公开(公告)号：WO2004043596A3

公开(公告)日：2004-08-12

申请号：PCT/GB0304873

申请日：2003-11-10

Applicant: STATOIL ASA ,  PETRO SA ,  RYTTER ERLING ,  ERI SIGRID ,  SCHANKE DAG ,  REES DAVID CHRISTOPHER

Inventor： RYTTER ERLING ,  ERI SIGRID ,  SCHANKE DAG

IPC: B01J23/75 ,  B01J23/889 ,  B01J35/02 ,  B01J35/10 ,  C10G2/00 ,  C07C1/04

CPC classification number: C10G2/332 ,  B01J23/75 ,  B01J23/8896 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  C10G2300/703

Abstract: A catalyst for use in a Fischer-Tropsch synthesis reaction which comprises cobalt supported on alumina, in which: the catalyst average particle size is in the range 20 to 100 µm; the specific surface area of the impregnated and calcined catalyst particles is greater than 80 m /g; the average pore size of the impregnated and calcined catalyst is at least 90Å (9nm); and the pore volume of the impregnated and calcined catalyst is greater than 0.35 cm /g.

Abstract translation: 一种用于费 - 托合成反应的催化剂，其包含负载在氧化铝上的钴，其中：催化剂平均粒度为20-100μm; 浸渍和煅烧的催化剂颗粒的比表面积大于80m 2 / g; 浸渍和煅烧的催化剂的平均孔径至少为90（9nm）; 并且浸渍和煅烧的催化剂的孔体积大于0.35cm 3 / g。

公开(公告)号：ZA200204552B

公开(公告)日：2003-10-01

申请号：ZA200204552

申请日：2002-06-06

Applicant: STATOIL ASA

Inventor： SCHANKE DAG ,  SOGGE JOSTEIN ,  WESENBERG MARGRETE H ,  HANSEN ROGER ,  HOFSTAD KARINA HEITNES ,  RYTTER ERLING

IPC: C01B3/38 ,  C07C1/04 ,  C10G2/00 ,  C07C ,  C10G ,  C01B

Abstract: A method is described for conversion of natural gas or other fossil fuels to higher hydrocarbons, comprising the following steps: a) reaction of natural gas with steam and oxygenic gas in at least one reforming zone in order to produce a synthesis gas consisting primarily of hydrogen and CO, in addition to some carbon dioxide; b) passing said synthesis gas to a Fisher-Tropsch reactor in order to produce a crude synthesis stream consisting of lower hydrocarbons, water and non-converted synthesis gas; c) separation of said crude synthesis stream in a recovery zone, into a crude product stream mainly containing heavier hydrocarbons, a water stream and a tail gas stream mainly containing the remaining constituents; which is charaterized in that the method also comprises the following steps; d) stream reformation of at least part of the tail gas in a separate steam reformer; e) introduction of the reformed tail gas into the gas stream before this is led into the Fischer-Tropsch reactor.

公开(公告)号：AU2003301952B2

公开(公告)日：2009-01-15

申请号：AU2003301952

申请日：2003-11-10

Applicant: PETROLEUM OIL & GAS CORPORATION OF SOUTH AFRICA PTY LTD ,  STATOIL ASA

Inventor： ERI SIGRID ,  SCHANKE DAG ,  RYTTER ERLING

IPC: B01J35/10 ,  B01J23/75 ,  B01J23/889 ,  B01J35/02 ,  C10G2/00

公开(公告)号：NO319053B1

公开(公告)日：2005-06-13

申请号：NO974606

申请日：1997-10-06

Applicant: STATOIL ASA

Inventor： SCHANKE DAG ,  KINNARI KEIJO JUHANI

IPC: B01J38/10

公开(公告)号：GB2389062B

公开(公告)日：2005-05-04

申请号：GB0316310

申请日：2001-12-11

Applicant: STATOIL ASA

Inventor： ERI SIGRID ,  KINNARI KEIJO JUHANI ,  SCHANKE DAG ,  HILMEN ANNE-METTE

IPC: B01J21/04 ,  B01J23/75 ,  B01J23/889 ,  B01J23/89 ,  B01J35/10 ,  C10G2/00 ,  C07C1/04

Abstract: Embodiments include a catalyst for use in a Fischer-Tropsch synthesis reaction which comprises cobalt supported on alumina. In some embodiments, the alumina support may have specific surface area of less than 50 m 2 /g and/or may be least 10% alpha-alumina.

公开(公告)号：CA2506534A1

公开(公告)日：2004-05-27

申请号：CA2506534

申请日：2003-11-10

Applicant: STATOIL ASA ,  PETROLEUM OIL & GAS CORP OF SO

Inventor： RYTTER ERLING ,  ERI SIGRID ,  SCHANKE DAG

IPC: B01J23/75 ,  B01J23/889 ,  B01J35/02 ,  B01J35/10 ,  C10G2/00 ,  C07C1/04

Abstract: A catalyst for use in a Fischer-Tropsch synthesis reaction which comprises cobalt supported on alumina, in which: the catalyst average particle size is in the range 20 to 100 ~m; the specific surface area of the impregnated and calcined catalyst particles is greater than 80 m2/g; the average pore size o f the impregnated and calcined catalyst is at least 90.ANG. (9nm); and the por e volume of the impregnated and calcined catalyst is greater than 0.35 cm3/g.

公开(公告)号：NO20052822A

公开(公告)日：2005-06-10

申请号：NO20052822

申请日：2005-06-10

Applicant: STATOIL ASA

Inventor： ERI SIGRID ,  RYTTER ERLING ,  SCHANKE DAG

IPC: B01J23/75 ,  B01J23/889 ,  B01J35/02 ,  B01J35/10 ,  C10G2/00 ,  C07C1/04

CPC classification number: C10G2/332 ,  B01J23/75 ,  B01J23/8896 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  C10G2300/703

公开(公告)号：AU2031501A

公开(公告)日：2001-06-18

申请号：AU2031501

申请日：2000-12-01

Applicant: STATOIL ASA

Inventor： SCHANKE DAG ,  HANSEN ROGER ,  SOGGE JOSTEIN ,  HOFSTAD KARINA HEITNES ,  WESENBERG MARGRETE H ,  RYTTER ERLING

IPC: C01B3/38 ,  C07C1/04 ,  C10G2/00 ,  C01B3/36

Abstract: A method is described for conversion of natural gas or other fossil fuels to higher hydrocarbons, comprising the following steps: a) reaction of natural gas with steam and oxygenic gas in at least one reforming zone in order to produce a synthesis gas consisting primarily of hydrogen and CO, in addition to some carbon dioxide; b) passing said synthesis gas to a Fisher-Tropsch reactor in order to produce a crude synthesis stream consisting of lower hydrocarbons, water and non-converted synthesis gas; c) separation of said crude synthesis stream in a recovery zone, into a crude product stream mainly containing heavier hydrocarbons, a water stream and a tail gas stream mainly containing the remaining constituents; which is charaterized in that the method also comprises the following steps; d) stream reformation of at least part of the tail gas in a separate steam reformer; e) introduction of the reformed tail gas into the gas stream before this is led into the Fischer-Tropsch reactor.

公开(公告)号：CA2506534C

公开(公告)日：2013-05-07

申请号：CA2506534

申请日：2003-11-10

Applicant: STATOIL ASA ,  PETROLEUM OIL & GAS CORP OF SOUTH AFRICA PTY LTD

Inventor： RYTTER ERLING ,  ERI SIGRID ,  SCHANKE DAG

IPC: B01J35/10 ,  B01J23/75 ,  B01J23/889 ,  B01J35/02 ,  C07C1/04 ,  C10G2/00

Abstract: A catalyst for use in a Fischer-Tropsch synthesis reaction which comprises cobalt supported on alumina, in which: the catalyst average particle size is in the range 20 to 100 ~m; the specific surface area of the impregnated and calcined catalyst particles is greater than 80 m2/g; the average pore size of the impregnated and calcined catalyst is at least 90.ANG. (9nm); and the pore volume of the impregnated and calcined catalyst is greater than 0.35 cm3/g.

公开(公告)号：EA009572B1

公开(公告)日：2008-02-28

申请号：EA200500805

申请日：2003-11-10

Applicant: STATOIL ASA ,  PETROLEUM OIL & AMP GAS CORP O

Inventor： RYTTER ERLING ,  ERI SIGRID ,  SCHANKE DAG

IPC: B01J35/10 ,  B01J23/75 ,  B01J23/889 ,  B01J35/02 ,  C10G2/00

Abstract: Предлпгпетсякатализатордляиспользованияв процессесинтезаФишера-Тропша, содержащийкобальт, нанесенныйнаоксидалюминия, вкоторомсреднийразмерчастицкатализаторасоставляетот 20 до 100 мкм; удельнаяплощадьповерхностипропитанныхи прокаленныхчастицкатализаторабольшечем 80 м/г; среднийразмерпорпропитанногои прокаленногокатализаторасоставляетпоменьшеймере 90Å (9 нм) иобъемпорпропитанногои прокаленногокатализаторабольшечем 0,35 см/г.