about 900.degree.F. in the absence of supplied hydrogen and in the presence of a sulfur- and nitrogen-resistant catalyst.

公开(公告)号：CA1187864A

公开(公告)日：1985-05-28

申请号：CA404601

申请日：1982-06-07

Applicant: STANDARD OIL CO

Inventor： HENSLEY ALBERT L JR ,  QUICK LEONARD M

IPC: B01J21/02 ,  B01J21/12 ,  B01J23/28 ,  B01J27/16 ,  B01J35/10 ,  B01J37/10 ,  C10G45/04 ,  B01J27/14 ,  B01J35/04 ,  C10G45/26

Abstract: A catalyst support is prepared from a composite comprising two or more inorganic oxides by forming the composite into a shaped support material having at least 0.8 cc/gm of its pore volume in pore diameters of 0 nm (0 .ANG.) to 120 nm (1,200 .ANG.) and at least 0.1 cc/gm of its pore volume in pore diameters of 120 nm (1,200 .ANG.) to 5,000 nm (50,000 .ANG.) and heating said shaped support material in the presence of steam at sufficient elevated temperature, steam pressure, and time period to increase the average pore diameter of said shaped support in the absence of any appreciable reduction in pore volume. A catalyst is prepared by impregnating the steam-treated support with at least one hydrogenating metal. The catalyst can be used suitably in hydrocarbon conversion processes, such as a process for the hydrodemetallization of a hydrocarbon stream containing asphaltenes and a substantial amount of metals.

公开(公告)号：DD150221A5

公开(公告)日：1981-08-19

申请号：DD22080380

申请日：1980-04-30

Applicant: STANDARD OIL CO

Inventor： HENSLEY ALBERT L ,  QUICK LEONARD M ,  HOPKINS PAUL D

IPC: C10G45/06 ,  C10G45/08

公开(公告)号：DD140870A5

公开(公告)日：1980-04-02

申请号：DD21006978

申请日：1978-12-21

Applicant: STANDARD OIL CO

Inventor： QUICK LEONARD M ,  HENSLEY JUN ALBERT L

IPC: B01J23/28 ,  B01J23/88 ,  B01J23/887 ,  B01J35/10 ,  C10G45/04 ,  C10G69/04

Abstract: A heavy hydrocarbon stream containing metals, asphaltenes, nitrogen compounds, and sulfur compounds is (a) contacted with hydrogen and a hydrotreating catalyst containing molybdenum and chromium, either as metals, as oxides, as sulfides, or mixtures thereof, deposed on a large-pore, catalytically active alumina to reduce the metals content in said stream, to convert the asphaltenes, nitrogen compounds, and sulphur compounds in said stream, the catalyst has a pore volume within the range of about 0.4 cc/gm to about 0.8 cc/gm, a surface area within the range of about 150 m2/gm to about 300 m2/gm, and an average pore diameter within the range of about 100 A (10 nm) to about 200 A (20 nm); and (b) at least a portion of the hydrotreated stream is cracked with a cracking catalyst to produce gasoline and distillates in improved yields. The catalyst in step (a) may also contain cobalt.